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公开(公告)号：EP2545107A1
公开(公告)日：2013-01-16
申请号：EP11708023.4
申请日：2011-03-07
Applicant: BASF SE
Inventor： FERSTL, Wolfgang , GAO, Jun , HAHN, Klaus , HESSE, Pascal , HOLOCH, Jan , HUNGENBERG, Klaus-Dieter , HUSEMANN, Wolfram , JOVANOVIC, Renata , KASTEN, Wolfgang , KRIHA, Olaf , NEUFELD, Eckhard , PEPERS, Michel , REINHARD, Birgit , SCHMIED, Bernhard , SÜTTINGER, Rudolf , ZHANG, Ping
CPC classification number: C08F12/08 , C08F212/12 , C08J9/141 , C08J9/20 , C08J2325/06
Abstract: The invention relates to a method for producing expandable styrene polymers, which method comprises the following steps: (a) adding an aqueous phase containing a suspension stabilizer and an organic phase containing styrene and initiator to a reactor, (b) starting the addition of a blowing agent at a conversion rate of styrene in the range from 40 to 70% and addition of the blowing agent over a period of 30 to 60 minutes, (c) adding a stabilizer for stabilizing the bead size distribution of the expandable styrene polymer at a conversion rate of styrene in the range from 65 to 99%.
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公开(公告)号：EP2032609A1
公开(公告)日：2009-03-11
申请号：EP07729713.3
申请日：2007-05-31
Applicant: BASF SE
Inventor： KREBS, Thilo , HOLOCH, Jan , SCHMIED, Bernhard
CPC classification number: C08J9/20 , C08F112/08 , C08J2203/06 , C08J2203/14 , C08J2325/06 , C08F2/18
Abstract: A process for production of expandable styrene polymers with narrow bead-size distribution with high specific reactor yield via polymerization of the monomers in aqueous suspension in a stirred tank in the presence of a volatile blowing agent, where the styrene-containing organic phase is added simultaneously with the aqueous phase to the stirred tank over a period of from 5 to 60 minutes.
Abstract translation: 一种通过单体在含水悬浮液中在挥发性发泡剂存在下在搅拌槽中聚合而制备具有窄特定反应器产率的窄粒径分布的可发性苯乙烯聚合物的方法，其中含苯乙烯的有机相同时加入 与水相一起搅拌5至60分钟。
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3.发明公开VERFAHREN UND VORRICHTUNG ZUR GRANULIERUNG VON TREIBMITTELHALTIGEN POLYMERSCHMELZEN 有权方法和设备的发泡剂造粒含聚合物熔体
公开(公告)号：EP1998948A1
公开(公告)日：2008-12-10
申请号：EP07726931.4
申请日：2007-03-15
Applicant: BASF SE
Inventor： SCHMAUS, Paulus , HEEGER, Michael , RUCH, Joachim , HOLOCH, Jan , RASCH, Christian
CPC classification number: B29B9/065 , B29B9/16 , B29C44/3461
Abstract: The invention relates to a method and a device for granulating polymer melts containing blowing agent in a granular heating chamber, through which there flows a liquid at a pressure above ambient pressure. In a first step, the polymer melt is forced into the granulating chamber, in a second step the polymer melt is cut by a cutting device into individual granular grains and in a third step the granular grains produced in the granulation are discharged with the liquid from the granulating chamber and separated from the liquid. The method additionally comprises at least one of the following steps: (a) comminuting agglomerates or granular grains that exceed a predetermined maximum size, in a comminuting machine arranged downstream of the granulating chamber or in a comminuting unit arranged downstream of the cutting device, (b) allowing the liquid to expand in an expansion machine, (c) allowing the liquid to expand in a throttle device, a pressure equalizing tank being arranged upstream of the throttle device, (d) separating the granular grains from the liquid without previously allowing the liquid to expand with the granular grains contained in it.
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4.发明公开HOCHTEMPERATURPEROXID-HALTIGE STYROLPOLYMERISATPERLEN FÜR DIE SAATPOLYMERISATION 审中-公开高温含过氧化物的STYROLPOLYMERISATPERLEN用于种子聚合
公开(公告)号：EP2794739A1
公开(公告)日：2014-10-29
申请号：EP12806025.8
申请日：2012-12-17
Applicant: BASF SE
Inventor： SPIES, Patrick , HESSE, Pascal , SCHMIED, Bernhard , SEDA, Libor , OSTERMANN, Rainer , BRAUN, Frank , HAVERKEMPER, Gregor , LEHNEN, Uwe-Johannes , HAHN, Klaus , HOLOCH, Jan
CPC classification number: C08F112/08 , C08F4/34 , C08F12/08
Abstract: The invention relates to styrene polymer beads, characterized in that the styrene polymer beads contain 0.5 to 5 wt % of one or more high-temperature peroxides, wherein the high-temperature peroxides have a half-value period of one hour in the range of 110 to 160⁰C, measured in cumene.
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5.发明授权
公开(公告)号：EP2576674B1
公开(公告)日：2014-08-27
申请号：EP11722085.5
申请日：2011-05-31
Applicant: BASF SE
Inventor： HUSEMANN, Wolfram , LEHNEN, Uwe-Johannes , SPIES, Patrick , BREITSCHEIDEL, Boris , HAHN, Klaus , HOLOCH, Jan , KRIHA, Olaf , SCHMIED, Bernhard , HESSE, Pascal
IPC: C08J9/00
CPC classification number: C08J9/0023 , C08J2325/04
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Patent Agency Ranking
公开(公告)号：EP1998948B1
公开(公告)日：2010-11-03
申请号：EP07726931.4
申请日：2007-03-15
Applicant: BASF SE
Inventor： SCHMAUS, Paulus , HEEGER, Michael , RUCH, Joachim , HOLOCH, Jan , RASCH, Christian
CPC classification number: B29B9/065 , B29B9/16 , B29C44/3461
Abstract: The invention relates to a method and a device for granulating polymer melts containing blowing agent in a granular heating chamber, through which there flows a liquid at a pressure above ambient pressure. In a first step, the polymer melt is forced into the granulating chamber, in a second step the polymer melt is cut by a cutting device into individual granular grains and in a third step the granular grains produced in the granulation are discharged with the liquid from the granulating chamber and separated from the liquid. The method additionally comprises at least one of the following steps: (a) comminuting agglomerates or granular grains that exceed a predetermined maximum size, in a comminuting machine arranged downstream of the granulating chamber or in a comminuting unit arranged downstream of the cutting device, (b) allowing the liquid to expand in an expansion machine, (c) allowing the liquid to expand in a throttle device, a pressure equalizing tank being arranged upstream of the throttle device, (d) separating the granular grains from the liquid without previously allowing the liquid to expand with the granular grains contained in it.
Abstract translation: 本发明涉及一种用于造粒聚合物熔体的方法和设备，所述聚合物熔体在造粒室中包含发泡剂，液体通过所述发泡剂，其压力高于环境压力。 在第一步骤中，将聚合物熔体注射到造粒室中，在第二步骤中，聚合物熔体通过切割装置切割成单个颗粒，并且在第三步中，在造粒过程中产生的颗粒用液体 从造粒室中分离，然后与液体分离。 该方法还包括以下步骤中的至少一个：（a）在造粒室下游的粉碎机或切割装置下游的粉碎单元中粉碎团聚体或超过规定最大尺寸的颗粒，（b ）减压机中的液体的减压，（c）节流装置中的液体的减压，其中在节流装置的上游存在压力均衡容器，（d）颗粒与液体的分离，没有 任何现有的液体与其包含的颗粒的减压。
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公开(公告)号：EP1694753B1
公开(公告)日：2010-03-31
申请号：EP04803716.2
申请日：2004-12-10
Applicant: BASF SE
Inventor： HAHN, Klaus , EHRMANN, Gerd , RUCH, Joachim , ALLMENDINGER, Markus , SCHMIED, Bernhard , HOLOCH, Jan , MÜHLBACH, Klaus , RIETHUES, Michael
CPC classification number: C08J9/14 , C08J9/0061 , C08J9/141 , C08J2205/052 , C08J2325/08 , C08J2425/00 , C08J2453/00
Abstract: The invention relates to expanded particulate moulded parts with a density ranging between 10 and 100 g/l. Said parts are obtained by welding pre-expanded particulate consisting of expandable thermoplastic polymer granulates, the latter containing between 5 and 100 wt. % styrene copolymer A), between 0 and 95 wt. % polystyrene B) and between 0 and 95 wt. % thermoplastic polymer C) that differs from a) and b). The invention also relates to methods for producing the expandable thermoplastic polymer granulates.
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8.发明授权EXPANDIERBARE STYROLPOLYMERGRANULATE MIT BI- ODER MULTIMODALER MOLEKULARGEWICHTSVERTEILUNG 有权与BI或峰分子量分布的可膨胀苯乙烯聚合物细粒
公开(公告)号：EP1694755B1
公开(公告)日：2010-03-10
申请号：EP04803719.6
申请日：2004-12-10
Applicant: BASF SE
Inventor： HAHN, Klaus , EHRMANN, Gerd , RUCH, Joachim , ALLMENDINGER, Markus , SCHMIED, Bernhard , HOLOCH, Jan , DIETZEN, Franz-Josef
CPC classification number: C08J9/16 , C08J2201/03 , C08J2325/06 , C08L25/02 , C08L2205/02 , C08L2666/06
Abstract: The invention relates to expandable polystyrene granulates with at least a bi- or multi-modal molecular-weight distribution, to a method for producing said granulates and to their use in the production of expanded particulate moulded parts.
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9.发明公开
公开(公告)号：EP2576674A1
公开(公告)日：2013-04-10
申请号：EP11722085.5
申请日：2011-05-31
Applicant: BASF SE
Inventor： HUSEMANN, Wolfram , LEHNEN, Uwe-Johannes , SPIES, Patrick , BREITSCHEIDEL, Boris , HAHN, Klaus , HOLOCH, Jan , KRIHA, Olaf , SCHMIED, Bernhard , HESSE, Pascal
IPC: C08J9/00
CPC classification number: C08J9/0023 , C08J2325/04
Abstract: The invention relates to a composition containing at least one expandable styrene polymer component and at least one cyclohexane carboxylic acid ester, and optionally other components. Said composition can be processed to form mechanically loadable foams.
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公开(公告)号：EP1994085B1
公开(公告)日：2009-05-13
申请号：EP07712339.6
申请日：2007-02-27
Applicant: BASF SE
Inventor： EXNER, Christian , HOLOCH, Jan
CPC classification number: C08J9/0028 , C08J9/20 , C08J2203/02 , C08J2203/06 , C08J2203/14 , C08J2325/06
Abstract: A process for preparing expandable styrene polymers with narrow bead size distribution, which can be processed to foams with homogeneous cell structure and low thermal conductivity, by polymerizing the monomers in aqueous suspension in the presence of a volatile blowing agent and from 0.1 to 30 ppm, based on the organic phase, of a hydroxyalkylamine.
Abstract translation: 本发明涉及一种制备具有窄珠尺寸分布的可膨胀苯乙烯聚合物的方法，所述可膨胀苯乙烯聚合物可通过在存在挥发性发泡剂的情况下在含水悬浮液中聚合所述单体而被加工成具有均质泡孔结构和低导热率的泡沫， 基于有机相的羟烷基胺。
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