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公开(公告)号：EP3237111A1
公开(公告)日：2017-11-01
申请号：EP15819917.4
申请日：2015-12-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： ILIAS, Samia , LOVELESS, Brett , MCCARTHY, Stephen, J. , VIJAY, Rohit
CPC classification number: C07C1/20 , B01J23/06 , B01J29/405 , B01J35/023 , B01J35/1019 , B01J37/04 , B01J37/28 , C07C2523/06 , C07C2529/40 , C10G3/49 , C10G2400/20 , C10G2400/22 , C10G2400/30 , C07C11/02 , C07C15/00 , C07C9/00
Abstract: Described herein are processes for production of hydrocarbon products comprising contacting a feed comprising methanol and/or dimethyl ether with a catalyst composition, which comprises a zeolite having a constraint index from 1-12 and an active binder comprising a metal oxide with a dehydrogenation function, under conditions sufficient to form the hydrocarbon product, wherein the hydrocarbon product comprises aromatics, olefins, and/or paraffins. Also described herein are catalyst compositions comprising a zeolite having a 10-/12-membered ring framework and a microporous surface area of at least 150 m
2 /g, and from ~1 wt% to ~10 wt% of a zinc oxide binder, the catalyst composition having a zinc to aluminum atomic ratio from ~0.08 to ~8.5.Abstract translation: 本文描述了用于生产烃产物的方法，其包括使包含甲醇和/或二甲醚的进料与催化剂组合物接触，所述催化剂组合物包含约束指数为1-12的沸石和包含具有脱氢功能的金属氧化物的活性粘合剂， 在足以形成烃产物的条件下，其中烃产物包含芳族化合物，烯烃和/或链烷烃。 本文还描述了包含具有10- / 12-元环骨架和微孔表面积为至少150m 2 / g的沸石和约1重量％〜约10重量％的氧化锌粘合剂的催化剂组合物， 该催化剂组合物具有约0.08至约8.5的锌与铝的原子比。
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公开(公告)号：EP3894521A1
公开(公告)日：2021-10-20
申请号：EP19836235.2
申请日：2019-12-09
Applicant: ExxonMobil Research and Engineering Company
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3.发明公开
公开(公告)号：EP3368500A1
公开(公告)日：2018-09-05
申请号：EP16794117.8
申请日：2016-10-25
Applicant: ExxonMobil Research and Engineering Company
Inventor： ILIAS, Samia , LOVELESS, Brett, T. , MCCARTHY, Stephen, J. , O'NEILL, Brandon
CPC classification number: C07C1/20 , B01J8/04 , C07C2/12 , C07C2529/40 , C07C2529/70 , C10G3/49 , C10G50/00 , C10G2400/02 , C10L1/06 , Y02P30/20 , C07C9/14 , C07C11/06
Abstract: Processes for forming refined hydrocarbons are disclosed. Exemplary processes include providing a first mixture comprising ≧10 wt % of at least one oxygenate; contacting at least a portion of the first mixture with a methanol conversion catalyst under suitable conditions including a first pressure, P1, to yield an intermediate composition including olefins having at least two carbon atoms; introducing at least a portion of the intermediate composition to an oligomerization catalyst under suitable conditions including a second pressure, P2, to yield an effluent mixture comprising gasoline boiling range components and distillate boiling range components; and recovering at least a portion of the gasoline boiling range components and distillate boiling range components. The first and second pressure can be relatively similar. Apparatus and systems for carrying out the disclosed processes are also described.
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公开(公告)号：EP3607031A1
公开(公告)日：2020-02-12
申请号：EP18716793.7
申请日：2018-03-22
Applicant: ExxonMobil Research and Engineering Company
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Patent Agency Ranking
公开(公告)号：EP3607030A1
公开(公告)日：2020-02-12
申请号：EP18718292.8
申请日：2018-03-28
Applicant: ExxonMobil Research and Engineering Company
Inventor： BROWN, Stephen, H. , CUNNINGHAM, Brian, A. , SMILEY, Randolph, J. , ILIAS, Samia , RAICH, Brenda, A. , LE, Tien, V.
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公开(公告)号：EP3607029A1
公开(公告)日：2020-02-12
申请号：EP18716795.2
申请日：2018-03-22
Applicant: ExxonMobil Research and Engineering Company
Inventor： BROWN, Stephen, H. , CUNNINGHAM, Brian, A. , SMILEY, Randolph, J. , ILIAS, Samia , RAICH, Brenda, A. , LE, Tien, V.
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公开(公告)号：EP3679113A1
公开(公告)日：2020-07-15
申请号：EP18778608.2
申请日：2018-08-29
Applicant: ExxonMobil Research and Engineering Company
Inventor： DEIMUND, Mark, A. , ILIAS, Samia , SMILEY, Randolph, J. , DANDEKAR, Ajit, B. , WEIGEL, Scott, J. , LACY, Darryl, D.
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公开(公告)号：EP3607032A1
公开(公告)日：2020-02-12
申请号：EP18716826.5
申请日：2018-03-23
Applicant: ExxonMobil Research and Engineering Company
Inventor： BROWN, Stephen, H. , CUNNINGHAM, Brian, A. , SMILEY, Randolph, J. , ILIAS, Samia , RAICH, Brenda, A. , LE, Tien, V.
IPC: C10G67/04
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公开(公告)号：EP3083533A1
公开(公告)日：2016-10-26
申请号：EP14821941.3
申请日：2014-12-04
Applicant: ExxonMobil Research and Engineering Company
Inventor： LOVELESS, Brett , VIJAY, Rohit , ILIAS, Samia , MCCARTHY, Stephen J.
IPC: C07C15/08 , C07C1/20 , C07C15/02 , C10G3/00 , B01J38/02 , B01J38/12 , B01J23/06 , B01J29/40 , B01J29/90 , B01J35/10 , B01J37/02
CPC classification number: B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/7049 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
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