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    VEFAHREN ZUR HERSTELLUNG VIN TRIAZOLYLMETHYL-OXIRANEN
    1.
    发明公开
    VEFAHREN ZUR HERSTELLUNG VIN TRIAZOLYLMETHYL-OXIRANEN 有权
    VEFAHREN用于生产VIN三唑基甲基环氧乙烷

    公开(公告)号：EP1399437A1

    公开(公告)日：2004-03-24

    申请号：EP02738069.0

    申请日：2002-05-14

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： NOACK, Rainer ,  SANDER, Michael ,  KAISER, Reinhard

    IPC: C07D405/06

    CPC classification number: C07D405/00

    Abstract: The invention relates to a method for the purification of triazolylmethylepoxide isomers of formula (I), where A and B independently = C1-C4 alkyl, phenyl-(C1-C2 alkyl), C3-C6 cycloalkyl, C3.C6 cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl, whereby the phenyl residue can carry one to three substituent from the group: halogen, nitro, C1-C4 alkyl, C1-C4 alkyloxy, phenoxy, amino, C1-C2 haloalkyl or phenylsulphonyl obtained by reaction of an epoxide of formula (II), where A and B have the above given meanings and L is a nucleophilic leaving group, with a) a 1, 2, 4-triazole (IIIa) and a molar equivalent of an inorganic base or b) 1,2,4-triazolide of formula (IIIb), (IIIa): Me = H, IIIb: alkali metal, in which Me = an alkali metal atom or a quaternary ammonium ion, in an aprotic, dipolar solvent, characterised in that, at the end of the reaction, the reaction solution is treated with a water-miscible co-solvent and the triazolylmethylepoxide isomers are fractionally precipitated with water.

    VERFAHREN ZUR HERSTELLUNG VON TRIAZOLYMETHYLOXIRANEN
    2.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON TRIAZOLYMETHYLOXIRANEN 有权
    用于生产TRIAZOLYMETHYLOXIRANEN

    公开(公告)号：EP1395579A1

    公开(公告)日：2004-03-10

    申请号：EP02740595.0

    申请日：2002-05-14

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： SANDER, Michael ,  NOACK, Rainer ,  KAISER, Reinhard

    IPC: C07D405/06

    CPC classification number: C07D249/08 ,  C07D231/12 ,  C07D233/56

    Abstract: The invention relates to a method for producing triazolyl methyl oxiranes of formula I wherein A and B are the same or different and independently represent C1-C4-alkyl, phenyl-C1-C2-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl, the phenyl radical being able to carry between one and three substituents selected from the group containing halogen, nitro, C1-C4-alkyl, C1-C4-alkoxy, phenoxy, amino, C1-C2-halogenalkyl or phenylsulfonyl. Said compounds are produced by converting an oxirane of formula II wherein A and B have the aforementioned designation, and L represents a leaving group which can be substituted in a nucleophilic manner, with a) 1,2,4-triazole (IIIa) and a molar equivalent of an inorganic base, or b) a 1,2,4-triazolide of formula IIIb wherein Me represents an alkali metal atom or a quaternary ammonium ion, in a dipolar aprotic solvent having an OH-acid compound content of less than 0.5 % and/or having an NH-acid compound content of less than 2.5 %.

    VERFAHREN ZUR HERSTELLUNG VON 1,2,4-TRIAZOLYLMETHYL-OXIRANEN
    6.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON 1,2,4-TRIAZOLYLMETHYL-OXIRANEN 有权
    用于生产1,2,4-三唑基甲基环氧乙烷

    公开(公告)号：EP1517906B1

    公开(公告)日：2007-03-28

    申请号：EP03760593.8

    申请日：2003-06-06

    Applicant: BASF Aktiengesellschaft

    Inventor： NOACK, Rainer ,  SANDER, Michael ,  HENNINGSEN, Michael

    IPC: C07D405/06

    CPC classification number: C07D249/08 ,  C07D231/12 ,  C07D233/56

    Abstract: The invention relates to a method for the production of 1,2,4-triazol-1-yl-methyl-oxiranes of formula (I) wherein A and B are the same or different and independently represent C1-C4-alkyl, phenyl-C1-C2-alkyl,. C3 --C6-cycloalkyl, C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl. The phenyl radical can contain 1 3 substituents selected form the group: halogen, nitro, C1-C4-alkyl, C1-C4-alkyloxy, phenoxy, amino, C1-C2-halogenalkyl or phenylsulfonyl, characterised in that a) an oxirane of formula (II) wherein A and B have the above mentioned meaning and L represents a nucleophilically substitutable leaving group which is reacted with 4-amino-1,2,4-triazol of formula (III), IV to form 4-amino-1,2,4-triazolium salts of formula (IV). The invention also relates to a method for the production of l,2,4-triazolylmethyl-oxiranes.

    VERFAHREN ZUR HERSTELLUNG VON TRIAZOLYMETHYLOXIRANEN
    7.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON TRIAZOLYMETHYLOXIRANEN 有权

    公开(公告)号：EP1395579B1

    公开(公告)日：2005-01-19

    申请号：EP02740595.0

    申请日：2002-05-14

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： SANDER, Michael ,  NOACK, Rainer ,  KAISER, Reinhard

    IPC: C07D405/06

    CPC classification number: C07D249/08 ,  C07D231/12 ,  C07D233/56

    Abstract: The invention relates to a method for producing triazolyl methyl oxiranes of formula I wherein A and B are the same or different and independently represent C1-C4-alkyl, phenyl-C1-C2-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl, the phenyl radical being able to carry between one and three substituents selected from the group containing halogen, nitro, C1-C4-alkyl, C1-C4-alkoxy, phenoxy, amino, C1-C2-halogenalkyl or phenylsulfonyl. Said compounds are produced by converting an oxirane of formula II wherein A and B have the aforementioned designation, and L represents a leaving group which can be substituted in a nucleophilic manner, with a) 1,2,4-triazole (IIIa) and a molar equivalent of an inorganic base, or b) a 1,2,4-triazolide of formula IIIb wherein Me represents an alkali metal atom or a quaternary ammonium ion, in a dipolar aprotic solvent having an OH-acid compound content of less than 0.5 % and/or having an NH-acid compound content of less than 2.5 %.

    Abstract translation: 本发明涉及用于制备式I的三唑基甲基环氧乙烷的方法，其中A和B相同或不同并且独立地表示C1-C4-烷基，苯基-C1-C2-烷基，C3-C6-环烷基，C3- 环烷基，四氢吡喃基，四氢呋喃基，二恶烷基或苯基，苯基可以带有1至3个选自卤素，硝基，C 1 -C 4烷基，C 1 -C 4烷氧基，苯氧基，氨基，C 1 -C 2 卤代烷基或苯基磺酰基。 所述化合物通过将式II的环氧乙烷（其中A和B具有上述名称）和L代表可以以亲核方式取代的离去基团与a）1,2,4-三唑（IIIa）和 摩尔当量的无机碱，或b）式IIIb的1,2,4-三唑化物，其中Me代表碱金属原子或季铵离子，在OH-酸化合物含量小于0.5的偶极非质子溶剂中 ％和/或具有小于2.5％的NH-酸化合物含量。

    VERFAHREN ZUR HERSTELLUNG VON 1,2,4-TRIAZOLYLMETHYL-OXIRANEN
    10.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON 1,2,4-TRIAZOLYLMETHYL-OXIRANEN 有权
    用于生产1,2,4-三唑基甲基环氧乙烷

    公开(公告)号：EP1517906A1

    公开(公告)日：2005-03-30

    申请号：EP03760593.8

    申请日：2003-06-06

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： NOACK, Rainer ,  SANDER, Michael ,  HENNINGSEN, Michael

    IPC: C07D405/06

    CPC classification number: C07D249/08 ,  C07D231/12 ,  C07D233/56

    Abstract: The invention relates to a method for the production of 1,2,4-triazol-1-yl-methyl-oxiranes of formula (I) wherein A and B are the same or different and independently represent C1-C4-alkyl, phenyl-C1-C2-alkyl,. C3 --C6-cycloalkyl, C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl. The phenyl radical can contain 1 3 substituents selected form the group: halogen, nitro, C1-C4-alkyl, C1-C4-alkyloxy, phenoxy, amino, C1-C2-halogenalkyl or phenylsulfonyl, characterised in that a) an oxirane of formula (II) wherein A and B have the above mentioned meaning and L represents a nucleophilically substitutable leaving group which is reacted with 4-amino-1,2,4-triazol of formula (III), IV to form 4-amino-1,2,4-triazolium salts of formula (IV). The invention also relates to a method for the production of l,2,4-triazolylmethyl-oxiranes.

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