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公开(公告)号：EP1366198B1
公开(公告)日：2012-02-08
申请号：EP01994869.4
申请日：2001-12-28
申请人： Danisco A/S
发明人： HEIKKILÄ, Heikki , MÄNTTÄRI, Mika , NYSTRÖM, Marianne , LINDROOS, Mirja , PAANANEN, Hannu , PUUPPO, Outi , KOIVIKKO, Hannu
CPC分类号： C13B20/165 , C13K13/002
摘要： The invention relates to a process of separating compounds with a small molar mass from compounds having a molar mass less than 1.9 times that of the compounds with a small molar mass using nanofiltration. The compounds with a small molar mass have a typical molar mass less than 250 g/mol. In one embodiment of the invention, pentose sugars are separated from hexose sugars. The invention can be applied to the recovery of xylose from spent liquors and to the recovery of betaine from sugar beet pulp extracts, for example.
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公开(公告)号：EP2401047A1
公开(公告)日：2012-01-04
申请号：EP10745858.0
申请日：2010-02-24
申请人： Danisco A/S
摘要： The present invention relates to a chromatographic separation process for fractionating betaine-containing solutions by utilizing fractions comprising parts of the separation profile as a substituent of the eluent in a novel and inventive manner. The process provides improved separation capacity and separation efficiency without affecting the yield or purity of betaine or other products. The process can especially be applied to sequential SMB separation systems.
摘要翻译： 本发明涉及通过利用包含部分分离曲线作为洗脱液的取代基的馏分以新颖且创造性的方式分馏含甜菜碱的溶液的色谱分离方法。 该方法提供了改进的分离能力和分离效率，而不影响甜菜碱或其他产品的产量或纯度。 该过程尤其可以应用于顺序SMB分离系统。
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公开(公告)号：EP1468121B1
公开(公告)日：2011-11-09
申请号：EP02788021.0
申请日：2002-12-30
申请人： Danisco A/S
发明人： ENNELIN, Anu , JUMPPANEN, Juho , RAVANKO, Vili , NURMI, Juha , KAIRA, Miikka , HEIKKILÄ, Heikki
IPC分类号： C13B20/14
CPC分类号： C13B20/144 , C13K13/007
摘要： The invention relates to a chromatographic separation process of recovering mannose with high purity. The invention is based on the use of a chromatographic separation resin including a resin which is at least partly in a Ba2+ form resin and a resin which is in other than Ba2+ form.
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公开(公告)号：EP2016087A1
公开(公告)日：2009-01-21
申请号：EP07730722.1
申请日：2007-04-26
申请人： Danisco A/S
IPC分类号： C07H15/04 , C07C31/18 , C07C29/141 , C07C29/145
CPC分类号： C07C29/141 , C07B2200/07 , C07H15/04 , C07C31/26
摘要： The invention relates to an improved process for the production of a sugar alcohol from the corresponding sugar through catalytic hydrogenation. Especially, the invention relates to a process for reducing the interference of sugar-derived aldonic acids in the hydrogenation process by adjusting the hydrogenation conditions so that the activity of the catalyst is maintained. In one embodiment of the invention, the process of the invention is carried out by adjusting the hydrogenation temperature by starting the hydrogenation at a lower temperature and then gradually rising the temperature to the final hydrogenation temperature. In another embodiment of the invention, the process of the invention is carried out by adding small-molecular monocarboxylic acids to the hydrogenation solution.
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公开(公告)号：EP2044225A1
公开(公告)日：2009-04-08
申请号：EP07730793.2
申请日：2007-05-29
申请人： DANISCO A/S
CPC分类号： C13B35/08 , B01D61/027 , B01D2315/14 , C13B20/165
摘要： The invention relates to an improved nanofiltration process for separating and recovering components, such as sug ars and sugar alcohols from multicomponent mixtures. The process of the invention is characterized by collecting the nanofiltration retentate/permeate in several fractions with different purity, optional recycling of at least one of the collected nanofiltration retentate/permeate fractions to the nanofiltration and recovering the desired component from the nanofiltration permeate/retentate fractions by dif ferent methods. In one embodiment of the invention, the process comprises a combination of nanofiltration and chromatography.
摘要翻译： 本发明涉及用于从多组分混合物中分离和回收组分（例如糖和糖醇）的改进的纳滤过程。 本发明的方法的特征在于将纳滤渗余物/渗透物收集在具有不同纯度的几个级分中，任选地将收集的纳滤渗余物/渗透物级分中的至少一个回收至纳滤并从纳滤渗透物/渗余物级分回收期望的组分 通过不同的方法。 在本发明的一个实施方案中，该方法包括纳滤和色谱的组合。
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6.发明授权USE OF A WEAKLY ACID CATION EXCHANGE RESIN FOR CHROMATOGRAPHIC SEPARATION OF CARBOHYDRATES 有权使用弱酸阳离子交换CHROMATROGRAPHISCHEN用于分离碳水化合物的
公开(公告)号：EP1348037B1
公开(公告)日：2008-11-05
申请号：EP01972130.7
申请日：2001-09-28
申请人： Danisco A/S
发明人： KÄRKI, Ari , HEIKKILÄ, Heikki , JUMPPANEN, Juho , TIIHONEN, Jari , TERVALA, Tiina , MÄYRÄ, Nina , RAVANKO, Vili , PAANANEN, Hannu , PAATERO, Erkki
CPC分类号： C13B20/144 , B01J39/05 , B01J39/26 , C13K3/00 , C13K11/00 , C13K13/00 , C13K13/002
摘要： The invention relates to the use of a weakly acid cation exchange resin for chromatographic separation of carbohydrates. In the invention the hydrophilic/hydrophobic interaction of carbohydrates, sugars and sugar alcohols with the weakly acid cation exchange resin is utilised. The weakly acid cation exchange resin is used for separation of hydrophobic saccharides, such as deoxy, methyl and anhydrosugars and anhydrosugaralcohols from more hydrophilic saccharides.
摘要翻译： 本发明涉及使用弱酸阳离子交换树脂的碳水化合物的色谱分离。 在本发明的碳水化合物，糖和糖醇的与弱酸阳离子交换树脂的亲水性/疏水相互作用被利用。 该弱酸阳离子交换树脂用于疏水性糖类，：如脱氧，甲基和anhydrosugars和从多种亲水性糖类anhydrosugaralcohols的分离。
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公开(公告)号：EP1941063A1
公开(公告)日：2008-07-09
申请号：EP06808006.8
申请日：2006-10-27
申请人： DANISCO A/S
CPC分类号： C13K13/002 , B01D61/027 , B01D61/12 , B01D2311/10 , B01D2311/18 , B01D2313/083 , B01D2315/14 , B01D2317/04 , C13B20/165 , C13K1/02 , C13K1/04 , C13K13/00
摘要： The invention relates to a nanofiltration process for enriching and concentrating a neutral organic compound into the permeated liquid with negative retention.
摘要翻译： 本发明涉及用于将中性有机化合物浓缩和浓缩到具有负保留的渗透液体中的纳滤过程。
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8.发明授权
公开(公告)号：EP1341935B1
公开(公告)日：2007-11-21
申请号：EP01972132.3
申请日：2001-09-28
申请人： DANISCO A/S
发明人： HEIKKILÄ, Heikki , JUMPPANEN, Juho , KURULA, Vesa , RAVANKO, Vili , TERVALA, Tiina , MÄYRÄ, Nina
CPC分类号： C13B30/02 , B01J39/07 , B01J39/26 , C13B20/144 , C13K13/00 , C13K13/002
摘要： The present invention relates to a method for recovering a monosaccharide selected from the group consisting of rhamnose, arabinose, xylose and mixtures thereof from a solution containing the same by a multistep process using chromatographic separation comprising at least one step, where a weakly acid cation exchange resin is used for the chromatographic separation.
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公开(公告)号：EP2401046A1
公开(公告)日：2012-01-04
申请号：EP10745857.2
申请日：2010-02-24
申请人： Danisco A/S
CPC分类号： C13B20/14 , B01D15/185 , B01D15/362 , B01D15/363 , C07H1/06 , C13K13/00
摘要： The present invention relates to a chromatographic separation process for fractionating solutions containing sugars, sugar alcohols, sugar acids and/or betaine by utilizing fractions comprising parts of the separation profile as a substituent of the eluent in a novel and inventive manner. The starting solutions are typically multicomponent plant- based extracts and hydrolysates, stillages, and fermentation products and derivatives thereof. The process provides improved separation capacity and separation efficiency without affecting the yield or purity of product components, such as sugars, sugar alcohols, sugar acids, and betaine. The process can especially be applied to sequential SMB separation systems.
摘要翻译： 本发明涉及一种通过利用包含部分分离特征的级分作为洗脱液的取代基以新颖且创造性的方式分馏含有糖，糖醇，糖酸和/或甜菜碱的溶液的色谱分离方法。 起始溶液通常是多组分基于植物的提取物和水解产物，酒糟，以及发酵产物及其衍生物。 该方法提供了改进的分离能力和分离效率，而不影响产品组分例如糖，糖醇，糖酸和甜菜碱的产率或纯度。 该过程尤其可以应用于顺序SMB分离系统。
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公开(公告)号：EP2350322A1
公开(公告)日：2011-08-03
申请号：EP09821646.8
申请日：2009-10-20
申请人： Danisco A/S
CPC分类号： C13K13/002 , C13B20/148 , C13B20/165 , C13B30/02 , C13K1/04 , D21C1/04 , D21C3/02 , D21C11/0007
摘要： The present invention relates to a process for the production of xylose and dissolving pulp from xylan-containing biomass, such as hardwood. The invention is based on prehydrolysis of the xylan-containing biomass with SO
2 in specified conditions, followed by chromatographic fractionation, nanofiltration or precipitation crystallization of the xylose-containing prehydrolyzate to obtain a xylose product having a xylose content of at least 55% on DS. The dissolving pulp obtained from the process can be used for example for the production of viscose.
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