摘要:
The present invention aims to provide a composition which can provide molded foams and foamed electric wires having a small average cell size and a high expansion ratio. The composition of the present invention includes a fluororesin; and boron nitride having an average particle size of 10.5 µm or greater, or boron nitride having a particle size distribution represented by (D84 - D16)/D50 of 1.2 or lower.
摘要:
The present invention aims to provide a composition which can provide foamed moldings and foamed electric wires having a small average cell size and a high foam content and causing fewer sparks. The composition of the present invention includes a fluororesin (A) and a compound (B) which is a sulfonic acid or a salt thereof. The sulfonic acid is represented by the following formula (1): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒF(CF 2 ) n SO 3 H€ƒ€ƒ€ƒ€ƒ€ƒ(1) wherein n is 4 or 5, or the following formula (2): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒF(CF 2 ) n CH 2 CH 2 SO 3 H€ƒ€ƒ€ƒ€ƒ€ƒ(2) wherein n is 4 or 5.
摘要:
The present invention provides a novel production process by which unstable terminal groups can be sufficiently stabilized under mild conditions. The present invention is related to a method for producing an -SO 3 H group-containing fluoropolymer wherein a fluoropolymer to be treated having a -SO 2 X group-containing monomer unit (X representing F or Cl) is subjected to a procedure comprising at least the steps A, B and C defined below in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a decomposition treatment agent; C: Step of reacting with a fluorinating agent.
摘要:
An object of the present invention is to provide a method for recovering a hydrofluorocarbon capable of recovering a hydrofluorocarbon used for producing fluoropolymers, in a higher recovery efficiency and in a shorter time. The present invention relates to a method for recovering a hydrofluorocarbon, including: producing a wet fluoropolymer by suspension polymerization, solution polymerization, or bulk polymerization in the presence of a hydrofluorocarbon; vaporizing and discharging vaporizable substances including the hydrofluorocarbon by heating the wet fluoropolymer in a container; and transferring the discharged vaporizable substances to a cooling means to cool the substances.
摘要:
A method for producing a stabilized fluoropolymer wherein a stabilized fluoropolymer is produced by fluorinating an object containing a fluoropolymer having a group derived from sulfonic acid is characterized in that the fluoropolymer having a group derived from sulfonic acid has -SO3M (wherein M represents H, NR R R R or M 1/L; R , R , R and R may be the same or different and respectively represent H or an alkyl group having 1-4 carbon atoms; and M represents an L-valent metal) and the moisture content of the object is not more than 500 ppm in mass.
摘要:
A process for producing a fluorocopolymer which comprises polymerizing an ethylenic fluoromonomer with a fluorovinyl ether derivative represented by the following general formula (I): CF2=CF-O-[CF2CF(CF3)O]n-(CF2)m-A (I) (wherein n is an integer of 0 to 3; m is an integer of 1 to 5; A represents -SO2X or -COOY; X represents halogeno or -NR1R2; R1 and R2 are the same or different and each represents hydrogen, an alkali metal, alkyl, or a sulfonyl-containing group; and Y represents hydrogen or C1-4 alkyl) in a saturated perfluorohydrocarbon, characterized by conducting the polymerization while additionally feeding the ethylenic fluoromonomer and the fluorovinyl ether derivative.
摘要:
The present invention relates to a method of producing the fluoropolymer according to any one of Claims 1 to 3, by subjecting a fluoropolymer precursor containing acid/acid salt groups and having -CF 2 COOX groups at polymer chain terminals, in the formula X represents H, NR 11 R 12 R 13 R 14 or M 4 1/L ; R 11 , R 12 , R 13 and R 14 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms and M 4 represents a metal having a valence of L, said metal having a valence of L being a metal belonging to the group 1, 2, 4, 8, 11, 12 or 13 of the long-form periodic table, to heat treatment for the conversion of said -CF 2 COOX groups to -CF 2 H groups, X being as defined above, wherein said fluoropolymer precursor is one obtained by polymerizing a perhalovinyl ether derivative represented by the general formula (I): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒCF 2 =CF-O- (CF 2 CFY 1 -O) n - (CFY 2 ) m -SO 2 Z€ƒ€ƒ€ƒ€ƒ€ƒ(I) wherein Y 1 represents F, Cl or a perfluoroalkyl group, n represents an integer of 0 to 3, the n atoms/groups of Y 1 are the same or different, Y 2 represents F or Cl, m represents an integer of 1 to 5, the m atoms of Y 2 are the same or different and Z represents F, Cl, Br, I, -OM 5 1/L or -ONR 15 R 16 R 17 R 18 ; M 5 represents a metal having a valence of L and the metal having a valence of L is as defined above, and R 15 , R 16 , R 17 and R 18 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms, when the group -SO 2 Z in the general formula (I) is not said acid/acid salt group but is a group convertible to such acid/acid salt group, said fluoropolymer precursor is one subjected to a conversion treatment, after the above-mentioned polymerization, for the conversion of said group -SO 2 Z to the above-mentioned acid/acid salt group, and said heat treatment comprises heating said fluoropolymer precursor at 120 to 400°C.