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    Hybrid compounds formed from ionic liquids and uses thereof in ion selective electrodes
    7.
    发明公开
    Hybrid compounds formed from ionic liquids and uses thereof in ion selective electrodes 审中-公开
    ，从离子液体的混合化合物制备和在离子选择性电极及其用途

    公开(公告)号：EP2995630A1

    公开(公告)日：2016-03-16

    申请号：EP14184047.0

    申请日：2014-09-09

    申请人： Dublin Institute of Technology ,  Keele University

    发明人： Schazmann, Benjamin ,  Radu, Aleksander

    IPC分类号： C08F8/48 ,  C08F8/30 ,  C08F14/06 ,  G01N27/333 ,  B01D71/82 ,  C08F114/06 ,  C08F8/26 ,  C09D127/22 ,  C07D233/58 ,  C07D295/037

    CPC分类号： C08F8/30 ,  C08F8/48 ,  G01N27/3335 ,  C08F8/26 ,  C08F114/06

    摘要： A hybrid compound is provided that is formed by reaction between (a) an imidazolium-based ionic liquid functionalised with an alkyne group and (b) a polymer backbone comprising a plurality of azide functional groups, via an azide-alkyne cycloaddition reaction. The hybrid compound comprises a synthetic polymer backbone comprising at least one functional group X of general formula (I):

    in which:
    R 1 to R 4 are each, independently, any chemical group, selected from H, halogen, a substituted or unsubstituted, branched or unbranched alkyl, alkenyl, cycloalkyl, aryl, acyl, heteroaryl, arylalkyl, heteroarylalkyl, aryloxy, alkyloxy, arylalkyloxy, aromatic polycycles, non-aromatic polycycles, mixed aryl and non-aryl polycycles, polyheteroaryl, non-aromatic polyheterocycles, mixed aryl and non-aryl polyheterocycles, and a pyridine group; L is a linker; and B ⊝ is an anion. An ion selective electrode (ISE) sensor of the type comprising an ion selective electrode and a reference electrode is also provided, wherein the ion selective electrode comprises a coating comprising a hybrid compound of the invention.

    摘要翻译： 本发明提供一种混合式化合物并通过间的反应形成的（a）与炔基和官能化咪唑鎓基的离子液体（b）的聚合物主链包含酸性官能团的复数，经由在叠氮化物 - 炔环加成反应。 的混合化合物包括合成聚合物主链，其包含（I）通式中的至少一个官能团X：其中R 1至R 4各自独立地是任何化学基团，选自H，卤素，substituiertem奥德unsubstituiertem选择 支链或无支链的烷基，烯基，环烷基，芳基，酰基，杂芳基，芳烷基，杂芳基烷基，芳氧基，烷氧基，芳基烷氧基，芳族多环，非芳香族多环，混合的芳基和非芳多环，多杂，非芳香族多杂环，混合的芳基 和非芳聚杂环，和吡啶基; L是连接基; 和B S是一个阴离子。 因此类型包括离子选择性电极和参考电极的的离子选择性电极（ISE）传感器设置，worin离子选择性电极包括涂层包含本发明的复合化合物。