VERFAHREN ZUR HERSTELLUNG VON ALKYLKETENDIMEREN
    2.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON ALKYLKETENDIMEREN 有权
    用于生产烷基烯酮

    公开(公告)号:EP1453821B1

    公开(公告)日:2010-01-20

    申请号:EP02785395.1

    申请日:2002-11-19

    申请人: BASF SE

    IPC分类号: C07D315/00

    CPC分类号: C07D315/00

    摘要: The invention relates to a method for producing alkyl ketene dimers by reacting carboxylic acid chlorides with tertiary amines in a molar ratio of between 1: 1 and 1: 1.6 at temperatures of between 65 and 150 °C and with a residence time of between 1 and 30 mins in the absence of solvents. Said reaction partners are intensively mixed and the alkyl ketene dimers are separated from the reaction mixture.

    VERFAHREN ZUR HYDROLYSE VON VINYLCARBONSÄUREAMIDEINHEITEN ENTHALTENDEN POLYMEREN
    5.
    发明公开
    VERFAHREN ZUR HYDROLYSE VON VINYLCARBONSÄUREAMIDEINHEITEN ENTHALTENDEN POLYMEREN 有权
    乙烯基羧酰胺含聚合物的方法水解

    公开(公告)号:EP2346907A1

    公开(公告)日:2011-07-27

    申请号:EP09744405.3

    申请日:2009-11-02

    申请人: BASF SE

    IPC分类号: C08F8/12

    CPC分类号: C08F8/12 C08F126/06

    摘要: A process for hydrolyzing polymers containing vinylcarboxamide units by heating polymers containing vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer containing vinylcarboxamide units and an aqueous solution of an acid or base are supplied continuously to a tubular reactor under elevated pressure, and 0.05 to less than one equivalent of an acid or base is used per vinylcarboxamide equivalent, and the mixture is passed through the tubular reactor at a temperature of >100°C up to 250°C, decompressed and cooled.

    VERFAHREN ZUR HERSTELLUNG VON N-VINYLCARBONSÄUREAMIDEN
    9.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON N-VINYLCARBONSÄUREAMIDEN 有权
    工艺生产N-乙烯基羧

    公开(公告)号:EP2376426A1

    公开(公告)日:2011-10-19

    申请号:EP09764823.2

    申请日:2009-12-04

    申请人: BASF SE

    IPC分类号: C07C231/12 C07C233/03

    CPC分类号: C07C231/12 C07C233/03

    摘要: The invention relates to a method for producing N-vinylcarboxamides by pyrolyzing a compound of the formula (I), in which R and R
    1 stand for H or C
    1 to C
    6 alkyl, in the presence of solids that are doped with alkali metal or alkaline-earth metal ions under reduced pressure at a temperature of 330 to 750°C by splitting off hydrogen cyanide and cooling, separating, and isolating the reaction products, wherein a solid arranged in a tubular reactor is treated with a solution of an alkali metal and/or alkaline-earth metal base at a temperature in the range of 0 to 250°C, the solution is discharged, the remaining solvent, which adheres to the catalyst that can be obtained in such away, is evaporated, and afterwards the catalyst is heated to a temperature of at least 380°C in order to activate the catalyst.