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    VERFAHREN ZUR HERSTELLUNG EINES MONO-N-ALKYL-PIPERAZINS
    2.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES MONO-N-ALKYL-PIPERAZINS 有权
    VERFAHREN ZUR HERSTELLUNG EINES单-N-烷基哌嗪

    公开(公告)号：EP2855443A1

    公开(公告)日：2015-04-08

    申请号：EP13726752.2

    申请日：2013-05-29

    Applicant: BASF SE

    Inventor： BOU CHEDID, Roland ,  MELDER, Johann-Peter ,  ABEL, Ulrich ,  DOSTALEK, Roman ,  STEIN, Bernd

    IPC: C07D295/088

    CPC classification number: C07D295/088 ,  B01J23/83 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  B01J2523/00 ,  C07D295/03 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/3706

    Abstract: The invention relates to a method for producing a mono-N-alkyl piperazine of formula (I), where R1 represents C1 - C5 alkyl or 2-(2-hydroxy-ethoxy) ethyl, by reacting diethanolamine (DEOA) of formula (II) with a primary amine of formula H
    2 N-R
    1 (III) in the presence of hydrogen and a catalyst moulded body. The reaction is carried out in the liquid phase at an absolute pressure ranging from 150 to 250 bar and the amination is carried out using a catalyst moulded body, the precursor of which can be produced according to a method in which (i) an oxidic material comprising copper oxide, aluminium oxide and lanthanum oxide is provided, (ii) powdered metallic copper and/or copper flakes and optionally graphite are added to the oxidic material, (iii) the mixture resulting from step (ii) is moulded into a moulded body. The oxidic material can be obtained by the simultaneous or successive precipitation of the components copper oxide, aluminium oxide and lanthanum oxide and by subsequent drying and calcination and the catalyst moulded body is calcined once again after the moulding process in step (iii).

    Abstract translation: 本发明涉及制备式（I）的单-N-烷基哌嗪的方法，其中R 1表示C 1 -C 5烷基或2-（2-羟基 - 乙氧基）乙基，通过使式（II）的二乙醇胺 ）与式H 2 N-R 1（III）的伯胺在氢和催化剂成型体的存在下反应来制备。 反应在150-250巴的绝对压力下在液相中进行，并且使用催化剂成型体进行胺化，其前体可以根据以下方法制备：（i）氧化物质 其包含氧化铜，氧化铝和氧化镧，（ii）将粉末状金属铜和/或铜片和任选的石墨加入氧化材料中，（iii）将由步骤（ii）得到的混合物模塑成模制体 。 氧化材料可以通过同时或连续沉淀氧化铜，氧化铝和氧化镧组分并随后干燥和煅烧而获得，并且在步骤（iii）中的模制过程之后将催化剂成型体再次煅烧。

    VERFAHREN ZUR HERSTELLUNG EINES MONO-N-ALKYL-PIPERAZINS
    3.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES MONO-N-ALKYL-PIPERAZINS 有权
    VERFAHREN ZUR HERSTELLUNG EINES单-N-烷基哌嗪

    公开(公告)号：EP2855442A1

    公开(公告)日：2015-04-08

    申请号：EP13724592.4

    申请日：2013-05-23

    Applicant: BASF SE

    Inventor： BOU CHEDID, Roland ,  MELDER, Johann-Peter ,  ABEL, Ulrich ,  DOSTALEK, Roman ,  STEIN, Bernd

    IPC: C07D295/088

    CPC classification number: C07D295/088 ,  C07D295/023 ,  C07D295/03

    Abstract: The invention relates to a method for producing a mono-N-alkyl piperazine of formula (I), where R
    1 represents C
    1 to C
    5 alkyl or 2-(2-hydroxy-ethoxy) ethyl, by reacting diethanolamine (DEOA) of formula (II) with a primary amine of formula H
    2 N-R
    1 (III) in the presence of hydrogen and a supported catalyst containing metal. The catalytically active mass of the catalyst, before reduction of the latter using hydrogen, contains oxygenic compounds of aluminum, copper, nickel and cobalt and between 0.2 and 5.0 wt. % oxygenic compounds of tin, calculated as SnO, and the reaction is carried out in the liquid phase at an absolute pressure ranging from 95 to 145 bar.

    Abstract translation: 本发明涉及制备式（I）的单-N-烷基哌嗪的方法，其中R 1表示C 1至C 5烷基或2-（2-羟基 - 乙氧基）乙基，通过使二乙醇胺（DEOA）与 （II）与式H 2 N-R 1（III）的伯胺在氢气和含金属的负载型催化剂存在下反应。 在使用氢气还原后，催化剂的催化活性物质包含铝，铜，镍和钴的含氧化合物以及0.2-5.0wt。 以SnO计算的锡的％氧化合物，并且反应在95至145bar的绝对压力下在液相中进行。

    VERFAHREN ZUR HERSTELLUNG EINES ZYKLISCHEN TERTIÄREN AMINS
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES ZYKLISCHEN TERTIÄREN AMINS 有权
    用于生产环胺第三纪

    公开(公告)号：EP2627644A1

    公开(公告)日：2013-08-21

    申请号：EP11767694.0

    申请日：2011-10-10

    Applicant: BASF SE

    Inventor： WIGBERS, Christof Wilhelm ,  MELDER, Johann-Peter ,  STEIN, Bernd ,  MEIßNER, Harald

    IPC: C07D295/023

    CPC classification number: C07D295/023

    Abstract: The invention relates to a method for producing a cyclic tertiary amine having the formula (I), in which A denotes a C
    4 -alkylene group, a C
    5 -alkylene group or a -(CH
    2 )
    2 -B-(CH
    2 )
    2 group, where B denotes oxygen (O) or a N-R
    1 group and R
    1 denotes C
    1 - to C
    5 -alkyl, aryl or C
    5 - to C
    7 -cycloalkyl, and the group R
    2 denotes linear or branched C
    2 - to C
    16 -alkyl, C
    5 - to C
    7 -cycloalkyl or C
    7 - to C
    20 -aralkyl, by reacting (i) an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) or aminoethylethanolamine having the formula (IIa), in which R
    1 is as stated above or denotes hydrogen (H), wherein in the amine I then R
    1 = R
    2 , with a primary or secondary alcohol R
    2 OH (III) in a reactor at a temperature ranging between 150 and 270ºC in the presence of a copper-containing heterogenous catalyst in the liquid phase.

    VERFAHREN ZUR HERSTELLUNG EINES AMINS
    9.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES AMINS 无效

    公开(公告)号：EP1999099A1

    公开(公告)日：2008-12-10

    申请号：EP07726838.1

    申请日：2007-03-13

    Applicant: BASF SE

    Inventor： EBERHARDT, Jan ,  HOFFER, Bram Willem ,  HAESE, Frank ,  MELDER, Johann-Peter ,  STEIN, Bernd ,  STANG, Michael ,  HILL, Thomas ,  SCHWAB, Ekkehard

    IPC: C07C209/26 ,  C07D295/02

    CPC classification number: C07C209/26 ,  C07C2601/14 ,  C07D295/023 ,  C07C211/35 ,  C07C211/08

    Abstract: A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, the catalyst being a coated catalyst which comprises at least one metal of Group VIII of the Periodic Table of the Elements as a hydrogenation metal and additionally a promoter on an oxidic support, at least 80% of the metal of Group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which corresponds to a maximum of 80% of the radius of the catalyst, calculated from the surface of the catalyst.

    Abstract translation: 一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属 元素周期表第VIII族作为氢化金属，另外在氧化载体上是促进剂，元素周期表第VIII族金属的至少80％存在于 催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。

    VERFAHREN ZUR ÜBERWACHUNG EINES REAKTORS FÜR EINE MEHRPHASENREAKTION
    10.
    发明公开
    VERFAHREN ZUR ÜBERWACHUNG EINES REAKTORS FÜR EINE MEHRPHASENREAKTION 审中-公开

    公开(公告)号：EP3922348A1

    公开(公告)日：2021-12-15

    申请号：EP20178862.7

    申请日：2020-06-09

    Applicant: BASF SE

    Inventor： ZIEGLER, Andreas Norbert ,  KLEINERT, Tobias ,  SCHREIBER, Michael ,  ZAHN, Volker Michael ,  STEIN, Bernd

    IPC: B01J19/00

    Abstract: Verfahren zur Überwachung eines Reaktors, in dem eine chemische Mehrphasenreaktion abläuft, bei der ein Gemisch mit mindestens einer Flüssigphase und darin ungelösten Gasblasen vorhanden ist, umfassend die Schritte
    (a) Erfassung von Messwerten ausgewählter Zustandsgrößen, die für die Bestimmung von Gasvolumina relevant sind,
    (b) Berechnung des Gesamtvolumens an ungelöstem Gas im Reaktor auf Basis der erfassten Messwerte,
    (c) Vergleich des berechneten Gesamtvolumens an ungelöstem Gas mit einem vorgegebenen Grenzwert, und
    (d) Einleiten von Sicherungsmaßnahmen, falls der vorgegebene Grenzwert überschritten wird.

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