公开(公告)号：EP1575908A1

公开(公告)日：2005-09-21

申请号：EP03785813.1

申请日：2003-12-13

申请人： BASF Aktiengesellschaft

发明人： SOHN, Martin ,  STROEFER, Eckhard ,  NEVEJANS, Filip ,  PENZEL, Ulrich ,  PALLASCH, Hans-Jürgen ,  VAN DEN ABEEL, Peter ,  DEBERDT, Filip ,  JACOBS, Jan D. ,  MACKENROTH, Wolfgang

IPC分类号： C07C263/20

CPC分类号： C07C263/10 ,  C07C263/20 ,  Y10S203/08 ,  C07C265/14

摘要： The invention relates to a method for producing isocyanates by reacting amines with phosgene in the presence of inert organic solvents inside a reactor and by subsequently processing the reaction mixture exiting the reactor. The invention is characterized in that the separating out of the solvent ensues in a two-step or multi-step, preferably two-step distillation process, and the solvent is separated out in a first apparatus under a pressure of 0.1 to 15 bar and in a second or other apparatuses under a pressure of 1 to 900 mbar. The condensation heat of the solvent vapor from the first apparatus is used for partially or completely vaporizing solvent in the second apparatus.

公开(公告)号：EP1575906A1

公开(公告)日：2005-09-21

申请号：EP03789264.3

申请日：2003-12-13

申请人： BASF Aktiengesellschaft

发明人： SOHN, Martin ,  STROEFER, Eckhard ,  NEVEJANS, Filip ,  PENZEL, Ulrich ,  PALLASCH, Hans-Jürgen ,  VAN DEN ABEEL, Peter ,  DEBERDT, Filip ,  JACOBS, Jan D. ,  MACKENROTH, Wolfgang

IPC分类号： C07C263/10 ,  B01D53/70 ,  C01B7/07

CPC分类号： C01B7/0731 ,  B01D53/002 ,  B01D2257/2045 ,  B01D2257/2064 ,  C01B7/0712 ,  C01B32/80 ,  C07C263/10 ,  Y02P20/154 ,  C07C265/14 ,  C07C265/12 ,  C07C265/10

摘要： The invention relates to a method for partially or completely separating a substance mixture consisting of hydrogen chloride and phosgene, optionally of solvents and optionally of low-boiling fractions and inert substances such as those that normally arise during the production of isocyanates by reacting amines with phosgene. The inventive method is characterized in that a partial or complete condensation of phosgene is firstly carried out followed by a distillation or stripping inside a column for removing the hydrogen chloride from the bottom product phosgene and lastly, a washing of the top product hydrogen chloride with the process solvent for absorbing the phosgene in the process solvent is carried out. A subsequent purification by means of adsorption on activated carbon or other appropriate methods can be used for removing solvent remnants.

公开(公告)号：EP1575904A1

公开(公告)日：2005-09-21

申请号：EP03789262.7

申请日：2003-12-13

申请人： BASF Aktiengesellschaft

发明人： SOHN, Martin ,  STROEFER, Eckhard ,  NEVEJANS, Filip ,  PENZEL, Ulrich ,  PALLASCH, Hans-Jürgen ,  LEUTHOLD, Rene ,  BRODHAGEN, Andreas ,  WÖLFERT, Andreas ,  MACKENROTH, Wolfgang ,  MAURER, Markus

IPC分类号： C07C263/10 ,  C07C265/14

CPC分类号： C07C263/10 ,  C07C265/14

摘要： The invention relates to a method for the continuous production of polyisocyanates by reaction of organic amines with phosgene, characterised in that the reaction occurs in at least three stages, whereby the first stage is in a mixing unit, the second stage in at least one residence time unit and the third stage in at least one material separating apparatus and the pressure in each subsequent stage is lower than in the previous stage.

公开(公告)号：EP1706370A1

公开(公告)日：2006-10-04

申请号：EP05700737.9

申请日：2005-01-07

申请人： BASF Aktiengesellschaft

发明人： KNÖSCHE, Carsten ,  SOHN, Martin ,  PENZEL, Ulrich ,  PALLASCH, Hans-Jürgen ,  GEORGI, Gunter ,  MACKENROTH, Wolfgang ,  SCHWARZ, Hans Volkmar ,  MAIXNER, Stefan ,  MOLZ, Gerald ,  STROEFER, Eckhard

IPC分类号： C07C209/84 ,  C07C211/50

CPC分类号： C07C209/84 ,  C07C211/50

摘要： The invention relates to a method for the distillative recovery of TDA from an educt flow containing TDA, high boilers, and low boilers in a partition column in which a partition is disposed in the longitudinal direction of the column so as to form a common upper column zone (2), a common bottom column zone (3), a feeding section (4) that encompasses a rectification section (5) and a stripping section (6), and a withdrawal section (7) encompassing a rectification section (9) and a stripping section (8). The inventive method comprises the following steps: A) the educt flow (13) is delivered to the feeding section (4) of the partition column (1); B) a low boiler fraction is discharged via the top (11) of the column; C) TDA is discharged via a lateral discharge point (14) located in the withdrawal section (7) of the partition column (1); D) a high boiler fraction is discharged via the bottom (12) of the column.

公开(公告)号：EP1474378B1

公开(公告)日：2005-09-07

申请号：EP03714720.4

申请日：2003-01-30

申请人： BASF Aktiengesellschaft

发明人： VANOPPEN, Dominic ,  SCHWAB, Ekkehard ,  VAN LAAR, Frederik ,  VOSS, Hartwig ,  OEHLENSCHLÄGER, Steffen ,  MACKENROTH, Wolfgang ,  MORGENSCHWEIS, Konrad ,  PENZEL, Ulrich ,  WEIDNER, Bernd

IPC分类号： C07C209/36 ,  C07C209/86

CPC分类号： C07C209/36 ,  C07C209/86 ,  C07C211/50 ,  C07C211/46

摘要： The invention relates to a method for producing amines by catalytically hydrogenating nitroaromatics and then separating the catalysts from the reaction mixture containing at least one aromatic amine and water. According to the inventive method, the catalysts are separated by means of membrane filtration which is carried out at a pressure of 5 to 50 bar on the side of the suspension, a difference in pressure between the side of the suspension and the side of the permeate of at least 0.3 bar, and a flow rate of 1 to 6 m/s on the side of the suspension.

公开(公告)号：EP0609253A1

公开(公告)日：1994-08-10

申请号：EP92920403.0

申请日：1992-09-24

申请人： BASF Aktiengesellschaft

发明人： KLEIN, Ulrich ,  NEUMANN, Ulrich ,  MACKENROTH, Wolfgang ,  RENZ, Guenter ,  KRIEG, Wolfgang ,  MACKENROTH, Christiane ,  BUSCHMANN, Ernst ,  DE KRAMER, Jacobus, Jan ,  MILLI, Roland

IPC分类号： C07C29 ,  A01N31 ,  A01N49 ,  C07C33 ,  C07C43

CPC分类号： C07C33/02 ,  C07C43/313 ,  C07C43/315 ,  Y02P20/55

摘要： Procédé de fabrication d'un mélange de 8E,10E-dodécadiènol (Ia), 8E,10Z-dodécadiènol (Ib), 8Z,10E-dodécadiènol (Ic) et 8Z,10Z-dodécadiènol (Id), H3C-CH=CH-CH=CH-(CH2)6-CH2-OH, (8E,10E = Ia), (8E,10Z = Ib), (8Z,10E = Ic), (8Z,10Z = Id) à partir de 1,8-octanediol (II), que l'on transforme, au moyen d'un agent d'halogénation, en (III): Hal-CH2-(CH2)6-CH2-OH, (III) étant ensuite mis à réagir avec (IV): H2C=CH-OR de manière à obtenir (V): Hal-CH2-(CH2)6-CH2-O-CH(CH3)-OR que l'on transforme en (VI): H3C-CH=CH-CH(OH)-(CH2)8-O-CH(CH3)-OR, par réaction avec l'aldéhyde crotonique, en présence de magnésium, et, à partir de (VI), en présence d'acide, on sépare en même temps le groupe inhibant alcoolique et on élimine la fonction hydroxy; nouveaux produits intermédiaires pour ce procédé de fabrication et procédé pour combattre la carpocapse Cydia pomonella, au moyen de ce mélange, selon la méthode de dysfonctionnement d'appariement.

公开(公告)号：EP1575905A1

公开(公告)日：2005-09-21

申请号：EP03789263.5

申请日：2003-12-13

申请人： BASF Aktiengesellschaft

发明人： SOHN, Martin ,  STROEFER, Eckhard ,  NEVEJANS, Filip ,  PENZEL, Ulrich ,  PALLASCH, Hans-Jürgen ,  SANDER, Michael ,  SCHWARZ, Hans, Volkmar ,  MACKENROTH, Wolfgang

IPC分类号： C07C263/10 ,  C07C263/20 ,  C07C265/14

CPC分类号： C07C263/20 ,  C07C263/10 ,  C07C265/14

摘要： The invention relates to a method for producing isocyanates by reacting amines with phosgene inside a reactor followed by separating the isocyanate out from the reaction mixture exiting the reactor and purifying this isocyanate. The invention is characterized in that the isocyanate is separated out and purified in a column with a top pressure of 1 to 950 mbar, preferably 5 to 50 mbar, particularly preferred 10 to 20 mbar, with a bottom temperature of 90 to 250 °C, preferably 120 to 170 °C, particularly preferred 130 to 150 °C, and that the pure isocyanate flow is withdrawn in liquid or gaseous form, preferably in a side-stream of the column.

公开(公告)号：EP1474378A1

公开(公告)日：2004-11-10

申请号：EP03714720.4

申请日：2003-01-30

申请人： BASF AKTIENGESELLSCHAFT

发明人： VANOPPEN, Dominic ,  SCHWAB, Ekkehard ,  VAN LAAR, Frederik ,  VOSS, Hartwig ,  OEHLENSCHLÄGER, Steffen ,  MACKENROTH, Wolfgang ,  MORGENSCHWEIS, Konrad ,  PENZEL, Ulrich ,  WEIDNER, Bernd

IPC分类号： C07C209/36 ,  C07C209/86

CPC分类号： C07C209/36 ,  C07C209/86 ,  C07C211/50 ,  C07C211/46

摘要： The invention relates to a method for producing amines by catalytically hydrogenating nitroaromatics and then separating the catalysts from the reaction mixture containing at least one aromatic amine and water. According to the inventive method, the catalysts are separated by means of membrane filtration which is carried out at a pressure of 5 to 50 bar on the side of the suspension, a difference in pressure between the side of the suspension and the side of the permeate of at least 0.3 bar, and a flow rate of 1 to 6 m/s on the side of the suspension.

摘要翻译： 本发明涉及一种通过催化氢化硝基芳族化合物制备胺的方法，然后从含有至少一种芳族胺和水的反应混合物中分离催化剂。 根据本发明的方法，催化剂借助膜过滤进行分离，膜过滤是在悬浮液侧5至50巴的压力下进行的，悬浮液侧与渗透液侧之间的压力差 为至少0.3巴，悬浮液侧的流速为1至6m / s。

公开(公告)号：EP0609253B1

公开(公告)日：1995-12-20

申请号：EP92920403.0

申请日：1992-09-24

申请人： BASF Aktiengesellschaft

发明人： KLEIN, Ulrich ,  NEUMANN, Ulrich ,  MACKENROTH, Wolfgang ,  RENZ, Guenter ,  KRIEG, Wolfgang ,  MACKENROTH, Christiane ,  BUSCHMANN, Ernst ,  DE KRAMER, Jacobus, Jan ,  MILLI, Roland

IPC分类号： C07C33/02 ,  C07C43/313 ,  C07C43/315 ,  C07C29/62 ,  C07C41/54 ,  C07C41/48 ,  C07C29/60

CPC分类号： C07C33/02 ,  C07C43/313 ,  C07C43/315 ,  Y02P20/55

摘要： A process is disclosed for preparing a mixture of 8E,10E-dodecadienol (Ia), 8E,10Z-dodecadienol (Ib), 8Z,10E-dodecadienol (Ic) and 8Z,10Z-dodecadienol (Id), H3C-CH=CH-CH=CH-(CH2)6-CH2-OH, (8E,10E = Ia), (8E,10Z = Ib), (8Z,10E = Ic), (8Z,10Z = Id) from 1,8-octandiol (II) which is transformed by a halogenating agent into (III): Hal-CH2-(CH2)6-CH2-OH, (III) is then reacted with (IV): H2C=CH-O-R, producing (V): Hal-CH2-(CH2)6-CH2-O-CH(CH3)-OR, which is transformed in the presence of magnesium with crotonaldehyde into (VI): H3C-CH=CH-CH(OH)-(CH2)8-O-CH(CH3)-OR. The alcohol protective group is split off from (VI) in the presence of an acid, at the same time as the hydroxyl function is eliminated. Also disclosed are intermediates for this process, and a process for fighting the fruit surface eating tortrix moth Cydia pomonella with this mixture according to the mating interruption method.

公开(公告)号：EP1841530A1

公开(公告)日：2007-10-10

申请号：EP05823051.7

申请日：2005-12-20

申请人： BASF AKTIENGESELLSCHAFT

发明人： DIALER, Harald ,  FRAUENKRON, Matthias ,  EVERS, Holger ,  SCHWAB, Ekkehard ,  MELDER, Johann-peter ,  ROSOWSKI, Frank ,  VAN LAAR, Frederik ,  ANDERS, Joachim-Thierry ,  CRONE, Sven ,  MACKENROTH, Wolfgang

IPC分类号： B01J23/885 ,  C07C209/02 ,  B01J23/76 ,  B01J27/24

CPC分类号： C07C209/02 ,  B01J23/755 ,  B01J23/76 ,  B01J23/885 ,  B01J23/8892 ,  B01J23/8933 ,  B01J23/94 ,  B01J27/24 ,  B01J27/28 ,  B01J37/03 ,  B01J37/04 ,  B01J38/08 ,  B01J38/18 ,  Y02P20/584 ,  C07C211/46

摘要： The invention relates to a method for the production of nitrogen-containing catalysts, comprising: a) production of an oxidic species containing the following components: at least one metal, M, selected from the groups Ib to VIIb and VIII of the periodic table of the elements, whereby the same metal may be present in different oxidation states, optionally one or more promoters, P, selected from the groups Ib to VIIb and VIII of the periodic table of the elements, lanthanides and groups IIIa to VIa of the periodic table of the elements, with the exclusion of oxygen and sulphur, optionally one or more elements, R, selected from hydrogen, alkaline metals and earth alkaline metals, optionally one or more elements Q, selected from chlorides and sulphates, oxygen, whereby the molar proportion of oxygen is determined by the valency and frequency of the elements other than oxygen in the oxidic species, b) reaction of the oxidic species with an amine component selected from ammonia, primary and secondary amines and ammonium salts, whereby the ammonium-containing catalyst is produced with generation of water and nitrogen-containing catalysts produced by said method. The invention further relates to a method for amination of hydrocarbons using said nitrogen-containing catalyst and the use of an oxidic species in a direct method for amination of hydrocarbons.