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1.发明公开CO-PRODUCTION OF DIALKYL CARBONATES AND DIOLS WITH TREATMENT OF HYDROXY ALKYL CARBONATE 审中-公开KOPPEL和二DIOLEN与处理羟烷基酯制造
公开(公告)号：EP1434754A1
公开(公告)日：2004-07-07
申请号：EP02744822.4
申请日：2002-07-02
IPC分类号： C07C68/06
CPC分类号： C07C68/065 , Y02P20/127 , C07C69/96
摘要： A process for the production of a dialkyl carbonate and a diol from a cyclic carbonate and an aliphatic monohydric alcohol wherein the cyclic carbonate and aliphatic monohydric alcohol are reacted in the presence of a transesterification catalyst to form a crude product stream which contains a dialkyl carbonate, a diol, a hydroxy alkyl carbonate, which is formed as an intermediate of the two step transesterification reaction, unreacted aliphatic monohydric alcohol and unreacted cyclic carbonate. The dialkyl carbonate and unreacted aliphatic monohydric alcohol are separated from the crude product stream and then the hydroxy alkyl carbonate is diminished, reduced or eliminated from the crude product stream, prior to the separation and purification steps needed to recover the diol, resulting in improved yields and product purity.
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公开(公告)号：EP2244992A1
公开(公告)日：2010-11-03
申请号：EP09711464.9
申请日：2009-01-13
CPC分类号： C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2: 1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译： 在生产环己基苯的方法中，将氢气和包含苯的液体进料引入反应区并在加氢烷基化条件下在反应区中接触以产生环己基苯。 将包含环己基苯和未反应的苯的流出物流从反应区中除去并分成至少第一部分和第二部分，其中流出物流第一部分与流出物流第二部分的质量比为至少2：1。流出物 然后将第一部分流冷却，并将冷却的流出物流第一部分循环至反应区。
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公开(公告)号：EP2200954A1
公开(公告)日：2010-06-30
申请号：EP08797654.4
申请日：2008-08-12
发明人： CHEN, Tan-jen , BENITEZ, Francisco, M. , CHENG, Jane, C. , STANAT, Jon, E. , BUCHANAN, J., Scott
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The ratio of the total number of moles of hydrogen fed to said at least one reaction zone to the number of moles of benzene fed to said at least one reaction zone is between 0.4 and 0.9: 1.
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4.发明公开INTEGRATED PROCESS FOR PREPARING DIALKYL CARBONATES WITH A CIRCULATING CATALYST 审中-公开集成工艺用于生产二烷基用圆催化剂
公开(公告)号：EP1401798A1
公开(公告)日：2004-03-31
申请号：EP02731621.5
申请日：2002-05-03
IPC分类号： C07C68/06 , C07D317/36 , C07D317/38
CPC分类号： C07C68/065 , B01J2219/00006 , C07D317/36 , C07D317/38 , C08G64/307 , C08G64/34 , Y02P20/125 , Y02P20/127 , Y02P20/584 , C07C69/96
摘要： An integrated process for the production of a dialkyl carbonate and a diol from an alkylene oxide, carbon dioxide and an aliphatic monohydric alcohol is described in which an alkylene oxide if first reacted with carbon dioxide in the presence of a homogeneous carbonation catalyst to provide a corresponding cyclic carbonate and the cyclic carbonate is then reacted with an aliphatic monohydric alcohol in the presence of the homogeneous carbonation catalyst and/or a heterogeneous transesterification catalyst and recycling the homogeneous carbonation catalyst to provide a corresponding dialkyl carbonate and diol.
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公开(公告)号：EP2200954B1
公开(公告)日：2017-06-14
申请号：EP08797654.4
申请日：2008-08-12
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公开(公告)号：EP2244992B1
公开(公告)日：2012-08-08
申请号：EP09711464.9
申请日：2009-01-13
IPC分类号： C07C2/74 , C07C37/08 , C07C39/04 , C07C45/53 , C07C13/28 , C07C49/403 , C07C37/07 , C07C409/14
CPC分类号： C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2: 1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译： 在生产环己基苯的方法中，将氢和含苯的液体原料引入反应区，并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去，并分成至少第一和第二部分，其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却，将冷却的流出物流第一部分再循环至反应区。
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公开(公告)号：EP2356087A1
公开(公告)日：2011-08-17
申请号：EP09819618.1
申请日：2009-08-17
发明人： LATTNER, James, R. , HAGEMEISTER, Mark, P. , STANAT, Jon, E. , BUCHANAN, J., Scott , DAKKA, Jihad, M. , ZUSHMA, Stephen
CPC分类号： C07C409/08 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in a reaction zone and in the presence of a catalyst comprising a cyclic imide. During the oxidation process, a portion of the reaction medium is continuously or intermittently removed from the reaction zone, is stripped of water and organic acid impurities and then returned to the reaction zone.
摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质在反应区中与含氧气体接触，并且在包含环状 酰亚胺。 在氧化过程中，反应介质的一部分从反应区连续或间歇地除去，汽提水和有机酸杂质，然后返回到反应区。
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公开(公告)号：EP2200955B1
公开(公告)日：2011-04-20
申请号：EP08797656.9
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid- to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后在加氢烷基化条件下，使苯和氢在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系具有包括在12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系的酸与金属摩尔比为约75至约750。
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公开(公告)号：EP2222620A1
公开(公告)日：2010-09-01
申请号：EP08841854.6
申请日：2008-10-02
CPC分类号： C07C2/12 , C07C2/66 , C07C7/177 , C07C15/02 , C07C37/08 , C07C39/04 , C07C41/05 , C07C45/53 , C07C2529/70 , C07C11/08 , C07C49/10 , C07C43/04
摘要： A process for oligomerizing isobutene comprises contacting a feedstock comprising isobutene with a catalyst comprising a MCM-22 family molecular sieve under conditions effective to oligomerize the isobutene, wherein said conditions including a temperature from about 45°C to less than 140°C. The isobutene may be a component of a hydrocarbon feedstock containing at least one additional C4 alkene.
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公开(公告)号：EP2200955A1
公开(公告)日：2010-06-30
申请号：EP08797656.9
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid- to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气供给至少一个反应区。 然后苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述分子筛的X-射线衍射图包括d-间距最大值在12.4±0.25,6.9±0.15,3.57±0.07和 3.42±0.07埃，并且至少有一种加氢金属产生含有环己基苯的流出物。 该催化剂体系具有约75至约750的酸与金属的摩尔比。
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