公开(公告)号：EP1999099B1

公开(公告)日：2012-02-15

申请号：EP07726838.1

申请日：2007-03-13

Applicant: BASF SE

Inventor： EBERHARDT, Jan ,  HOFFER, Bram Willem ,  HAESE, Frank ,  MELDER, Johann-Peter ,  STEIN, Bernd ,  STANG, Michael ,  HILL, Thomas ,  SCHWAB, Ekkehard

IPC: C07C209/26 ,  C07D295/02

CPC classification number: C07C209/26 ,  C07C2601/14 ,  C07D295/023 ,  C07C211/35 ,  C07C211/08

Abstract: A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, the catalyst being a coated catalyst which comprises at least one metal of Group VIII of the Periodic Table of the Elements as a hydrogenation metal and additionally a promoter on an oxidic support, at least 80% of the metal of Group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which corresponds to a maximum of 80% of the radius of the catalyst, calculated from the surface of the catalyst.

Abstract translation: 一种通过醛和/或酮与氢和选自伯胺和仲胺的氮化合物在非均相催化剂存在下反应制备胺的方法，所述催化剂为包含至少一种 元素周期表第VIII族作为氢化金属和另外在氧化性载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于催化剂表面之间的层中 和从催化剂表面计算出的对应于最大为催化剂半径的80％的穿透深度。

公开(公告)号：EP1699751B1

公开(公告)日：2011-03-02

申请号：EP04804184.2

申请日：2004-12-22

Applicant: BASF SE

Inventor： MEIER, Anton ,  MELDER, Johann-Peter ,  GERLACH, Till ,  HAESE, Frank

IPC: C07C209/16 ,  C07C29/76 ,  C12P7/06

CPC classification number: B01J20/0233 ,  B01D15/00 ,  B01J8/0285 ,  B01J8/0292 ,  B01J20/0296 ,  B01J20/186 ,  B01J20/3204 ,  B01J20/3236 ,  B01J23/755 ,  C07C29/76 ,  C07C209/16 ,  Y02E50/17 ,  C07C211/05 ,  C07C31/08

Abstract: Process for preparing an ethylamine by reacting ethanol with ammonia, a primary amine or a secondary amine in the presence of hydrogen and a heterogeneous catalyst, in which a biochemically prepared ethanol (bioethanol) in which the concentration of sulfur and/or sulfur-containing compounds has been reduced beforehand by bringing it into contact with an adsorbent is used.

公开(公告)号：EP1968960B1

公开(公告)日：2010-05-26

申请号：EP06830698.4

申请日：2006-12-18

Applicant: BASF SE

Inventor： DITRICH, Klaus ,  HAESE, Frank

IPC: C07D295/02

CPC classification number: C07D295/027

Abstract: The invention relates to a method for producing optically active trans-2,6-dimethylmorpholine by (i) reacting racemic trans-2,6-dimethylmorpholine with D-mandelic acid, (ii) separating the formed salt from D-mandelic acid and the one enantiomer of the trans-2,6-dimethylmorpholine from the other enantiomer of the trans-2,6-dimethylmorpholine and (iii) isolating the desired optically active trans-2,6-dimethylmorpholine.

公开(公告)号：EP1539666B1

公开(公告)日：2009-01-07

申请号：EP03748014.2

申请日：2003-09-12

Applicant: BASF SE

Inventor： VOLLAND, Martin ,  AHLERS, Wolfgang ,  EBEL, Klaus ,  PACIELLO, Rocco ,  RÖPER, Michael ,  MACKEWITZ, Thomas ,  BÖHM, Volker ,  SAVA, Xavier ,  LÖBER, Oliver ,  BEY, Oliver ,  STEPHAN, Jürgen ,  HAESE, Frank

IPC: C07C45/50 ,  C07C47/21 ,  C07C47/12 ,  C07F9/6558

CPC classification number: C07F9/6596 ,  C07C45/50 ,  C07F9/5721 ,  C07F9/5728 ,  C07F9/65522 ,  C07F9/65586 ,  C07F9/65842 ,  C07F9/65848 ,  C07C47/12 ,  C07C47/21

Abstract: The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.

公开(公告)号：EP1999102A1

公开(公告)日：2008-12-10

申请号：EP07727106.2

申请日：2007-03-20

Applicant: BASF SE

Inventor： HAESE, Frank ,  MELDER, Johann-Peter ,  KRAUSE, Alfred ,  PAPE, Frank-Friedrich ,  STEIN, Bernd , 

IPC: C07C213/04 ,  C07C217/08 ,  B01D3/00

CPC classification number: C07C213/04 ,  B01J2219/00006 ,  C07C217/08

Abstract: A process for preparing N,N-dimethylaminoethoxyethanol (DMAEE), wherein a) dimethylamine and ethylene oxide are reacted, b) the resulting product mixture is separated by distillation from N,N-dimethylethanol-amine and DMAEE to obtain a DMAEE-containing fraction as a bottom stream and c) DMAEE is removed by distillation from the fraction obtained in (b).

公开(公告)号：EP1899291A1

公开(公告)日：2008-03-19

申请号：EP06777386.1

申请日：2006-06-21

Applicant: BASF SE

Inventor： HAESE, Frank ,  WULFF-DÖRING, Joachim ,  KÖHLER, Ulrich ,  GAA, Peter ,  PAPE, Frank-Friedrich ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: C07C209/18

CPC classification number: C07C209/18 ,  Y02P20/582 ,  C07C211/45

Abstract: Disclosed is a method for continuously producing a primary aromatic amine by reacting an adequate aromatic alcohol with ammonia in the presence of hydrogen and a heterogeneous catalyst at a temperature ranging from 80 to 350 °C. The catalytically active mass of the catalyst contains 90 to 99.8 wt. % of zirconium dioxide (ZrO2), 0.1 to 5.0 wt. % of oxygen-containing palladium compounds, and 0.1 to 5.0 wt. % of oxygen-containing platinum compounds before the catalyst is reduced with hydrogen.

公开(公告)号：EP1999102B1

公开(公告)日：2011-12-14

申请号：EP07727106.2

申请日：2007-03-20

Applicant: BASF SE

Inventor： HAESE, Frank ,  MELDER, Johann-Peter ,  KRAUSE, Alfred ,  PAPE, Frank-Friedrich ,  STEIN, Bernd , 

IPC: C07C213/04 ,  C07C217/08 ,  B01D3/00

CPC classification number: C07C213/04 ,  B01J2219/00006 ,  C07C217/08

Abstract: A process for preparing N,N-dimethylaminoethoxyethanol (DMAEE), wherein a) dimethylamine and ethylene oxide are reacted, b) the resulting product mixture is separated by distillation from N,N-dimethylethanol-amine and DMAEE to obtain a DMAEE-containing fraction as a bottom stream and c) DMAEE is removed by distillation from the fraction obtained in (b).

公开(公告)号：EP1791805B1

公开(公告)日：2011-10-12

申请号：EP05774100.1

申请日：2005-08-10

Applicant: BASF SE

Inventor： HAESE, Frank ,  MELDER, Johann-Peter ,  DOSTALEK, Roman ,  JULIUS, Manfred

IPC: C07C213/10 ,  C07C215/12

CPC classification number: C07C213/10 ,  C07C215/12

Abstract: The invention relates to a method for producing triethanolamine, according to which a phosphane or a phosphane-releasing compound is added to the triethanolamine.

公开(公告)号：EP1899291B1

公开(公告)日：2009-03-18

申请号：EP06777386.1

申请日：2006-06-21

Applicant: BASF SE

Inventor： HAESE, Frank ,  WULFF-DÖRING, Joachim ,  KÖHLER, Ulrich ,  GAA, Peter ,  PAPE, Frank-Friedrich ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: C07C209/18

CPC classification number: C07C209/18 ,  Y02P20/582 ,  C07C211/45

Abstract: Disclosed is a method for continuously producing a primary aromatic amine by reacting an adequate aromatic alcohol with ammonia in the presence of hydrogen and a heterogeneous catalyst at a temperature ranging from 80 to 350 °C. The catalytically active mass of the catalyst contains 90 to 99.8 wt. % of zirconium dioxide (ZrO2), 0.1 to 5.0 wt. % of oxygen-containing palladium compounds, and 0.1 to 5.0 wt. % of oxygen-containing platinum compounds before the catalyst is reduced with hydrogen.

公开(公告)号：EP1996543A1

公开(公告)日：2008-12-03

申请号：EP07726567.6

申请日：2007-03-01

Applicant: BASF SE

Inventor： HAHN, Thilo ,  HAESE, Frank ,  KÖHLER, Ulrich ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EBERHARDT, Jan

IPC: C07C249/02 ,  A61Q17/04 ,  A61K8/40 ,  A61K8/41

CPC classification number: C07C249/02 ,  C07C251/16

Abstract: Method of producing benzophenoneimine (BPI) of the general formula (I) in which R1 and R2 are C1- to C4-alkoxy, C1- to C2-alkylamine and C2- to C4-dialkylamine and m and n are integers from 0 to 5, and R1 and R2, independently of one another, may be identical or different, in which benzophenone (BP) of the general formula (II) in which R1, R2, m and n have the meanings given above, is reacted in ammonia and in the presence of titanium dioxide, where the titanium dioxide is essentially present in the anatase modification.