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公开(公告)号：EP2621978A1
公开(公告)日：2013-08-07
申请号：EP11761812.4
申请日：2011-09-23
Applicant: CYTEC TECHNOLOGY CORP.
Inventor： GUPTA, Ram, B. , FLOOD, Lawrence, A. , TREASURER, Urvee, Y , LAWLESS, Barry, A. , BROGAN, Colin
CPC classification number: C08L61/24 , C08G8/10 , C08G12/10 , C08G12/12 , C08G12/30 , C08G12/40 , C08G16/0256 , C08G16/0268 , C08K5/29 , C08K5/34 , C08L61/06 , C08L61/22 , C08L61/26 , C08L61/30
Abstract: The invention relates to a crosslinker composition comprising a reaction product of a cyclic urea U and a multifunctional aliphatic aldehyde A , and at least one crosslinker selected from the group consisting of reaction products of an aminotriazine and at least one aldehyde selected from the group consisting of aliphatic monoaldehydes and multifunctional aliphatic aldehydes having the structure Y(CHO) n , where Y is an n-functional aliphatic residue, and n is greater than 1; reaction products of urea and/or cyclic ureas and aliphatic monoaldehydes; alkoxycarbonylaminotriazines; multifunctional isocyanates which may be partially or completely blocked; reaction products of phenols and aliphatic monoaldehydes; multifunctional epoxides; multifunctional aziridines; and multifunctional carbodiimides, wherein any of the crosslinkers which have hydroxyl groups may be etherified with one or more linear, branched, or cyclic aliphatic alcohols.
Abstract translation: 本发明涉及一种交联剂组合物，其包含环脲U和多官能脂族醛A的反应产物和至少一种选自以下的交联剂：氨基三嗪和至少一种选自以下的醛的反应产物： 具有结构Y（CHO）n的脂肪族单醛和多官能脂族醛，其中Y是N-官能脂族残基，n大于1; 脲和/或环脲和脂族单醛的反应产物; alkoxycarbonylaminotriazines; 可能部分或完全封闭的多官能异氰酸酯; 苯酚和脂肪族单醛的反应产物; 多功能环氧化物; 多功能氮丙啶; 和多官能碳化二亚胺，其中任何具有羟基的交联剂可以与一种或多种直链，支链或环状脂族醇醚化。
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2.发明公开
公开(公告)号：EP2621977A1
公开(公告)日：2013-08-07
申请号：EP11764932.7
申请日：2011-09-23
Applicant: CYTEC TECHNOLOGY CORP.
Inventor： GUPTA, Ram, B. , FLOOD, Lawrence, A. , TREASURER, Urvee, Y. , LAWLESS, Barry, A. , BROGAN, Colin
CPC classification number: C09D133/02 , C08G12/12 , C08G12/36 , C09D161/24
Abstract: The invention relates to a coating composition comprising a reaction product UA of at least one multifunctional aldehyde A with at least one cyclic urea U, and a crosslinkable resin having at least one kind of functional groups selected from the group consisting of hydroxyl functional groups, acid functional groups, amide functional groups, amino functional groups, imino functional groups, mercaptan functional groups, phosphine functional groups, and carbamate functional groups, characterised in that the degree of etherification, measured as the ratio «(-0-R) / «(U) of the amount of substance n(-O-R) of alkoxy groups as substituents of the aldehyde carbon atoms of the multifunctional aldehyde chemically bound in the reaction product UA to the amount of substance «(U) of cyclic urea U chemically bound in the reaction products, is less than 0.01 mol/mol, and to a process for the preparation of the reaction product UA.
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3.发明公开PROCESS FOR THE PREPARATION OF A REACTION PRODUCT OF A CYCLIC UREA AND A MULTIFUNCTIONAL ALDEHYDE 审中-公开用于生产循环尿素和多功能醛的反应产物
公开(公告)号：EP2621975A1
公开(公告)日：2013-08-07
申请号：EP11761813.2
申请日：2011-09-23
Applicant: CYTEC TECHNOLOGY CORP.
Inventor： GUPTA, Ram, B. , FLOOD, Lawrence, A. , TREASURER, Urvee, Y. , LAWLESS, Barry, A. , BROGAN, Colin
CPC classification number: C09D167/02 , C08G12/12 , C08G12/26 , C08G12/36 , C09D161/24
Abstract: This invention relates to a process to make a reaction product UA of at least one multifunctional aldehyde A with at least one cyclic urea U, by mixing the at least one multifunctional aldehyde A with the at least one cyclic urea U in the presence of at least one alcohol R 1 -OH, and optionally, at least one solvent that has no reactive groups which may react with aldehyde groups, -CO-NH- groups, or hydroxyl groups, to effect an addition reaction to obtain a solution of a product UA, where R 1 is selected from the group consisting of linear, branched or cyclic alkyl groups having from one to twelve carbon atoms, to the reaction product obtained by this process, and to a method of use thereof as crosslinker for coating compositions.
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公开(公告)号：EP2220152A1
公开(公告)日：2010-08-25
申请号：EP08857154.2
申请日：2008-12-05
Applicant: CYTEC TECHNOLOGY CORP.
Inventor： FLOOD, Lawrence, A. , LAWLESS, Barry, A.
IPC: C08K3/38 , C08L61/26 , C08L61/32 , C09D161/26 , C09D161/32
CPC classification number: C08G14/08 , C09D161/34 , C09D167/08 , C08L2666/16
Abstract: This invention is directed to a process for the preparation of a crosslinker composition, comprising the steps of providing a mixture of an aliphatic alcohol A having at least one hydroxyl group and from 1 to 10 carbon atoms, with at least one multifunctional aldehyde C having at least two aldehyde groups -CHO to form a mixture AC, heating the mixture AC to convert at least a part of the multifunctional aldehyde C to its hemiacetal or to its acetal to form a mixture (AC)', adding to the mixture (AC)' least one cyclic urea U or the educts to produce the said cyclic urea U in situ, which cyclic urea U has at least one unsubstituted >NH group, and reacting the mixture thus obtained to form a chemical bond between the nitrogen atom of the at least one unsubstituted >NH group of the at least one cyclic urea U5 and the carbon atom of the least one aldehyde group -CHO of the multifunctional aldehyde C, and coating compositions comprising the said crosslinker composition.
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Patent Agency Ranking
公开(公告)号：EP0851893B1
公开(公告)日：2000-07-05
申请号：EP96931620.7
申请日：1996-09-17
Applicant: Cytec Technology Corp.
Inventor： ZHAO, Hong , LAWLESS, Barry, A. , LEES, Robert, G.
IPC: C08K5/3492 , C08K5/3445 , C07D251/64 , C07D251/18 , C07D487/04
CPC classification number: C07D487/04 , C07D251/48 , C07D251/64 , C08G12/26 , C08K5/3445 , C08K5/34922
Abstract: The present invention relates to N-1,2,2-trihydrocarbyloxyethyl derivatives of certain amino compounds, which derivatives are particularly suitable for use as crosslinking agents in curable compositions such as coatings, and which derivatives do not release formaldehyde as a volatile by-product during cure. Processes for preparing such derivatives, curable compositions based thereon as well as various specific uses thereof are also disclosed.
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公开(公告)号：EP0832143A1
公开(公告)日：1998-04-01
申请号：EP96917220.0
申请日：1996-06-05
Applicant: Cytec Technology Corp.
Inventor： BRIGHT, John, H. , LAWLESS, Barry, A. , LEES, Robert, G. , LIN, Lon-Tang, Wilson , SZITA, Jeno, G.
CPC classification number: C08G12/42 , C08G12/38 , C09D161/28 , C09D161/32
Abstract: Described is a liquid, partially alkoxymethylated melamine cross-linker composition having from about 2.6 to about 4.6 moles of combined formaldehyde per mole of melamine, from about 1.4 to about 4.4 moles of alkyl per mole of melamine, from about 1.3 to about 3.4 moles of NH per mole of melamine, a free formaldehyde level of less than about 0.5 weight percent based on 100 percent solids, and an N-methylol level of less than about 6.0 weight percent; processes for its preparation; a low formaldehyde emitting curable composition containing the cross-linker; as well as a method of coating a substrate and substrates so coated.
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公开(公告)号：EP2220152B1
公开(公告)日：2012-07-04
申请号：EP08857154.2
申请日：2008-12-05
Applicant: CYTEC TECHNOLOGY CORP.
Inventor： FLOOD, Lawrence, A. , LAWLESS, Barry, A.
IPC: C08G14/08 , C09D161/34 , C09D167/08 , C08K3/38 , C08L61/26 , C08L61/32 , C09D161/26 , C09D161/32
CPC classification number: C08G14/08 , C09D161/34 , C09D167/08 , C08L2666/16
Abstract: This invention is directed to a process for the preparation of a crosslinker composition, comprising the steps of providing a mixture of an aliphatic alcohol A having at least one hydroxyl group and from 1 to 10 carbon atoms, with at least one multifunctional aldehyde C having at least two aldehyde groups -CHO to form a mixture AC, heating the mixture AC to convert at least a part of the multifunctional aldehyde C to its hemiacetal or to its acetal to form a mixture (AC)', adding to the mixture (AC)' least one cyclic urea U or the educts to produce the said cyclic urea U in situ, which cyclic urea U has at least one unsubstituted >NH group, and reacting the mixture thus obtained to form a chemical bond between the nitrogen atom of the at least one unsubstituted >NH group of the at least one cyclic urea U5 and the carbon atom of the least one aldehyde group -CHO of the multifunctional aldehyde C, and coating compositions comprising the said crosslinker composition.
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公开(公告)号：EP0832143B1
公开(公告)日：1999-01-27
申请号：EP96917220.4
申请日：1996-06-05
Applicant: Cytec Technology Corp.
Inventor： Bright, John H. , LAWLESS, Barry, A. , LEES, Robert, G. , LIN, Lon-Tang, Wilson , SZITA, Jeno, G.
IPC: C08G12/42
CPC classification number: C08G12/42 , C08G12/38 , C09D161/28 , C09D161/32
Abstract: Described is a liquid, partially alkoxymethylated melamine cross-linker composition having from about 2.6 to about 4.6 moles of combined formaldehyde per mole of melamine, from about 1.4 to about 4.4 moles of alkyl per mole of melamine, from about 1.3 to about 3.4 moles of NH per mole of melamine, a free formaldehyde level of less than about 0.5 weight percent based on 100 percent solids, and an N-methylol level of less than about 6.0 weight percent; processes for its preparation; a low formaldehyde emitting curable composition containing the cross-linker; as well as a method of coating a substrate and substrates so coated.
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公开(公告)号：EP0851893A1
公开(公告)日：1998-07-08
申请号：EP96931620.0
申请日：1996-09-17
Applicant: Cytec Technology Corp.
Inventor： ZHAO, Hong , LAWLESS, Barry, A. , LEES, Robert, G.
CPC classification number: C07D487/04 , C07D251/48 , C07D251/64 , C08G12/26 , C08K5/3445 , C08K5/34922
Abstract: The present invention relates to N-1,2,2-trihydrocarbyloxyethyl derivatives of certain amino compounds, which derivatives are particularly suitable for use as crosslinking agents in curable compositions such as coatings, and which derivatives do not release formaldehyde as a volatile by-product during cure. Processes for preparing such derivatives, curable compositions based thereon as well as various specific uses thereof are also disclosed.
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