公开(公告)号：EP2803503A1

公开(公告)日：2014-11-19

申请号：EP13735691.1

申请日：2013-01-11

申请人： DNP Fine Chemicals Co., Ltd. ,  Bridgestone Corporation

发明人： SAITO, Yasuma ,  FURUTAKA, Toshio ,  SUGITA, Yukio ,  NAKAMURA, Yuki ,  Torisu, Kojiro ,  HAJIKANO, Akihiko

IPC分类号： B60C13/00 ,  B41J2/01 ,  C09D5/02 ,  C09D11/00 ,  C09D133/04 ,  C09D183/10

CPC分类号： B60C13/001 ,  B41J2/01 ,  B41M5/0047 ,  B41M5/0064 ,  B60C1/0025 ,  B60C13/00 ,  C09D11/101 ,  C09D11/30 ,  C09D133/04 ,  G01N3/08 ,  Y10T428/24802 ,  Y10T428/24851

摘要： Provided is a decorative tire in which an ink composition including a colorant is directly applied onto the tire surface in order to improve the degree of flexibility in design. This decorative tire has a decorative printed layer formed on the tire surface, the decorative printed layer being a cured film of an active-energy-ray-curable ink composition including a colorant. The ink composition includes a monofunctional monomer having a glass transition point of -30°C or lower, and a polyfunctional monomer having a glass transition point of 0°C or lower. Preferably, the ink composition further includes a monofunctional monomer having an alicyclic structure with a glass transition point between 0-110°C inclusive. Preferably, a surface protection layer that protects the surface of the decorative printed layer is formed on the surface of the decorative printed layer. Also, preferably, a primer layer is formed between the tire surface and the decorative printed layer.

公开(公告)号：EP3012300A1

公开(公告)日：2016-04-27

申请号：EP14813105.5

申请日：2014-06-16

申请人： DNP Fine Chemicals Co., Ltd.

发明人： FURUTAKA, Toshio ,  MORIYAMA, Gaku ,  SAITO, Yasuma

IPC分类号： C09D133/00 ,  B32B27/30 ,  B32B27/40 ,  B41M7/02 ,  C09D5/02 ,  C09D7/12 ,  C09D11/00 ,  C09D175/04

CPC分类号： C09D175/04 ,  B32B25/08 ,  B32B27/08 ,  B32B27/26 ,  B32B27/306 ,  B32B27/308 ,  B32B27/40 ,  B32B2250/24 ,  B32B2274/00 ,  B32B2307/4023 ,  B32B2307/712 ,  B32B2451/00 ,  B41M7/0045 ,  B41M2205/40 ,  C08G18/44 ,  C09D5/02 ,  C09D11/101 ,  C09D11/54 ,  C09D133/00 ,  C09D133/08

摘要： Provided are: a surface protection layer composition having excellent damage resistance, and followability with respect to expansion and contraction of an elastic base material; and a decorative body using the same. This surface protection layer composition includes a silicone-modified (meth)acrylate-based resin having a glass transition point (Tg) of 0°C or less, and a carbonate-modified urethane resin. The surface protection layer composition is used to configure a surface protection layer for protecting: an elastomer base material, or a base material having a Young's modulus of 0.001MPa to -30MPa inclusive; and the surface of the decorative layer which is a cured film of an ink composition formed on the base material. Thus, adhesion to the decorative layer is excellent, and with respect to expansion and contraction of the base material, followability, and damage resistance, and the like, are excellent.

摘要翻译： 提供：具有优异的耐损伤性的表面保护层组合物，以及弹性基材的膨胀和收缩的随动性; 和使用其的装饰体。 该表面保护层组合物包含玻璃化转变点（Tg）为0℃以下的硅氧烷改性（甲基）丙烯酸酯系树脂和碳酸酯改性聚氨酯树脂。 表面保护层组合物用于构成保护层的表面保护层：弹性体基材或杨氏模量为0.001MPa〜-30MPa的基材; 以及作为形成在基材上的油墨组合物的固化膜的装饰层的表面。 因此，对装饰层的附着性优异，并且在基材的膨胀和收缩方面，追随性和耐损伤性等优异。

公开(公告)号：EP3020547A1

公开(公告)日：2016-05-18

申请号：EP14822740.8

申请日：2014-07-10

申请人： DNP Fine Chemicals Co., Ltd.

发明人： SAITO, Yasuma ,  MORIYAMA, Gaku ,  FURUTAKA, Toshio

IPC分类号： B32B27/00 ,  B32B25/08 ,  B32B27/16 ,  B32B27/30 ,  C08F290/06 ,  C08J7/04 ,  C09D11/30

CPC分类号： C09D11/101 ,  B32B27/06 ,  B32B27/16 ,  B32B27/30 ,  B32B2307/581 ,  B32B2605/00 ,  C08F290/062 ,  C08J7/047 ,  C08J2321/00 ,  C08J2433/04 ,  C09D11/107 ,  C09D11/30

摘要： Provided is a laminate body having a decorative layer formed on the surface thereof, having excellent cracking resistance and external appearance retention even in an environment such as one in which the base material undergoes repeated expansion and contraction. A laminate body on which a decorative layer, which is a cured film made from an active-energy-ray-curable ink composition, is formed on a stretchable base material, wherein the cured film contains a cured product comprising: a monofunctional monomer (monomer (A)) having a glass transition point at or below -30°C; and an alkylene-oxide-modified tri-or higher-functional monomer (monomer (B)) in which the number of alkylene oxide modifications/number of functional groups, which is the ratio of the number of alkylene oxide modifications and the number of functional groups, is 3 or greater, the number of cracks in a test piece of the cured film after prescribed repeated tensile testing being 3 or less.

摘要翻译： 本发明提供一种在表面形成有装饰层的层压体，即使在基材反复伸缩的环境下，也具有优异的耐龟裂性和外观保持性。 1。一种层叠体，其是在伸缩性基材上形成作为由活性能量射线固化型油墨组合物形成的固化膜的装饰层的层叠体，其中，所述固化膜含有包含单官能单体（单体 （A））具有等于或低于-30℃的玻璃化转变点; 和烯化氧改性的三官能或更高官能的单体（单体（B）），其中烯化氧改性的数量/官能团的数量是烯化氧改性的数量与官能团的数量 组为3以上时，规定的反复拉伸试验后的固化膜的试验片的裂纹的数量为3个以下。

公开(公告)号：EP2803705A1

公开(公告)日：2014-11-19

申请号：EP13735867.7

申请日：2013-01-11

申请人： DNP Fine Chemicals Co., Ltd.

发明人： SAITO, Yasuma ,  FURUTAKA, Toshio ,  SUGITA, Yukio

IPC分类号： C09D11/00 ,  B41J2/01 ,  B41M5/00 ,  B41M5/50 ,  B41M5/52

CPC分类号： C09D11/107 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/30 ,  C09D11/38 ,  Y10T428/24802

摘要： Provided is an ink composition having excellent conformability even to a flexible base material to be printed. This active-energy-ray-curable ink composition comprises active-energy-ray-polymerizable monomers and an active-energy-ray polymerization initiator. The active-energy-ray-polymerizable monomers include: monomer A which is a monofunctional monomer having a glass transition point of -30°C or lower; and monomer B which is a polyfunctional monomer having a glass transition point of 0°C or lower. Preferably, said monomer B is a bifunctional monomer having a glass transition point of -30°C or lower. Preferably, the active-energy-ray-polymerizable monomers further include monomer C which is a monofunctional monomer having an alicyclic structure with a glass transition point between 0-110°C inclusive. The ink composition may also include a colorant.

摘要翻译： 本发明提供一种具有优异的贴合性，即使在柔性基底材料将被打印的油墨组合物。 这种活性能量线固化型油墨组合物含有活性能量射线聚合性单体的活性能量射线聚合引发剂的和。 活性能量射线聚合性单体包括：单体A所有其是具有-30℃或更低的玻璃化转变点的单官能单体; 和单体B的所有其是具有0℃或更低的玻璃化转变点的多官能单体。 优选地，所述单体B为具有-30℃或更低的玻璃化转变点的双官能单体。 优选地，活性能量射线聚合性单体进一步单体包括C所有这是在具有脂环式结构与0-110℃以下的玻璃化转变点的单官能单体。 因此，该油墨组合物可以包括着色剂。