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1.发明公开PROCEDE DE FORMATION D'UN FILM POLYMERE SUR UNE SURFACE CONDUCTRICE OU SEMI-CONDUCTRICE DE L'ELECTRICITE PAR ELECTRO-GREFFAGE, SURFACES OBTENUES ET APPLICATIONS 有权进行培训聚合物膜上的导电或半导电区域的方法BY电接枝，GOT SURFACES及其用途
公开(公告)号：EP1687463A1
公开(公告)日：2006-08-09
申请号：EP04787470.6
申请日：2004-09-28
发明人： BUREAU, Christophe , GONZALEZ, José , DENIAU, Guy
CPC分类号： C09D5/4476 , C25D9/02 , Y10T428/265
摘要： The invention relates to a method for forming a polymer film on a surface that conducts or semiconducts electricity by means of electrografting. Said method uses an electrolytic solution containing a selected quantity of Brönsted acid. The invention also relates to the electrically conductive or semiconductive surfaces obtained by means of said method.
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2.发明公开FORMATION DE FILMS ULTRAMINCES GREFFES SUR DES SURFACES CONDUCTRICES OU SEMI-CONDUCTRICES DE L'ELECTRICITE 审中-公开超薄薄膜上的电导体或半导体SURFACES的形成接枝
公开(公告)号：EP1859081A2
公开(公告)日：2007-11-28
申请号：EP06726076.0
申请日：2006-03-13
发明人： DENIAU, Guy , PALACIN, Serge
CPC分类号： C25D9/02 , Y10T428/26 , Y10T428/265 , Y10T428/31855
摘要： The invention relates to the use of organic precursors comprising an electroattractive group for the formation, by means of electrochemical grafting, of a uniform organic film, preferably having a thickness of less than or equal to 10nm, on an electrically-conducting or semiconducting surface. The invention also relates to the corresponding method of forming a uniform ultra-thin organic film on an electrically-conducting or semiconducting surface.
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公开(公告)号：EP1543080B1
公开(公告)日：2010-03-03
申请号：EP03773827.5
申请日：2003-08-25
发明人： BUREAU, Christophe , DENIAU, Guy , PALACIN, Serge
CPC分类号： C09D5/4476 , Y10T29/49126 , Y10T29/49128 , Y10T29/49165
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4.发明公开PROTHESES BIOACTIVES A PROPRIETES IMMUNOSUPPRESSIVES, ANTISTENOSE ET ANTITHROMBOSE 有权生物活性移植材料由导电用聚合物，有免疫抑制，ANTISTENOSEN及抗血栓性的物质COATED
公开(公告)号：EP1131113A1
公开(公告)日：2001-09-12
申请号：EP99972115.2
申请日：1999-11-15
申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE , INSTITUT NATIONAL DE LA SANTE ET DE LARECHERCHE MEDICALE (INSERM) , Justus-Liebig- Universitat Giessen
发明人： LE MOEL, Alain , BETZ, Natacha , BUREAU, Christophe , DENIAU, Guy , BAQUEY, Charles , DELERIS, Gérard , HABERBOSCH, Werner
CPC分类号： A61L33/0029 , A61F2/06 , A61F2/82 , A61L27/28 , A61L27/34 , A61L27/54 , A61L2300/258 , A61L2300/406 , A61L2300/41 , A61L2300/416 , A61L2300/42 , A61L2400/18
摘要： The invention concerns a bioactive prosthesis comprising a support coated with a polymer layer with reactive functions, and a bioactive substance fixed on the prosthesis via said reactive functions so as to be gradually released on a site for implanting the prosthesis. Such prostheses are useful in the field of cardiology to avoid for example restenosis resulting from implantation of stents in coronary arteries.
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5.发明公开PROCEDE DE FIXATION DE MACRO-OBJETS SUR UNE SURFACE CONDUCTRICE OU SEMI-CONDUCTRICE DE L ELECTRICITE PAR ELECTRO-GREFFAGE, SURFACES OBTENUES ET APPLICATIONS 有权PROCEDURE宏观物体的一个电导体或半导体区域通过电接枝杀青，获得的区域及其用途
公开(公告)号：EP1490444A1
公开(公告)日：2004-12-29
申请号：EP03738176.1
申请日：2003-03-19
CPC分类号： C09D5/4476 , Y10T29/49126 , Y10T29/49128 , Y10T29/49165 , Y10T428/12493
摘要： The invention relates to a method of fixing macro-objects to an electricity conducting- or semi-conducting surface by means of electrografting. The invention also relates to the electricity conducting- or semi-conducting-surfaces obtained using the aforementioned method and to the applications of same.
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6.发明公开PROCÉDÉ DE PRÉPARATION D'UN FILM ORGANIQUE À LA SURFACE D'UN SUPPORT SOLIDE DANS DES CONDITIONS NON-ÉLECTROCHIMIQUES, SUPPORT SOLIDE AINSI OBTENU ET KIT DE PRÉPARATION 有权方法制备有机薄膜上的固体基质在非电化学条件的表面，因此硬质和基质HERSTELLUNGSSET
公开(公告)号：EP2121814A2
公开(公告)日：2009-11-25
申请号：EP07871969.7
申请日：2007-12-19
发明人： MEVELLEC, Vincent , ROUSSEL, Sébastien , PALACIN, Serge , BERTHELOT, Thomas , BAUDIN, Cécile , TRENGGONO, Adhitya , DENIAU, Guy
IPC分类号： C08J5/18 , C09D4/00 , C09D133/00 , C09D139/08 , C08F2/38 , C08J5/24 , C08J7/12 , B05D7/00 , B05D3/12 , B82B3/00
CPC分类号： C09D4/00 , B82Y30/00 , C08J7/02 , C08J7/04 , C23C18/04 , C23C18/08 , C23C18/14 , C23C18/28 , C23C18/31 , H01L51/0006 , H01L51/0021 , H01L51/0075 , Y10T428/31616 , Y10T428/31681
摘要： The present invention relates to a method for preparing an organic film at the surface of a solid substrate, comprising a step of contacting said surface with a liquid solution containing (i) at least one solvent, at least one adhesion primer in non-electrochemical conditions and for generating radicalar entities from the adhesion primer. The liquid solution may further include (iii) at least one monomer different from the adhesion primer and polymerisable in a radicalar manner. The present invention also relates to an electrically non-conductive solid substrate on which an organic film is grafted according to said method, and to a kit for preparing an essentially polymeric organic film at the surface of the solid substrate.
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7.发明公开PROCEDE DE FORMATION DE FILMS ORGANIQUES SUR DES SURFACES CONDUCTRICES OU SEMI-CONDUCTRICES DE L'ELECTRICITE A PARTIR DE SOLUTIONS AQUEUSES 有权法有关电气导电或半导电表面上形成的水溶液的有机BASIS层形成
公开(公告)号：EP1989345A1
公开(公告)日：2008-11-12
申请号：EP07731040.7
申请日：2007-02-26
发明人： DENIAU, Guy , PALACIN, Serge
IPC分类号： C25D13/08
CPC分类号： C25D9/02 , C08F2/24 , C09D133/08 , C25D13/08
摘要： The present invention relates to the field of surface coatings, said coatings being in the form of organic films. It relates more particularly to a method of forming copolymeric organic films by electrochemical grafting onto electrically conducting or semiconducting surfaces from aqueous electrolyte solutions containing at least one protic solvent, at least one radical polymerization initiator soluble in the protic solvent, at least one radical-polymerizable monomer, and at least one surfactant. The invention also relates to the surfaces obtained by implementing this method, to their applications, in particular for the preparation of microelectronic components, biomedical devices or screen kits, and also to the electrolyte solution employed during the method.
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8.发明授权PROCEDE DE FORMATION D'UN FILM POLYMERE SUR UNE SURFACE CONDUCTRICE OU SEMI-CONDUCTRICE DE L'ELECTRICITE PAR ELECTRO-GREFFAGE, SURFACES OBTENUES ET APPLICATIONS 有权进行培训聚合物膜上的导电或半导电区域的方法BY电接枝，GOT SURFACES及其用途
公开(公告)号：EP1687463B1
公开(公告)日：2007-04-25
申请号：EP04787470.6
申请日：2004-09-28
发明人： BUREAU, Christophe , GONZALEZ, José , DENIAU, Guy
CPC分类号： C09D5/4476 , C25D9/02 , Y10T428/265
摘要： The invention relates to a method for forming a polymer film on a surface that conducts or semiconducts electricity by means of electrografting. Said method uses an electrolytic solution containing a selected quantity of Brönsted acid. The invention also relates to the electrically conductive or semiconductive surfaces obtained by means of said method.
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9.发明授权PROTHESES BIOACTIVES EN MATERIAU CONDUCTEUR REVETU D'UN POLYMERE ET D'UNE SUBSTANCE A PROPRIETES IMMUNOSUPPRESSIVES, ANTISTENOSE ET ANTITHROMBOSE 有权生物活性移植材料由导电用聚合物，有免疫抑制，ANTISTENOSEN及抗血栓性的物质COATED
公开(公告)号：EP1131113B1
公开(公告)日：2005-07-20
申请号：EP99972115.2
申请日：1999-11-15
申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE , INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE MEDICALE (INSERM) , Kerckhoff-Klinik GmbH
发明人： LE MOEL, Alain , BETZ, Natacha , BUREAU, Christophe , DENIAU, Guy , BAQUEY, Charles , DELERIS, Gérard , HABERBOSCH, Werner
CPC分类号： A61L33/0029 , A61F2/06 , A61F2/82 , A61L27/28 , A61L27/34 , A61L27/54 , A61L2300/258 , A61L2300/406 , A61L2300/41 , A61L2300/416 , A61L2300/42 , A61L2400/18
摘要： The invention concerns a bioactive prosthesis comprising a support coated with a polymer layer with reactive functions, and a bioactive substance fixed on the prosthesis via said reactive functions so as to be gradually released on a site for implanting the prosthesis. Such prostheses are useful in the field of cardiology to avoid for example restenosis resulting from implantation of stents in coronary arteries.
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公开(公告)号：EP1543080A2
公开(公告)日：2005-06-22
申请号：EP03773827.5
申请日：2003-08-25
发明人： BUREAU, Christophe , DENIAU, Guy , PALACIN, Serge
CPC分类号： C09D5/4476 , Y10T29/49126 , Y10T29/49128 , Y10T29/49165
摘要： The invention relates to a method of coating a simple or complex, conducting or semiconducting surface with an organic film using at least one precursor of said organic film. The invention is characterised in that the surface is coated with the organic film through the initiated electro-grafting of said at least one precursor onto the surface by performing at least one potential scanning on the surface such that, at every point of the surface, the maximum potential of each scanning of potentials, in absolute value and in relation to a reference electrode, is greater than or equal to the potential value (Vbloc) from which the curves of a graphic representation, expressing the quantity of electro-grafted precursor on a surface identical to said surface according to the number of potential scannings, all overlap and are independent of potential Vbloc.
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