Suppressor for continuous electrochemically suppressed ion chromatography and method
    1.
    发明公开
    Suppressor for continuous electrochemically suppressed ion chromatography and method 审中-公开
    用于连续电化学抑制器离子色谱抑制器和方法

    公开(公告)号:EP1640714A3

    公开(公告)日:2006-07-05

    申请号:EP05028383.7

    申请日:2000-10-13

    IPC分类号: G01N30/96

    摘要: A method of detecting analyte ions by continuous electrochemically suppressed ion chromatography comprising: (a) flowing analyte ions in an aqueous mobile phase comprising electrolyte through an analytical column separating means to form an aqueous chromatography effluent comprising separated analyte ions and electrolyte; (b) flowing the aqueous chromatography effluent through a suppressor means for splitting the chromatography effluent into a first chromatography effluent flow stream and a second chromatography effluent flow stream; (c) applying an electrical potential in the suppressor means such that electrolyte is electrochemically driven into the first chromatography effluent stream and away from the second chromatography effluent flow stream; (d) flowing the second chromatography effluent flow stream out of the suppressor means; (e) detecting the analyte ions in the second chromatography effluent flow stream.

    Evaporative light scattering device
    4.
    发明公开
    Evaporative light scattering device 有权
    蒸发光散射检测器

    公开(公告)号:EP1132738A1

    公开(公告)日:2001-09-12

    申请号:EP01105606.6

    申请日:2001-03-06

    发明人: Benedict, Bart C.

    IPC分类号: G01N30/74 G01N21/47

    摘要: The present invention is directed to a device for evaporative light scattering detection that can be used for a wide range of sample types and mobile phases. The device may be quickly converted between a single flow and a split flow configuration through the use of a retractable impactor (105). The drift tube (104) of the device is in flow communication with the nebulizer (102) of the device, the drift tube (104) comprising a drain outlet (110) and the retractable impactor (105) positioned downstream in the direction of flow from the nebulizer (102).

    Suppressor for continuous electrochemically suppressed ion chromatography and method
    5.
    发明公开
    Suppressor for continuous electrochemically suppressed ion chromatography and method 审中-公开
    抑制剂和维生素Zur kontinuierlichen elektrochemischen抑制剂 - 离子色谱

    公开(公告)号:EP1074837A1

    公开(公告)日:2001-02-07

    申请号:EP00116707.1

    申请日:2000-08-02

    IPC分类号: G01N30/96

    摘要: Methods and devices for continuous electrochemically suppressed ion chromatography are disclosed. In preferred aspect of the invention, a chromatography effluent comprising analyte ions and electrolyte is split into a first chromatography effluent flow stream and a second chromatography effluent flow stream. Electrolysis ions selected from the group consisting of hydronium ions and hydroxide ions are generated by the electrolysis of water. Electrolysis ions of the same charge as the electrolyte and the second chromatography effluent stream are flowed through a stationary phase thereby suppressing the electrolyte in the second chromatography effluent flow stream. The analyte ions are subsequently detected in the suppressed second chromatography effluent flow stream.

    摘要翻译: 公开了用于连续电化学抑制离子色谱法的方法和装置。 在本发明的优选方面,包含分析物离子和电解质的色谱流出物被分成第一色谱流出物流和第二层析流出物流。 通过水的电解产生选自水合氢离子和氢氧根离子的电解离子。 与电解质和第二层析流出物流相同的电解离子流过固定相,从而抑制第二层析流出物流中的电解质。 随后在抑制的第二色谱流出物流中检测分析物离子。

    Suppressor for continuous electrochemically suppressed ion chromatography and method
    6.
    发明公开
    Suppressor for continuous electrochemically suppressed ion chromatography and method 审中-公开
    抑制剂和维生素Zur kontinuierlichen elektrochemischen抑制剂 - 离子色谱

    公开(公告)号:EP1640714A2

    公开(公告)日:2006-03-29

    申请号:EP05028383.7

    申请日:2000-10-13

    IPC分类号: G01N30/96

    摘要: A method of detecting analyte ions by continuous electrochemically suppressed ion chromatography comprising: (a) flowing analyte ions in an aqueous mobile phase comprising electrolyte through an analytical column separating means to form an aqueous chromatography effluent comprising separated analyte ions and electrolyte; (b) flowing the aqueous chromatography effluent through a suppressor means for splitting the chromatography effluent into a first chromatography effluent flow stream and a second chromatography effluent flow stream; (c) applying an electrical potential in the suppressor means such that electrolyte is electrochemically driven into the first chromatography effluent stream and away from the second chromatography effluent flow stream; (d) flowing the second chromatography effluent flow stream out of the suppressor means; (e) detecting the analyte ions in the second chromatography effluent flow stream.

    摘要翻译: 通过连续电化学抑制的离子色谱检测分析物离子的方法,其包括:(a)通过分析柱分离装置将包含电解质的水性流动相中的分析物离子流动,以形成包含分离的分析物离子和电解质的含水层析流出物; (b)使含水层析流出物流过抑制剂装置,用于将色谱流出物分离成第一色谱流出物流和第二色谱流出物流; (c)在抑制器装置中施加电势使得电解质被电化学驱动进入第一色谱流出物流并且远离第二层析流出物流; (d)使第二层析流出物流流出抑制装置; (e)检测第二层析流出物流中的分析物离子。