公开(公告)号：EP1675885B1

公开(公告)日：2008-03-05

申请号：EP04809940.2

申请日：2004-10-13

申请人： Bayer MaterialScience LLC

发明人： ADKINS, Rick, L. ,  GUELCHER, Scott

IPC分类号： C08G65/26 ,  C08G18/48

CPC分类号： C08G18/635 ,  C08G18/283 ,  C08G18/485 ,  C08G18/636 ,  C08G18/7628 ,  C08G18/7657 ,  C08G65/2612 ,  C08G2101/00 ,  C08G2101/0008 ,  C08G2101/0083

摘要： This invention relates to ethylenically unsaturated macromers which contain reactive unsaturation, and to a process for preparing these ethylenically unsaturated macromers which container reactive unsaturation. The process of preparing these ethylenically unsaturated macromers comprises reacting a monofunctional compound which corresponds to a specific formula with at least one alkylene oxide, in the presence of at least one alkoxylation catalyst. The ethylenically unsaturated macromers correspond to the formula set forth herein. This invention also relates to preformed stabilizers comprising ethylenically unsaturated macromers, to a process for preparing these preformed stabilizers, to polymer polyols comprising these preformed stabilizers, and to a process of preparing these polymer polyols which comprise these preformed stabilizers. Polymer polyols comprising ethylenically unsaturated macromers and a process for their preparation are also described.

公开(公告)号：EP2622011A2

公开(公告)日：2013-08-07

申请号：EP11792771.5

申请日：2011-06-07

申请人： Bayer MaterialScience LLC ,  Bayer MaterialScience AG

发明人： ADKINS, Rick, L. ,  ENGLAND, Jiong ,  HAHN, Norbert

IPC分类号： C08K5/20 ,  C08K5/29 ,  C08F12/08 ,  C08F20/44 ,  C08F2/38

CPC分类号： C08G18/636 ,  C08F4/04 ,  C08F283/06 ,  C08F285/00 ,  C08G18/4072 ,  C08G18/632 ,  C08G2101/005 ,  C08G2101/0083 ,  C08L51/08 ,  C08L71/02 ,  C08L2205/05 ,  C08F212/08 ,  C08F220/44

摘要： This invention relates to nitrile-free azo initiators for the preparation of polymer polyols and to the polymer polyols prepared therefrom. These novel polymer polyols comprise a base polyol, a preformed stabilizer and at least one ethylenically unsaturated monomer, in the presence of at least one free-radical polymerization initiator comprising as azo compound that is free of nitrile groups, and optionally, a polymer control agent. The process of preparing these polymer polyols is a continuous process comprising free-radically polymerizing a base polyol, a preformed stabilizer, and at least one ethylenically unsaturated monomer, in the presence of at least one free-radical polymerization initiator comprising as azo compound that is free of nitrile groups, and optionally, a polymer control agent.

公开(公告)号：EP2838923A1

公开(公告)日：2015-02-25

申请号：EP13778806.3

申请日：2013-04-12

申请人： Bayer MaterialScience LLC

发明人： ENGLAND, Jiong ,  ADKINS, Rick, L. ,  NEAL, Brian, L. ,  GILL, William, A.

IPC分类号： C08F265/04 ,  C08F20/10 ,  C08F2/38 ,  C08G63/00 ,  C08G65/00

摘要： Preformed stabilizers useful for the production of low viscosity, high solids polymer polyols are produced by free-radical polymerization of: (a) at least one ethylenically unsaturated macromolecule or macromer with (b) at least three different ethylenically unsaturated monomers in the presence of (c) at least one free-radical polymerization initiator, and, optionally, (d) a liquid diluent, and, optionally, (e) a chain transfer agent.

摘要翻译： （a）至少一种烯键式不饱和大分子或大分子单体与（b）至少三种不同的烯键式不饱和单体在（ c）至少一种自由基聚合引发剂，和任选的（d）液体稀释剂，和任选的（e）链转移剂。

公开(公告)号：EP2791194A1

公开(公告)日：2014-10-22

申请号：EP12858031.3

申请日：2012-12-12

申请人： Bayer MaterialScience LLC

发明人： ADKINS, Rick, L. ,  NEAL, Brian, L.

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/28 ,  C08J9/00 ,  C08G101/00

CPC分类号： C08G18/4072 ,  C08F283/006 ,  C08G18/0876 ,  C08G18/3231 ,  C08G18/632 ,  C08G18/636 ,  C08G18/7621 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08F212/08 ,  C08F220/44

摘要： This invention relates to hybrid polymer polyols. These hybrid polymer polyols comprise the free-radical polymerization product of (A) a base polyol comprising (1) a polymer modified polyol selected from (a) dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl group containing compound and (b) polyisocyanate polyaddition polyols, and (2) optionally, a polyol having a functionality of 2 to 6 and an OH number of from 20 to 500; (B) optionally, a preformed stabilizer; and (C) one or more ethylenically unsaturated monomers, in the presence of (D) a free-radical polymerization initiator, and (E) optionally, a polymer control agent. The present invention also relates to a process for the preparation of these hybrid polymer polyols, foams prepared from these hybrid polymer polyols and to a process for the preparation of these foams.

公开(公告)号：EP1506165B1

公开(公告)日：2011-12-28

申请号：EP03726641.8

申请日：2003-05-05

申请人： Bayer MaterialScience LLC

发明人： ADKINS, Rick, L. ,  PARSONS, Harold, R.

IPC分类号： C07C265/12 ,  C07C265/14

CPC分类号： C07C265/14 ,  C07C265/12 ,  C07C2602/10 ,  C08G18/7614 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： The present invention relates to novel aromatic isocyanates obtained by partially hydrogenating naphthalene as well as the processes for preparing the same, and to their use as an isocyanate component in the production of polyurethanes.

公开(公告)号：EP1651594A2

公开(公告)日：2006-05-03

申请号：EP04778812.0

申请日：2004-07-21

申请人： Bayer MaterialScience LLC

发明人： SLACK, William, E. ,  ADKINS, Rick, L. ,  KEMP, Hersel, T., II

IPC分类号： C07C273/18 ,  C07C275/62 ,  C08G18/38

CPC分类号： C08G18/10 ,  C08G18/089 ,  C08G18/7831 ,  C08G18/808

摘要： This invention relates to stable liquid biuret modified toluene diisocyanates, prepolymers thereof, stable liquid biuret allophanate modified toluene diisocyanates, prepolymers thereof, and to processes for the preparation of these compositions. The stable liquid biuret modified toluene diisocyanates comprise a secondary amine based biuret modified TDI having an NCO,group content of about 12 to about 46% by weight.

公开(公告)号：EP1506165A1

公开(公告)日：2005-02-16

申请号：EP03726641.8

申请日：2003-05-05

申请人： Bayer MaterialScience LLC

发明人： ADKINS, Rick, L. ,  PARSONS, Harold, R.

IPC分类号： C07C265/12 ,  C07C265/14

CPC分类号： C07C265/14 ,  C07C265/12 ,  C07C2602/10 ,  C08G18/7614 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： The present invention relates to novel aromatic isocyanates obtained by partially hydrogenating naphthalene as well as the processes for preparing the same, and to their use as an isocyanate component in the production of polyurethanes.

摘要翻译： 本发明涉及通过部分氢化萘获得的新型芳族异氰酸酯及其制备方法，以及它们在制备聚氨酯中作为异氰酸酯组分的用途。