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    Ene-yne unsaturated compounds as accelerators for hydrosilation
    3.
    发明公开
    Ene-yne unsaturated compounds as accelerators for hydrosilation 失效
    烯炔不饱和化合物作为氢化硅烷化促进剂

    公开(公告)号：EP0751140A3

    公开(公告)日：1997-09-17

    申请号：EP96304405.2

    申请日：1996-06-11

    申请人： DOW CORNING CORPORATION

    发明人： Bank, Howard Marvin ,  Decker, Gary Thomas ,  Lo, Peter Yin Kwai

    IPC分类号： C07F7/14

    CPC分类号： C07F7/14

    摘要： A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from ene-yne unsaturated compounds. The accelerators are especially useful for facilitating the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene or cyclohexene.

    摘要翻译： 一种氢化硅烷化方法，其中在铂催化剂和选自烯属不饱和化合物的促进剂存在下，使氢化硅与不饱和反应物反应。 促进剂特别适用于促进不饱和反应物的氢化硅烷化，其中不饱和基团位于反应物结构的内部部分中，例如在环戊烯或环己烯中。

    Unsaturated alcohols as accelerators for hydrosilation
    4.
    发明公开
    Unsaturated alcohols as accelerators for hydrosilation 失效
    UngesättigteAlkohole als BeschleunigerfürHydrosilylierungung

    公开(公告)号：EP0738730A3

    公开(公告)日：1997-09-10

    申请号：EP96302475.7

    申请日：1996-04-09

    申请人： DOW CORNING CORPORATION

    发明人： Bank, Howard Marvin ,  Decker, Gary Thomas

    IPC分类号： C07F7/14 ,  C07F7/08

    CPC分类号： C07F7/14

    摘要： A hydrosilation process is disclosed herein where a silicon hydride is contacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of unsaturated secondary and tertiary alcohols or silated unsaturated secondary and tertiary alcohols. These accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The accelerators are believed to be effective in the presence or absence of oxygen.

    摘要翻译： 氢化过程包括使式（I）（R1）a（H）bSiX（4-a-b）和（B）不饱和的（A）氢化硅接触。 反应物选自（i）选择。 substd。 unsatd。 和/或（ii）硅cpds。 包括选择。 substd。 unsatd。 有机取代基，在铂催化剂（Ⅵ）（铂cpds或铂络合物）和促进剂（不饱和或不饱和的式（II）和（III）的醇或甲硅烷基化的不饱和单元或叔 式（IV）和（V）的醇）。 式中R1为1-20C烷基，1-12环烷基或芳基; X为卤素或OR 1; a是0-3; b为1-3，z + b为1-4。 R2是H或1-6C烷基; R3是1-6C烷基; c和d为0-3; c + d为0-3; e和f为1-4，n为0-10。

    Disubstituted palladium catalysts for reacting organic halides with disilanes
    5.
    发明公开
    Disubstituted palladium catalysts for reacting organic halides with disilanes 失效
    Disubstituierte Palladium-Katalysatoren zur Umsetzung organischer Halide mit Disilanen

    公开(公告)号：EP0787737A1

    公开(公告)日：1997-08-06

    申请号：EP97300519.2

    申请日：1997-01-28

    申请人： DOW CORNING CORPORATION

    发明人： Bank, Howard Marvin ,  Naasz, Brian Michael ,  Nguyen, Binh Thanh

    IPC分类号： C07F7/08 ,  C07F7/12

    CPC分类号： C07F7/122 ,  C07F7/123

    摘要： A process is described for reacting organic halides with disilanes to form monosilanes. The process uses disubstituted palladium compounds as catalysts. This process is especially useful for reacting alkenyl chlorides, such as allyl chloride, with disilanes to form monosilanes having alkenyl substitution. Our process is also useful for converting the high-boiling disilane fraction, resulting from the direct process for forming organosilanes, into more useful monosilanes.

    摘要翻译： 有机卤化物与二硅烷反应形成单硅烷的方法。 该方法使用二取代的钯化合物作为催化剂。 该方法特别可用于使链烯基氯如烯丙基氯与二硅烷反应以形成具有烯基取代的单硅烷。 该方法也可用于将由形成有机硅烷的直接方法得到的含高沸点乙硅烷的级分转化为更有用的单硅烷。

    Aldehydes as accelerators for hydrosilation
    6.
    发明公开
    Aldehydes as accelerators for hydrosilation 失效
    Aldehyde als BeschleunigerfürHydrosilylierungsreaktionen

    公开(公告)号：EP0786465A1

    公开(公告)日：1997-07-30

    申请号：EP97101287.7

    申请日：1997-01-28

    申请人： DOW CORNING CORPORATION

    发明人： Bank, Howard Marvin ,  Decker, Gary Thomas

    IPC分类号： C07F7/14

    CPC分类号： C07F7/0829 ,  C07F7/14

    摘要： A hydrosilation process is described where a silicon hydride is reacted with an unsaturated component in the presence of a platinum catalyst and an aldehyde accelerator. Our aldehyde accelerators are especially useful for facilitating hydrosilation of unsaturated components where the unsaturation is in the internal portion of the component's structure, for example, as in cyclopentene and cyclohexene.

    摘要翻译： 硅氢化方法包括在包含Pt cpd的铂催化剂的存在下， 或Pt络合物和醛促进剂：（A）式R1aHbSiX4-a-b（Ⅰ）的氢化硅，其中：R1 = 1-20C烷基，4-12C环烷基或芳基; X =卤素或OR 1; a = 0-3; b = 1-3，a + b = 1-4; 和（B）不饱和。 反应物选自：（i）选择。 substd。 有机cpds。 contg。 非芳香族，不饱和的 碳 - 碳键; 和/或（ii）Si cpds。 包括选择。 substd。 有机取代基 非芳香族，不饱和的 C-C键。

    Process for organooxylation of cyanoalkylchlorosilanes
    9.
    发明公开
    Process for organooxylation of cyanoalkylchlorosilanes 失效
    氰烷基氯硅烷的有机氧化方法

    公开(公告)号：EP0682034A2

    公开(公告)日：1995-11-15

    申请号：EP95303063.2

    申请日：1995-05-04

    申请人： DOW CORNING CORPORATION

    发明人： Bank, Howard Marvin ,  Meindertsma, Richard Duane

    IPC分类号： C07F7/18

    CPC分类号： C07F7/188

    摘要： A process for the organooxylation of β-cyanoalkylchlorosilanes. The process comprises contacting in a film a β-cyanoalkylchlorosilane with an alcohol capable of forming an ester with the silicon of the β-cyanoalkylchlorosilane and thereby forming an equilibrium mixture comprising a (β-cyanoalkyl)organooxysilane and hydrogen chloride. The film is heated at a temperature sufficient to cause vaporization of the hydrogen chloride from the equilibrium mixture thereby increasing yield of (β-cyanoalkyl)organooxysilane in the equilibrium mixture. In a preferred process, the process is run in a falling-film type reactor or a wiped-film type reactor.

    摘要翻译： 一种β-氰基烷基氯硅烷有机氧化的方法。 该方法包括在膜中使β-氰基烷基氯硅烷与能够与β-氰基烷基氯硅烷的硅形成酯的醇接触，从而形成包含（β-氰基烷基）有机氧基硅烷和氯化氢的平衡混合物。 在足以引起氯化氢从平衡混合物中蒸发的温度下加热该膜，从而增加平衡混合物中（β-氰基烷基）有机氧基硅烷的收率。 在优选的方法中，该方法在降膜式反应器或刮膜式反应器中进行。