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公开(公告)号：EP1501879A1
公开(公告)日：2005-02-02
申请号：EP03720470.8
申请日：2003-04-15
CPC分类号： C08F297/04 , C07F5/062 , C08F4/54 , C08F36/04 , C08L53/02 , C08F4/52 , C08F4/48 , C08L2666/02
摘要： The invention relates to an initiator composition and method for anionic polymerisation, comprising at least one alkali metal hydride, selected from LiH, NaH and KH and at least one organoaluminium compound. The invention further relates to a method for anionic polymerisation of styrol or dienyl monomers using said initiator composition.
摘要翻译： 本发明涉及用于阴离子聚合的引发剂组合物和方法，其包含至少一种选自LiH，NaH和KH的碱金属氢化物和至少一种有机铝化合物。 本发明进一步涉及使用所述引发剂组合物使苯乙烯或二烯基单体阴离子聚合的方法。
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2.发明公开VERFAHREN ZUR KONTINUIERLICHEN ANIONISCHEN POLYMERISATION VON SCHLAGZÄHEM POLYSTYROL 审中-公开方法对于连续阴离子聚合高抗冲聚苯乙烯
公开(公告)号：EP1448639A2
公开(公告)日：2004-08-25
申请号：EP02779496.5
申请日：2002-10-18
IPC分类号： C08F279/02
CPC分类号： C08F287/00 , C08F279/02
摘要： A method for the production of impact-resistant moulding materials by anionic polymerization of vinyl aromatic monomers in the presence of rubber in a continuously through-flown reactor cascade consisting of at least two reactors. The vinyl aromatic monomers are fed to the reactors of the reactor cascade in partial flows and an anionic initiator and rubber are fed to at least the first reactor. The reactor cascade consists of backmixed reactors.
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公开(公告)号：EP1723192A1
公开(公告)日：2006-11-22
申请号：EP05715272.0
申请日：2005-02-08
发明人： DEININGER, Jürgen , DEMETER, Jürgen , HAHN, Thilo , KORY, Gad , SÖTJE, Oliver , ZEHNER, Peter
CPC分类号： C08G69/28 , C08G69/04 , Y02P20/127
摘要： Disclosed is a continuous method for producing polyamides, the oligomers or mixtures thereof, optionally with other reaction products, by reacting aminonitriles or dinitriles and diamines or mixtures thereof, optionally along with additional polyamide-forming monomers and/or oligomers, with an aqueous medium comprising aqueous monomer extracts or oligomer extracts which are obtained when extracting the polymer with water during the production of polyamides. Said reaction is carried out in a reactor which has a vertical longitudinal axis and is penetrated essentially in the longitudinal direction. According to the inventive method, water and/or the aqueous medium is/are introduced into the reactor at least at two different points located along the vertical longitudinal axis thereof, the aqueous medium being introduced at least at one point.
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公开(公告)号：EP1625173A1
公开(公告)日：2006-02-15
申请号：EP04731336.6
申请日：2004-05-06
发明人： WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , WILMS, Axel , WEISS, Robert , KREMPEL, Kurt , BENISCH, Christoph
IPC分类号： C08G69/02
CPC分类号： C08G69/26 , C08G69/02 , C08G69/08 , C08G69/14 , C08G69/265
摘要： The invention relates to a polyamide, the main chain thereof containing a chemically bonded amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, wherein R represents a functional group that can react with an amino group to form an amide group. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
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公开(公告)号：EP1558668A1
公开(公告)日：2005-08-03
申请号：EP03809735.8
申请日：2003-10-28
摘要： The invention relates to a polyamide comprising a compound having at least one hydroxyl group, chemically bonded to the end of the polymer chain by means of an amide group, a method for production of such a polyamide, and fibres, films and moulded bodies comprising at least one such polyamide.
摘要翻译： 本发明涉及包含具有至少一个羟基的化合物的聚酰胺，所述化合物通过酰胺基团化学键合到聚合物链的末端，制备这种聚酰胺的方法以及纤维，膜和模制体，所述纤维，膜和模制体包含 至少一个这种聚酰胺。
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公开(公告)号：EP1631615B1
公开(公告)日：2007-11-21
申请号：EP04731364.8
申请日：2004-05-06
发明人： WINTERLING, Helmut , DEMETER, Jürgen , DEININGER, Jürgen , KORY, Gad , SÖTJE, Oliver , NEUHAUS, Ralf , KREMPEL, Kurt , BENISCH, Christoph
摘要： The invention relates to a polyamide, the main chain thereof containing a chemically bonded N-alkyl lactam. The invention also relates to a method for producing one such polyamide, and to fibres, films and moulded bodies containing the same.
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公开(公告)号：EP1558668B1
公开(公告)日：2007-09-12
申请号：EP03809735.8
申请日：2003-10-28
摘要： The invention relates to a polyamide comprising a compound having at least one hydroxyl group, chemically bonded to the end of the polymer chain by means of an amide group, a method for production of such a polyamide, and fibres, films and moulded bodies comprising at least one such polyamide.
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8.发明公开VERFAHREN ZUR ABTRENNUNG VON AMMONIAK UND WASSER AUS GEMISCHEN, DIE BEI DER HERSTELLUNG VON POLYAMIDEN ENTSTEHEN 审中-公开用于分离氨和水对混合物的，聚酰胺ARISE制造
公开(公告)号：EP1756208A1
公开(公告)日：2007-02-28
申请号：EP05744786.4
申请日：2005-05-31
发明人： ASSMANN, Jens , DEMETER, Jürgen , DEININGER, Jürgen , SÖTJE, Oliver , KORY, Gad , LÖNING, Jan-Martin
CPC分类号： C08G69/04 , B01D3/14 , B01D5/0036 , C01C1/10 , C08G69/16 , C08G69/28 , C08J11/06 , Y02W30/701
摘要： The invention relates to a method for the distillative separation of ammonia and water from mixtures arising during the production of polyamides, said mixture containing a lactam and/or diamines and, optionally, an aminonitrile and/or dinitrile in addition to cyclopentanones as foreign substances. Said method consists of two steps: 1) the mixture is distilled at 11 - 35 bars, resulting in the production of water, ammonia and cyclopentanone as overhead products (K1), and water, lactam and/or diamines and, optionally, aminonitrile and/or dinitrile, as base products (S1), and 2) K1 is distilled at 11 - 35 bars, resulting in the production of ammonia and cyclopentanone as an overhead product, and water as a base product (S2).
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公开(公告)号：EP1611184A1
公开(公告)日：2006-01-04
申请号：EP04721865.6
申请日：2004-03-19
发明人： DEININGER, Jürgen , DEMETER, Jürgen , KORY, Gad , SÖTJE, Oliver , WINTERLING, Helmut , ZEHNER, Peter , HEEGER, Michael , GANN, Martin , POLT, Axel , TREULING, Ulrich , WEINLE, Werner
摘要： The invention relates to a method for producing polyamides, their oligomers or mixtures thereof, optionally containing other reaction products, by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine and optionally additional polyamide-forming monomers and/or oligomers with water in a reactor (1) with a vertical longitudinal axis. According to said method, the reaction product is exfiltrated from the sump in the reactor (1) and accumulated ammonia and optionally other accumulated low-molecular compounds and water are drawn off via the head (2). The invention is characterised in that the reactor (1) comprises at least two chambers (4) arranged in a longitudinal direction one above the other, that the chambers (4) are separated from one another by liquid-tight floors (5), that each chamber (4) is connected to the one (4) immediately below by a respective liquid overflow (6) and a liquid product stream is drawn off via the liquid overflow (6) of the lowest chamber (4), that the gas chamber (7) above the liquid level in each chamber (4) is connected to the respective chamber (4) lying immediately above it via one or several conduits (8), which open respectively into a gas diffuser (9) comprising orifices (11) for the discharge of gas below the liquid level. The reactor also comprises at least one respective deflector plate (12) positioned vertically around each gas diffuser (9), the upper end of said plate terminating below the liquid level and the lower end terminating above the liquid-tight floor (5) of the chamber (4), thus sub-dividing each chamber (4) into one or more compartments supplied with gas (13) and one or more compartments without gas (14).
摘要翻译： 本发明涉及通过将氨基腈或二腈和二胺或含有氨基腈，二腈和二胺的混合物以及任选另外的形成聚酰胺的单体和/或低聚物与含有其它反应产物的聚酰胺及其低聚物或其混合物 在具有垂直纵轴的反应器（1）中的水。 根据所述方法，反应产物从反应器（1）中的槽中渗出并且积聚氨和任选地其他积聚的低分子化合物和水经由头部（2）排出。 本发明的特征在于，反应器（1）包括至少两个沿上下方向纵向排列的室（4），室（4）通过液密地板（5）彼此分隔开， 每个腔室（4）通过相应的液体溢流（6）与正下方的一个（4）连接，并且液体产品物流通过最低腔室（4）的液体溢流（6）排出，使得气体腔室 （4）中液面以上的通道（7）通过一个或多个导管（8）连接到位于其正上方的相应室（4），所述导管分别通向包括孔口（11）的气体扩散器（9） 用于排放低于液位的气体。 该反应器还包括至少一个分别垂直放置在每个气体扩散器（9）周围的相应偏转板（12），所述板的上端终止于液位下方，并且其下端终止于液体密封层 从而将每个腔室（4）细分成供应有气体（13）的一个或多个隔室和不含气体（14）的一个或多个隔室。
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公开(公告)号：EP1611184B1
公开(公告)日：2006-09-27
申请号：EP04721865.6
申请日：2004-03-19
发明人： DEININGER, Jürgen , DEMETER, Jürgen , KORY, Gad , SÖTJE, Oliver , WINTERLING, Helmut , ZEHNER, Peter , HEEGER, Michael , GANN, Martin , POLT, Axel , TREULING, Ulrich , WEINLE, Werner
摘要： The invention relates to a method for producing polyamides, their oligomers or mixtures thereof, optionally containing other reaction products, by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine and optionally additional polyamide-forming monomers and/or oligomers with water in a reactor (1) with a vertical longitudinal axis. According to said method, the reaction product is exfiltrated from the sump in the reactor (1) and accumulated ammonia and optionally other accumulated low-molecular compounds and water are drawn off via the head (2). The invention is characterised in that the reactor (1) comprises at least two chambers (4) arranged in a longitudinal direction one above the other, that the chambers (4) are separated from one another by liquid-tight floors (5), that each chamber (4) is connected to the one (4) immediately below by a respective liquid overflow (6) and a liquid product stream is drawn off via the liquid overflow (6) of the lowest chamber (4), that the gas chamber (7) above the liquid level in each chamber (4) is connected to the respective chamber (4) lying immediately above it via one or several conduits (8), which open respectively into a gas diffuser (9) comprising orifices (11) for the discharge of gas below the liquid level. The reactor also comprises at least one respective deflector plate (12) positioned vertically around each gas diffuser (9), the upper end of said plate terminating below the liquid level and the lower end terminating above the liquid-tight floor (5) of the chamber (4), thus sub-dividing each chamber (4) into one or more compartments supplied with gas (13) and one or more compartments without gas (14).
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