公开(公告)号：EP4306569A2

公开(公告)日：2024-01-17

申请号：EP23209651.1

申请日：2016-04-13

申请人： E I Du Pont De Nemours ,  Archer Daniels Midland Company

发明人： Howard, Stephen J. ,  Kreutzer, Kristina A. ,  Rajagopalan, Bhuma ,  Sacia, Eric R. ,  Sanborn, Alexandra ,  Smith, Brennan

IPC分类号： C08G63/672

摘要： An integrated process for producing an ester of 2,5-furandicarboxylic acid from a six carbon sugar-containing feed, comprising:
e) dehydrating a feed comprising a six-carbon sugar unit, in the presence of a bromine source and of a solvent, at an elevated temperature and for a time sufficient to generate an oxidation feed comprised of at least one of 5-hydroxymethylfurfural and/or a derivative or derivatives of 5-hydroxymethylfurfural in the solvent, together with at least one bromine containing species;
f) contacting the oxidation feed from step (a) with a homogenous metal catalyst and with an oxygen source at an elevated temperature for a time sufficient to produce an oxidation product mixture comprising 2,5-furandicarboxylic acid (FDCA), the solvent, and a residual catalyst;
g) purifying and separating the mixture obtained in step (b) to obtain FDCA and the solvent;
h) recycling at least a portion of the solvent obtained in step (c) to step (a); and
e) esterifying 2,5-furandicarboxylic acid with a C 1 -C 12 aliphatic alcohol or a C 1 -C 12 aliphatic diol, under conditions effective for carrying out the esterification and optionally in the presence of a suitable esterification catalyst.

公开(公告)号：EP4306569A3

公开(公告)日：2024-04-10

申请号：EP23209651.1

申请日：2016-04-13

申请人： E I Du Pont De Nemours ,  Archer Daniels Midland Company

发明人： Howard, Stephen J. ,  Kreutzer, Kristina A. ,  Rajagopalan, Bhuma ,  Sacia, Eric R. ,  Sanborn, Alexandra ,  Smith, Brennan

IPC分类号： C07D307/40 ,  C07D307/44 ,  C07D307/46 ,  C07D307/68 ,  B01J31/04 ,  C08G63/181 ,  C08G63/672 ,  C08G63/78 ,  C08G63/80 ,  C08G69/28 ,  C08G69/32

摘要： An integrated process for producing an ester of 2,5-furandicarboxylic acid from a six carbon sugar-containing feed, comprising:
e) dehydrating a feed comprising a six-carbon sugar unit, in the presence of a bromine source and of a solvent, at an elevated temperature and for a time sufficient to generate an oxidation feed comprised of at least one of 5-hydroxymethylfurfural and/or a derivative or derivatives of 5-hydroxymethylfurfural in the solvent, together with at least one bromine containing species;
f) contacting the oxidation feed from step (a) with a homogenous metal catalyst and with an oxygen source at an elevated temperature for a time sufficient to produce an oxidation product mixture comprising 2,5-furandicarboxylic acid (FDCA), the solvent, and a residual catalyst;
g) purifying and separating the mixture obtained in step (b) to obtain FDCA and the solvent;
h) recycling at least a portion of the solvent obtained in step (c) to step (a); and
e) esterifying 2,5-furandicarboxylic acid with a C 1 -C 12 aliphatic alcohol or a C 1 -C 12 aliphatic diol, under conditions effective for carrying out the esterification and optionally in the presence of a suitable esterification catalyst.

公开(公告)号：EP4306568A3

公开(公告)日：2024-04-10

申请号：EP23209530.7

申请日：2016-04-13

申请人： E I Du Pont De Nemours ,  Archer Daniels Midland Company

发明人： Howard, Stephen J. ,  Kreutzer, Kristina A. ,  Rajagopalan, Bhuma ,  Sacia, Eric R. ,  Sanborn, Alexandra ,  Smith, Brennan

IPC分类号： C07D307/40 ,  C07D307/44 ,  C07D307/46 ,  C07D307/68 ,  B01J31/04 ,  C08G63/181 ,  C08G63/672 ,  C08G63/78 ,  C08G63/80 ,  C08G69/28 ,  C08G69/32

摘要： An integrated process for producing 2,5-furandicarboxylic acid and/or a derivative thereof from a six carbon sugar-containing feed, comprising:
a) dehydrating a feed comprising a six-carbon sugar unit, in the presence of a bromine source and of a solvent, at an elevated temperature and for a time sufficient to generate an oxidation feed comprised of at least one of 5-hydroxymethylfurfural and/or a derivative or derivatives of 5-hydroxymethylfurfural in the solvent, together with at least one bromine containing species;
b) reducing the water content of the oxidation feed produced in step (a);
c) contacting the oxidation feed from step (b) with a metal catalyst and with an oxygen source at an elevated temperature for a time sufficient to produce an oxidation product mixture comprising 2,5-furandicarboxylic acid (FDCA) and/or a derivative thereof, the solvent, and a residual catalyst, wherein the metal catalyst comprises either or both of Co and Mn;
d) purifying and separating the mixture obtained in step (c) to obtain FDCA and/or a derivative thereof and the solvent; and
e) recycling at least a portion of the solvent obtained in step (d) to step (a).

公开(公告)号：EP4306568A2

公开(公告)日：2024-01-17

申请号：EP23209530.7

申请日：2016-04-13

申请人： E I Du Pont De Nemours ,  Archer Daniels Midland Company

发明人： Howard, Stephen J. ,  Kreutzer, Kristina A. ,  Rajagopalan, Bhuma ,  Sacia, Eric R. ,  Sanborn, Alexandra ,  Smith, Brennan

IPC分类号： C08G63/672

摘要： An integrated process for producing 2,5-furandicarboxylic acid and/or a derivative thereof from a six carbon sugar-containing feed, comprising:
a) dehydrating a feed comprising a six-carbon sugar unit, in the presence of a bromine source and of a solvent, at an elevated temperature and for a time sufficient to generate an oxidation feed comprised of at least one of 5-hydroxymethylfurfural and/or a derivative or derivatives of 5-hydroxymethylfurfural in the solvent, together with at least one bromine containing species;
b) reducing the water content of the oxidation feed produced in step (a);
c) contacting the oxidation feed from step (b) with a metal catalyst and with an oxygen source at an elevated temperature for a time sufficient to produce an oxidation product mixture comprising 2,5-furandicarboxylic acid (FDCA) and/or a derivative thereof, the solvent, and a residual catalyst, wherein the metal catalyst comprises either or both of Co and Mn;
d) purifying and separating the mixture obtained in step (c) to obtain FDCA and/or a derivative thereof and the solvent; and
e) recycling at least a portion of the solvent obtained in step (d) to step (a).

公开(公告)号：EP4071142A1

公开(公告)日：2022-10-12

申请号：EP22175991.3

申请日：2018-06-20

申请人： Archer Daniels Midland Company

发明人： Anklam, Pam ,  Hoffman, William Chris ,  Howard, Stephen J. ,  Sanborn, Alexandra ,  Schultz, Mitchell ,  Soper, John G.

IPC分类号： C07D307/68 ,  B01J43/00

摘要： The present invention relates to a process for making the esters of 2,5-furandicarboxylic acid, and particularly the dimethyl, diethyl or dipropyl esters of FDCA for use as monomers in the production of polyesters and other types of polymers with biobased content, comprising: reacting an aqueous feed comprising glucaric acid with a high boiling first alcohol in the presence of an acid catalyst and with removing water during the reaction, to form a first product mixture comprising a first ester of FDCA and the high boiling first alcohol; removing unreacted high boiling first alcohol from the first product mixture; combining the first ester of FDCA and the high boiling first alcohol with a lower boiling second alcohol selected from the group consisting of methanol, ethanol, isopropanol and n-propanol; transesterifying the first ester with the lower boiling second alcohol to form a second product mixture comprising a second ester of FDCA with the lower boiling second alcohol; and recovering the second ester of FDCA with the lower boiling second alcohol.

公开(公告)号：EP2752408B1

公开(公告)日：2016-05-18

申请号：EP14162827.1

申请日：2011-12-13

申请人： Archer-Daniels-Midland Company

发明人： Howard, Stephen J. ,  Sanborn, Alexandra J.

IPC分类号： C07D307/02

CPC分类号： C07D307/12 ,  C07D307/14 ,  C07D307/42 ,  C07D307/44 ,  C07D307/52