摘要:
A producing process of amino resin crosslinked particles includes the step of curing an emulsion of an amino resin precursor and an emulsifier in the presence of a catalyst, the amino resin precursor being a product of a reaction of an amino compound with formaldehyde, so as to prepare amino resin particles, the step of neutralizing the suspension of the amino resin particles after the curing step, and the step of heating the suspension in a temperature range of 130°C to 230°C after the neutralizing step. The amino resin crosslinked particles thus prepared by the condensation of the amino compound and formaldehyde generate formaldehyde in an amount of not more than 1000 ppm in a pyrolysis test and have a characteristic that a Hunter whiteness is not less than 85 percent.
摘要:
A diguanamine represented by general formula (1); a process for producing the same by the reaction of a dicarbonitrile represented by the general formula: NC-R-CN with dicyandiamide in the presence of a basic catalyst; and a thermosetting composition comprising, for example, a coating resin containing methylolated diguanamine, etherified diguanamine, precondensates thereof and derivatives thereof, and a thermosetting resin composition comprising, for example, a coating resin or an adhesive resin containing the diguanamine and an epoxy resin. In said formulae, R represents bicyclo[2.2.1]-2,5-heptylene, bicyclo[2.2.1]-2,6-heptylene or cyclohexylene.
摘要:
The invention relates to condensation products obtained by condensation of (A) of mixture comprising (a) a triazine of the general formula (I), in which R is C1-C6 alkyl, unsubstituted phenyl or phenyl substituted up to three times with C1-C4 alkyl, p-hydroxy phenyl or o-hydroxy phenyl, and C1-C4 alkyl substituted with phenyl, or mixtures thereof, and (b) a mixture comprising (b1) a triazine of the general formula (II), in which Rx is C1-C6 alkyl, unsubstituted phenyl or phenyl substituted up to three times with C1-C4 alkyl, and C1-C4 alkyl substituted with phenyl, and Y' is -NHZ, Z being selected from the group comprising hydroxy-C2-C10-alkyl, hydroxy-C2-C4-alkyl-(oxa-C2-C4-alkyl)m, where m is 1 to 5, -NHCH2CH2SCH2CH2OH and amino-C2-C12-alkyl, or mixtures thereof, and (b2) a substituted melamine of the general formula (III), in which X, X' and X'' are selected from the group comprising -NH2, -NHR' and -NH'R'', in which X, X' and X'' are not simultaneously either -NH2 or -NH'R'', and R' and R'' are selected from the group comprising hydroxy-C2-C10-alkyl, hydroxy-C2-C4-alkyl-(oxa-C2-C4-alkyl)n, where n is 1 to 5, and amino-C2-C12-alkyl, or mixtures thereof, and optionally; (B), unsubstituted phenols or phenols substituted with radicals selected from the group comprising C1-C9 alkyl and hydroxy, C1-C4 alkanes substituted with two or three phenol groups, di(hydroxyphenyl)sulphones or mixtures of said phenols, with formaldehyde or formaldehyde-supplying compounds. The invention also relates to a process for preparing said condensation products, the use thereof for producing moulded bodies, in particular fibres, and moulded bodies, in particular fibres and foamed materials, obtained with this process.
摘要:
Die vorliegende Erfindung betrifft Melamin-Formaldehyd-Harze, die ein Guanamin enthalten, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Melaminharzfolien und -kanten.
摘要:
The invention relates to a crosslinker composition comprising a reaction product of a cyclic urea U and a multifunctional aliphatic aldehyde A , and at least one crosslinker selected from the group consisting of reaction products of an aminotriazine and at least one aldehyde selected from the group consisting of aliphatic monoaldehydes and multifunctional aliphatic aldehydes having the structure Y(CHO) n , where Y is an n-functional aliphatic residue, and n is greater than 1; reaction products of urea and/or cyclic ureas and aliphatic monoaldehydes; alkoxycarbonylaminotriazines; multifunctional isocyanates which may be partially or completely blocked; reaction products of phenols and aliphatic monoaldehydes; multifunctional epoxides; multifunctional aziridines; and multifunctional carbodiimides, wherein any of the crosslinkers which have hydroxyl groups may be etherified with one or more linear, branched, or cyclic aliphatic alcohols.
摘要:
A crosslinking agent is provided, prepared by reacting (A) an aminoplast resin; (B) a reactive urethane group-containing adduct and (C) at least one other compound having active hydrogen groups reactive with aminoplast resin (A). Compound (C) is selected from: (i) compounds having the structure (I), wherein X is aromatic; R?1, R2, and R3¿ each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group, (ii) compounds having the structure (II) or (III), where R' and R' each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii), having a melting point of at least 80 °C. Further provided are methods for preparing the crosslinking agent curable compositions containing the crosslinking agent, and coated substrates.
摘要:
A novel amino resin composition prepared by reacting one or more of the triazine derivatives represented by general formula (I) with formaldehyde, wherein R?1, R2, R?3, R4, R5 and R6¿ are each independent, and one to five of them are each C¿1?-C20 alkyl, C2-C20 alkenyle (wherein the alkyl or alkenyl may optionally contain an alicyclic structure or a phenyl group in the structure, or alternatively, when two of the alkyl or alkenyl groups are bonded to the same nitrogen atom, both of them together with the nitrogen atom may form a 3- to 8-membered nitrogenous heterocycle) or phenyl, while the other(s) of them is hydrogen; another novel amino resin composition prepared by reacting a mixture comprising one or more of the above triazine derivatives and melamine and/or urea with formaldehyde; and still another amino resin composition comprising a novel amino resin composition prepared by reacting one or more of the above triazine derivatives with formaldehyde and one or more resins selected from among melamine resins, melamine-urea-formaldehyde resins and urea-formaldehyde resins. These amino resin compositions are excellent in tenacity and post-formability and have heat resistance, high hardness and excellent gloss which are inherent in melamine resins, so that they are usable for laminated sheets, decorative sheets, molding materials, and so on. Further, the compositions can be improved also in solubility in organic solvents and lipophilicity by selecting the substituents, and therefore are usable in the fields of paints, adhesive bonding of wood difficult of adhesive bonding, and so on.