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6 条记录 (耗时 0.016 秒)

    AZAPERYLENES AS ORGANIC SEMICONDUCTORS
    5.
    发明授权
    AZAPERYLENES AS ORGANIC SEMICONDUCTORS 有权
    AZAPERYLENE有机半导体

    公开(公告)号：EP1880428B1

    公开(公告)日：2010-09-22

    申请号：EP06754974.1

    申请日：2006-05-03

    申请人： BASF SE

    发明人： BIENEWALD, Frank ,  SCHMIDHALTER, Beat ,  BERENS, Ulrich ,  KIRNER, Hans, Jürg

    IPC分类号： H01L51/00

    CPC分类号： C09B5/028 ,  C07D471/06 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0512 ,  H01L51/0541 ,  H01L51/5012 ,  Y10S428/93

    摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1 , R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH )3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11 )3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; X is O, S, NR8; Rδ is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, R11 being C1-C20-alkyl or -alkoxy.

    PROCESS FOR THE SYNTHESIS OF AMINE ETHERS FROM SECONDARY AMINO OXIDES
    6.
    发明授权
    PROCESS FOR THE SYNTHESIS OF AMINE ETHERS FROM SECONDARY AMINO OXIDES 有权
    用于生产胺醚继发胺氧化物

    公开(公告)号：EP1284966B1

    公开(公告)日：2010-03-17

    申请号：EP01945152.5

    申请日：2001-05-17

    申请人： BASF SE

    发明人： HAFNER, Andreas ,  KIRNER, Hans, Jürg ,  SCHWARZENBACH, Franz ,  VAN DER SCHAAF, Paul, Adriaan ,  NESVADBA, Peter

    IPC分类号： C07D211/94 ,  C07D405/12 ,  C07D401/12 ,  C08K5/3435 ,  C08F4/00 ,  C07D217/26 ,  C07D209/44 ,  C07D241/08

    CPC分类号： C07D401/14 ,  C04B35/632 ,  C07D209/44 ,  C07D211/94 ,  C07D217/26 ,  C07D241/08 ,  C07D401/12 ,  C07D405/12 ,  C08K5/3412

    摘要： An amine ether of formula (A) wherein a is 1 or 2; and when a is 1, E is E'; when a is 2, E is L; E' is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E' is a radical of formula (VII) as explained in claim 1; T' is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)-R22; or T' is C5-C12cycloalkyl; C5-C12cacloalkyl which is interrupted by at least one O or -NR18-; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or -NR18-; or T' is -C(G1)(G2)-T''; or C1-C18alkyl or C5-C12cycloalkyl substituted by F(I)T'' is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T'' and T' together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.