摘要:
A polyethylene composition and the use thereof, and a polyolefin microporous breathable film prepared therefrom. The polyethylene composition comprises a polyethylene matrix resin and a pore-forming agent, wherein the content of the pore-forming agent is 30-110 parts by weight on the basis of 100 parts by weight of the polyethylene matrix resin, the pore-foaming agent comprises maleic anhydride copolymer microspheres, a copolymer in the microsphere comprises a structural unit A from maleic anhydride, a structural unit B from a vinyl-containing comonomer M and an optional cross-linking structure unit from a cross-linking agent, and the average particle size of the maleic anhydride copolymer microspheres is 500-2000 nm. The polyethylene composition can be used for preparing a breathable film without using a coupling agent, a dispersing agent and/or a surfactant, and achieves uniform air permeability and a high water vapor transmission rate. The film can be used for breathable composite products such as sanitary products, medical products, and food packaging or building products.
摘要:
Disclosed are a flame-retardant antimicrobial agent, a preparation method therefor and the use thereof, and a flame-retardant antimicrobial thermoplastic resin composition. The flame-retardant antimicrobial agent is a polymer microsphere with the surface grafted thereof with a guanidine salt, wherein the polymer microsphere comprises a cross-linked structure composed of a structural unit A derived from maleic anhydride, a structural unit B derived from a monomer M, and a structural unit C derived from a cross-linking agent. The monomer M is selected from a C 4 -C 9 aliphatic olefin or a mixture thereof, and the guanidine salt comprises at least one guanidine salt having the property of flame resistance. The flame-retardant antimicrobial agent has both a good antimicrobial effect and a good flame-retardant effect, is an effective single-component multifunctional auxiliary, has a very good flame-retardant and antimicrobial efficiency, and also has a good dispersion, a good fluidity, and a low moisture absorption. A flame-retardant antimicrobial thermoplastic resin composition comprising the flame-retardant antimicrobial agent also has a good flame-retardant and antimicrobial performance and a good overall performance.
摘要:
The present invention provides a method for preparing polyolefin resin powder, comprising the following steps: a) heating a polyolefin resin to dissolve in an organic solvent with a solubility parameter smaller than or equal to that of the polyolefin resin to obtain a polyolefin resin solution; b) cooling the polyolefin resin solution, so that a solid precipitates out to obtain a solid-liquid mixture; c) optionally adding an additive to the solid-liquid mixture and mixing; d) performing solid-liquid separation and drying to obtain polyolefin resin powder for selective laser sintering, wherein the difference between the solubility parameter of the organic solvent and the solubility parameter of the polyolefin resin falls within 0-20% of the solubility parameter of the polyolefin resin. The polyolefin resin powder obtained in the present invention has good oxidation resistance and powder flowability, a moderate size, a smooth surface, a suitable bulk density, and appropriate dispersibility and particle size distribution. The polyolefin resin powder is especially applicable to a selective laser sintering method.
摘要:
Provided are a supported catalyst, a preparation method therefor and use thereof, and a method for the preparation of isobutylene from halomethane. The catalyst is characterized in that it comprises a carrier and a metallic active component supported on the carrier, wherein the metallic active component comprises zinc oxide and zinc halide. On the basis of the total amount of the catalyst, by weight content, the content of zinc oxide is 0.5%-20%, the content of zinc halide is 10%-50%, and the content of the support is 40%-88%. Compared with the prior art, the catalyst of the present invention can convert halomethane into isobutylene with a high selectivity. With the reaction for preparing of isobutylene by converting bromomethane according to the method of the present invention, the conversion of bromomethane is not less than 90% and the selectivity of isobutylene is not less than 80%.
摘要:
The present invention relates to a polymerizable phosphonate monomer and a preparation method therefor, a copolymer prepared and obtained from the polymerizable phosphonate monomer and a drilling fluid that uses the copolymer. The anion of the polymerizable phosphonic acid (salt) has a structure that is represented in the following formula (1), and the cation is at least one among hydrogen, a monovalent metal cation, a divalent metal cation, a trivalent metal cation, and a tetravalent metal cation. In addition, 1H NMR of the polymerizable phosphonic acid (salt) substantivelysubstantively has no peak at the chemical shift δ of 1.019. The preparation method for a polymerizable phosphonic acid (salt) monomer as provided in the present invention uses an organic solvent as the solvent of a reaction system, so that compared to a water solvent system, reaction efficiency is higher, less by-products are produced, and the separation of the obtained products is simpler. Moreover, the obtained product has higher purity, and thus a copolymer having higher molecular weight may be obtained, and the temperature and salt resistance of the drilling fluid can be improved.
摘要:
This invention relates to a composite oxide, production and use thereof as a methane selective oxidizing catalyst. The composite oxide has a composition as illustrated by the formula RhR x Mo y V z O ´-± , wherein the symbols are as defined in the specification. When used as a methane selective oxidizing catalyst, the present composite oxide provides a high methane conversion and a high selectivity to the aimed products.
摘要:
This invention relates to a composite oxide, production and use thereof as a methane selective oxidizing catalyst. The composite oxide has a composition as illustrated by the formula RhR x Mo y V z O δ-α , wherein the symbols are as defined in the specification. When used as a methane selective oxidizing catalyst, the present composite oxide provides a high methane conversion and a high selectivity to the aimed products.
摘要翻译:本发明涉及一种复合氧化物,其作为甲烷选择氧化催化剂的生产和应用。 复合氧化物具有由式RhR x Mo y V z O'-±所示的组成,其中符号如说明书中所定义。 当用作甲烷选择性氧化催化剂时,本发明复合氧化物提供高甲烷转化率和对目标产物的高选择性。