HYDROFLUOROCARBON RECOVERY METHOD
    5.
    发明公开

    公开(公告)号:EP3133092A4

    公开(公告)日:2017-11-29

    申请号:EP15810274

    申请日:2015-06-02

    申请人: DAIKIN IND LTD

    摘要: An object of the present invention is to provide a method for recovering a hydrofluorocarbon capable of recovering a hydrofluorocarbon used for producing fluoropolymers, in a higher recovery efficiency and in a shorter time. The present invention relates to a method for recovering a hydrofluorocarbon, including: producing a wet fluoropolymer by suspension polymerization, solution polymerization, or bulk polymerization in the presence of a hydrofluorocarbon; vaporizing and discharging vaporizable substances including the hydrofluorocarbon by heating the wet fluoropolymer in a container; and transferring the discharged vaporizable substances to a cooling means to cool the substances.

    FLUOROPOLYMER, PROCESS FOR PRODUCING FLUOROPOLYMER, ELECTROLYTE FILM, OBJECT HAVING IMMOBILIZED ACTIVE SUBSTANCE, AND SOLID POLYMER ELECTROLYTE TYPE FUEL CELL
    10.
    发明公开
    FLUOROPOLYMER, PROCESS FOR PRODUCING FLUOROPOLYMER, ELECTROLYTE FILM, OBJECT HAVING IMMOBILIZED ACTIVE SUBSTANCE, AND SOLID POLYMER ELECTROLYTE TYPE FUEL CELL 审中-公开
    含氟聚合物,用于生产含氟聚合物电解质薄膜,具有固定的活性和燃料电池由硬聚合物电解质类型的对象

    公开(公告)号:EP1702933A4

    公开(公告)日:2007-03-14

    申请号:EP04807243

    申请日:2004-12-17

    申请人: DAIKIN IND LTD

    摘要: The present invention relates to a method of producing the fluoropolymer according to any one of Claims 1 to 3, by subjecting a fluoropolymer precursor containing acid/acid salt groups and having -CF 2 COOX groups at polymer chain terminals, in the formula X represents H, NR 11 R 12 R 13 R 14 or M 4 1/L ; R 11 , R 12 , R 13 and R 14 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms and M 4 represents a metal having a valence of L, said metal having a valence of L being a metal belonging to the group 1, 2, 4, 8, 11, 12 or 13 of the long-form periodic table, to heat treatment for the conversion of said -CF 2 COOX groups to -CF 2 H groups, X being as defined above, wherein said fluoropolymer precursor is one obtained by polymerizing a perhalovinyl ether derivative represented by the general formula (I): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒCF 2 =CF-O- (CF 2 CFY 1 -O) n - (CFY 2 ) m -SO 2 Z€ƒ€ƒ€ƒ€ƒ€ƒ(I) wherein Y 1 represents F, Cl or a perfluoroalkyl group, n represents an integer of 0 to 3, the n atoms/groups of Y 1 are the same or different, Y 2 represents F or Cl, m represents an integer of 1 to 5, the m atoms of Y 2 are the same or different and Z represents F, Cl, Br, I, -OM 5 1/L or -ONR 15 R 16 R 17 R 18 ; M 5 represents a metal having a valence of L and the metal having a valence of L is as defined above, and R 15 , R 16 , R 17 and R 18 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms, when the group -SO 2 Z in the general formula (I) is not said acid/acid salt group but is a group convertible to such acid/acid salt group, said fluoropolymer precursor is one subjected to a conversion treatment, after the above-mentioned polymerization, for the conversion of said group -SO 2 Z to the above-mentioned acid/acid salt group, and said heat treatment comprises heating said fluoropolymer precursor at 120 to 400°C.