PROCESS FOR MAKING ESTERS OF 2,5-FURANDICARBOXYLIC ACID

    公开(公告)号:EP4071142A1

    公开(公告)日:2022-10-12

    申请号:EP22175991.3

    申请日:2018-06-20

    IPC分类号: C07D307/68 B01J43/00

    摘要: The present invention relates to a process for making the esters of 2,5-furandicarboxylic acid, and particularly the dimethyl, diethyl or dipropyl esters of FDCA for use as monomers in the production of polyesters and other types of polymers with biobased content, comprising: reacting an aqueous feed comprising glucaric acid with a high boiling first alcohol in the presence of an acid catalyst and with removing water during the reaction, to form a first product mixture comprising a first ester of FDCA and the high boiling first alcohol; removing unreacted high boiling first alcohol from the first product mixture; combining the first ester of FDCA and the high boiling first alcohol with a lower boiling second alcohol selected from the group consisting of methanol, ethanol, isopropanol and n-propanol; transesterifying the first ester with the lower boiling second alcohol to form a second product mixture comprising a second ester of FDCA with the lower boiling second alcohol; and recovering the second ester of FDCA with the lower boiling second alcohol.

    REGENERATIVE WATER SOFTENING DEVICE
    4.
    发明公开
    REGENERATIVE WATER SOFTENING DEVICE 有权
    再生水软化装置

    公开(公告)号:EP2708514A1

    公开(公告)日:2014-03-19

    申请号:EP12785473.5

    申请日:2012-05-11

    摘要: A regenerative demineralizer apparatus (201) comprises a cathode (8) and an anode (9); one or more water-splitting ion exchange membrane (1), having a cation exchange surface (1 a) in one surface and an anion exchange surface (1 b) in the other surface, and being laminated between the cathode and the anode so that the anion exchange surface faces the anode and the cation exchange surface faces the cathode; and a casing (7) for housing the cathode, the anode and one or more water-splitting ion exchange membrane, wherein the casing includes a first inlet (10) and a first outlet (11) serving as an inlet and an outlet of water for treatment, respectively, and a second inlet (12) and a second outlet (13) serving as an inlet and an outlet of water for regeneration, respectively, and wherein differential pressure of the water for treatment between the first inlet and the first outlet is larger than differential pressure of the water for regeneration between the second inlet and the second outlet at a flow rate identical with the flow rate of the water for treatment.

    摘要翻译: 再生式软化器装置(201)包括阴极(8)和阳极(9); 一个或多个水分解离子交换膜(1),在一个表面具有阳离子交换表面(1a),在另一个表面具有阴离子交换表面(1b),并且层叠在阴极和阳极之间,使得 阴离子交换表面面向阳极并且阳离子交换表面面向阴极; 和用于容纳阴极,阳极和一个或多个水分解离子交换膜的壳体(7),其中壳体包括用作水的入口和出口的第一入口(10)和第一出口(11) 分别用于处理的水和用作再生用水的入口和出口的第二入口(12)和第二出口(13),并且其中用于在第一入口和第一出口之间处理的水的压差 大于第二入口与第二出口之间的再生用水的压差,其流量与处理用水的流量相同。

    ION EXCHANGE
    7.
    发明公开
    ION EXCHANGE 有权
    IONENAUSTAUSCH

    公开(公告)号:EP1027158A1

    公开(公告)日:2000-08-16

    申请号:EP98946148.8

    申请日:1998-09-25

    申请人: Holbray Pty. Ltd.

    IPC分类号: B01J39/18 B01J41/12 B01J43/00

    CPC分类号: B01J43/00 B01J39/19 B01J41/13

    摘要: An ion exchange material comprising a superabsorbent polyurethane foam having an ion exchange medium contained therein. The ion exchange may be used in a process for the extraction of metal anions and cations from solutions and/or slurries including the steps of: (a) contacting a metal ion-containing solution with an ion exchange material comprising a superabsorbent polyurethane foam having an ion exchange medium contained therein; (b) separating the ion exchange material from the solution and/or slurry; and (c) recovering the sorbed metal ions from the ion exchange medium.

    摘要翻译: 一种离子交换材料,其包含其中含有离子交换介质的超吸收性聚氨酯泡沫。 离子交换可用于从溶液和/或浆料中萃取金属阴离子和阳离子的方法,包括以下步骤:(a)使含金属离子的溶液与包含超吸收性聚氨酯泡沫的离子交换材料接触,所述超吸收性聚氨酯泡沫具有 其中包含离子交换介质; (b)从溶液和/或浆液中分离离子交换材料; 和(c)从离子交换介质中回收吸附的金属离子。

    GENERATING INORGANIC POLYMER ELECTRET IN COLLOIDAL STATE
    8.
    发明公开
    GENERATING INORGANIC POLYMER ELECTRET IN COLLOIDAL STATE 失效
    ERZEUGUNG ANORGANISCHER POLYMEREKRETE在KOLLOIDALEM ZUSTAND

    公开(公告)号:EP0993336A4

    公开(公告)日:2000-07-19

    申请号:EP98930082

    申请日:1998-06-05

    申请人: HOLCOMB ROBERT R

    发明人: HOLCOMB ROBERT R

    摘要: An inorganic polymer electret in a colloidal state, for example silica, is generated by utilizing a magnetic field gradient through which the materials are passed. Referring to Figure 7, materials (5), aqueous sodium silicate and NaOH plus tripotassium citrate, are pumped from container (3) by pump (1) in conduit (2) through conduit (6) into conduit (7) out through holes (8), into conduit (13) out through holes (9), into conduit (14) out through holes (10), whereby the material reverses direction twice, and then enters into conduit (15) and chamber (11) in order, and finally is carried back to container (3) through conduit (4). Magnetic booster units (A), (B) and (C) shown in Figure 8 are added to build the electrostatic charge on the colloid faster.

    摘要翻译: 通过利用材料通过的磁场梯度产生胶体状态的无机聚合物驻极体,例如二氧化硅。 参照图7,通过导管(2)中的泵(1)将导管(2)中的材料(5),硅酸钠水溶液和NaOH加柠檬酸三钾从容器(3)泵送通过导管(7) 8)通过孔(9)进入导管(13),通过孔(10)进入导管(14),由此材料反向两次,然后依次进入导管(15)和腔室(11) 最后通过导管(4)运回容器(3)。 图8中所示的磁性增强器单元(A),(B)和(C)被加入以更快地建立胶体上的静电荷。