摘要:
Polyurethane foams are made and attached to a substrate having an open cavity, but reacting a polyisocyanate component and a polyol component in the presence of a blowing agent. The polyisocyanate component includes at least one isocyanate-terminated, oxazolidone-containing intermediate. This process allows for very fast curing, good quality, adherent foams to be produced on, for example, vehicle parts and assemblies, for acoustical or vibration dampening and for structural reinforcement.
摘要:
Polyolefin compositions that expand freely to form stable foams are disclosed. The compositions include at least one heat-activated expanding agent and typically include at least one heat-expanded crosslinker. The compositions are effective as sealers and noise/vibration insulation in automotive applications.
摘要:
Foam-in-place, one component polyurethane compositions are useful to produce foams that adhere to various substrates such as certain vehicle parts and assemblies. The polyurethane composition contains a heat-activated blowing agent. The composition is based on a polyurethane resin that is expandable. The resin is a heat-softenable material, or a low molecular weight material that engages in further curing during the heat expansion step.
摘要:
Polyurethane foams are made and attached to a substrate having an open cavity, but reacting prepolymer and polyol components in the presence of certain carbamate blowing agents. This process allows for very fast curing, good quality, adherent foamy to be produced on, for example, vehicle parts and assemblies, for acoustical or vibration dampening and for structural reinforcement.
摘要:
A structural member is reinforced with a thermoset polymer foam having (a) a density of 80 - 650 kg/m3, (b) a storage modulus, measured on a 12 mm wide x 3.5 mm thick x 17.5 single cantilever sample according to ASTM D 4065-01, under conditions of 1 Hz and a heating rate of 2°C/min, such that the ratio of the storage modulus at 0°C, expressed in MPa, divided by the density of the thermoset polymer foam, expressed in kg/m3, is at least 0.4, and (c) the ratio of the storage modulus of the thermoset polymer foam at 100°C divided by the storage modulus of the thermoset polymer foam at 0°C is at least 0.5. The foam is preferably a polyurethane-isocyanurate foam. The foam exhibits excellent resistance to cracking due to mechanical and thermal stresses.
摘要:
Polyurethane foams are made and attached to a substrate having an open cavity, but reacting prepolymer and polyol components in the presence of certain carbamate blowing agents. This process allows for very fast curing, good quality, adherent foamy to be produced on, for example, vehicle parts and assemblies, for acoustical or vibration dampening and for structural reinforcement.
摘要:
Polyolefin compositions that expand freely to form stable foams are disclosed. The compositions contain specified levels of adhesion-promoting resins. The compositions include at least one heat-activated expanding agent and typically include at least one heat-expanded crosslinker. The compositions are effective as sealers and noise/vibration insulation in automotive applications.
摘要:
Polyurethane foams are made using a prepolymer that is the reaction product of an organic polyisocyanate, a hydroxy-functional acrylate or methacrylate, and a polyol. This prepolymer is reacted at specified volume ratios and isocyanate indices with a polyol component that includes at least one polyol. The foam is made in the presence of a blowing agent and catalyst. Preferred blowing agents are water and chemical blowing agents that generate carbon dioxide in the reaction. Preferred catalysts have primary or secondary amine groups that allow them to react into the resulting polymer structure, thus decreasing the level of volatile components.
摘要:
Polyurethane foams are made using a prepolymer that is the reaction product of an organic polyisocyanate, a hydroxy-functional acrylate or methacrylate, and a polyol. This prepolymer is reacted at specified volume ratios and isocyanate indices with a polyol component that includes at least one polyol. The foam is made in the presence of a blowing agent and catalyst. Preferred blowing agents are water and chemical blowing agents that generate carbon dioxide in the reaction. Preferred catalysts have primary or secondary amine groups that allow them to react into the resulting polymer structure, thus decreasing the level of volatile components.
摘要:
A structural member is reinforced with a thermoset polymer foam having (a) a density of 80 - 650 kg/m3, (b) a storage modulus, measured on a 12 mm wide x 3.5 mm thick x 17.5 single cantilever sample according to ASTM D 4065-01, under conditions of 1 Hz and a heating rate of 2°C/min, such that the ratio of the storage modulus at 0°C, expressed in MPa, divided by the density of the thermoset polymer foam, expressed in kg/m3, is at least 0.4, and (c) the ratio of the storage modulus of the thermoset polymer foam at 100°C divided by the storage modulus of the thermoset polymer foam at 0°C is at least 0.5. The foam is preferably a polyurethane-isocyanurate foam. The foam exhibits excellent resistance to cracking due to mechanical and thermal stresses.