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    VERFAHREN ZUR HERSTELLUNG VON OXO-CYCLOHEXYL- ODER OXO-CYCLOHEXYLENDERIVATEN
    2.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON OXO-CYCLOHEXYL- ODER OXO-CYCLOHEXYLENDERIVATEN 审中-公开
    用于生产羰基合成丁辛环己基或CYCLOHEXYLENDERIVATEN

    公开(公告)号：EP1423350A1

    公开(公告)日：2004-06-02

    申请号：EP02767362.3

    申请日：2002-08-10

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： BOTZEM, Jörg ,  ERNST, Hansgeorg ,  GRIMMER, Johannes ,  MERK, Claudia ,  MÜLLER, Thomas ,  SAUERWALD, Manfred

    IPC分类号： C07C45/62

    CPC分类号： C25B3/04

    摘要： The invention relates to a method for producing compounds of general formula (I), wherein Rl represents an oxocyclohexyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, or an oxocyclohexenyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, the oxo groups being in the form of an acetal, a ketone, or an enol ether, and R2 represents a hydroxy group or a protective group which can be transformed into a hydroxy group by means of hydrolysis. A compound of general formula (II) is cathodically reduced in a divided or partially divided electrolysis cell at a pH value of between 2 and 9.

    VERFAHREN ZUR HYDRIERUNG VON CARBONYLVERBINDUNGEN
    4.
    发明公开
    VERFAHREN ZUR HYDRIERUNG VON CARBONYLVERBINDUNGEN 有权

    公开(公告)号：EP1060154A1

    公开(公告)日：2000-12-20

    申请号：EP99911740.1

    申请日：1999-03-05

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： HESSE, Michael ,  KRATZ, Detlef ,  SCHULZ, Gerhard ,  WALTER, Marc ,  SAUERWALD, Manfred

    IPC分类号： C07C29/141 ,  B01J23/72

    CPC分类号： B01J23/72 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22

    摘要： The invention relates to a method for the catalytic hydrogenation of a carbonyl compound or of a mixture comprised of two or more carbonyl compounds in the presence of a catalyst. Said catalyst comprises an inorganic supporting material containing TiO2, and, as an active component, copper or a mixture of copper with at least one of the metals selected from the group zinc, aluminum, cerium, a precious metal and a metal of subgroup VIII. The invention is characterized in that the copper surface amounts to a maximum of 10 m2/g.

    摘要翻译： 本发明涉及在催化剂存在下催化氢化羰基化合物或由两种或更多种羰基化合物组成的混合物的方法。 所述催化剂包含含有TiO 2的无机载体材料和作为活性组分的铜或铜与至少一种选自锌，铝，铈，贵金属和第Ⅷ族金属的金属的混合物。 本发明的特征在于铜表面达到最大10m 2 / g。