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1.发明公开
公开(公告)号：EP3906995A1
公开(公告)日：2021-11-10
申请号：EP20172717.9
申请日：2020-05-04
申请人： FRAUNHOFER-GESELLSCHAFT zur Förderung der angewandten Forschung e.V. , Centre National de la Recherche Scientifique , MOF Technologies Limited , Graphenea, S.A. , Université de Mons
发明人： HEYMANS, Nicolas , DE WEIRELD, Guy , CASABAN-JULIAN, Jose , HAMILL, Conor , ZHANG, Yuancheng , MOORE, Ashleigh , EMMERICH, Rudolf , GRAF, Matthias , RESS, Christian , SCHÖNWALD, Markus , TORIBIO, Beatriz Alonso , ZURUTUZA, Amaia , ORTEGA, Amaya , SERRE, Christian
摘要： The invention relates to a method of preparing an adsorbent material on the basis of a porous metal-organic framework (MOF) being suitable for adsorbing gases, in particular carbon dioxide (CO 2 ), comprising the steps of
(a) providing at least one porous metal-organic framework in particulate form;
(b) providing graphene oxide (GO) in particulate form; and
(c) combining the at least one porous particulate metal-organic framework with the particulate graphene oxide to obtain the adsorbent material.
Moreover, the invention relates to an adsorbent material of the type as mentioned above as well as to the use of said adsorbent material in an adsorption process, in which the adsorbent material is exposed to a gas stream so as to adsorb a gas component of the gas stream, and in which the gas component is desorbed by heating the adsorbent material by means of exposing it to high-frequency electromagnetic radiation for regeneration.-
公开(公告)号：EP2268382A2
公开(公告)日：2011-01-05
申请号：EP09733995.6
申请日：2009-04-22
发明人： DE WEIRELD, Guy , HAMON, Lomig , SERRE, Christian , DEVIC, Thomas , FEREY, Gérard , LOISEAU, Thierry
CPC分类号： B01D53/02 , B01D2253/204 , B01D2257/30 , B01D2257/304 , B01J20/226
摘要： The invention relates to a method for separating a sulphur compound from a gas mixture. It comprises contacting said gas mixture with an adsorbent which comprises a metal-organic framework (MOF) comprising a tridimensional succession of motifs having the formula: M
m O
k X
L p wherein, inter alia, M is a metal ion selected from the group consisting of Ti
4+ , V
4+ , Zr
4+ , Mn
4+ , Si
4+ , Al
3+ , Cr
3+ , V
3+ , Ga
3+ , In
3+ , Mn
3+ , Mn
2+ and Mg
2+ , L is a spacer ligand comprising a radical comprising one or more carboxylate groups.-
公开(公告)号：EP4054739A1
公开(公告)日：2022-09-14
申请号：EP20800150.3
申请日：2020-11-04
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4.发明公开
公开(公告)号：EP3498368A1
公开(公告)日：2019-06-19
申请号：EP17306798.4
申请日：2017-12-18
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Ecole Normale Supérieure de Paris , Ecole Nationale Supérieure de Chimie de Montpellier , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Université de Montpellier , Université de Versailles Saint-Quentin-en-Yvelines
发明人： SERRE, Christian , WANG, Sujing , MAURIN, Guillaume , WAHIDUZZAMAN, Mohammad , DEVAUTOUR-VINOT, Sabine
摘要： The present invention relates to crystalline Zr-, Hf-, Ln-based MOFs having aliphatic or heteroaliphatic, preferably aliphatic, linkers; a process of preparing same and uses thereof, particularly as separation/purification material, or as proton conductive material (fuel cells), or as water sorption material, or as catalyst; for example for gas separation, small molecule separation, for CO 2 /N 2 separation, separation of chiral molecules, size/shape-based molecule separation, or separation/extraction of metallic ions, as water sorption material, in adsorption-type cooling/heating systems, as catalyst, in biomass conversion systems/reactions.
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5.发明公开
公开(公告)号：EP4321181A1
公开(公告)日：2024-02-14
申请号：EP22306206.8
申请日：2022-08-10
申请人： Centre national de la recherche scientifique , École Normale Supérieure , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Instituto Superior Técnico , Faculdade De Ciências da Universidade de Lisboa
发明人： SERRE, Christian , TISSOT, Antoine , CAO, Chenchen , LUZIA GONCALVES PINTO, Moisés , SILVA, João , ANTUNES, Fernando , PINTO, Rosana
摘要： The present invention belongs to the field of nanoporous materials, in particular metal organic frameworks (MOFs) and Lewis-based gas delivery and/or slow release, or the detection of Lewis-based gas(es) in gases or liquid streams.
The present invention relates, inter alia, to a new ultra-microporous crystalline metal organic framework solid ( comprising bisphosphonic acid ligands (also refered to as Phosphonate MOF), such as MIP-210(M) and uses thereof as a carrier in Lewis-based gas (such as NO) delivery. The invention also relates to controlled release of the Lewis-based gas in wounds, for example by topical application. The invention also encompasses a synthetic method for producing the new ultra-microporous crystalline metal organic framework solid of the invention.
The MOFs of the present invention can be used in various applications such as gas carrier and/or for the controlled release of gas. The MOFs of the present invention thus are very versatile and have therapeutic and non therapeutic applications.-
公开(公告)号：EP3978113A1
公开(公告)日：2022-04-06
申请号：EP20382882.7
申请日：2020-10-05
申请人： Consejo Superior de Investigaciones Científicas (CSIC) , Universitat Politècnica de València , Paris Sciences et Lettres , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Centre national de la recherche scientifique , Ecole Normale Supérieure
发明人： NAVALÓN OLTRA, Sergio , VALLÉS GARCÍA, Cristina , CABRERO ANTONINO, María , GARCÍA GÓMEZ, Hermenegildo , SERRE, Christian , MOUCHAHAM, Georges , ZHOU, Lin
摘要： The present invention relates to metal-organic frameworks (MOFs) which contain trimetallic centres with pyrazole as a ligand in the structure thereof. Particularly, it relates to MOFs which contain units of formula (I). The present invention also relates to a photocatalytic method for generating H 2 starting from liquid water or vapour using said materials.
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公开(公告)号：EP3681627A1
公开(公告)日：2020-07-22
申请号：EP18765456.1
申请日：2018-09-12
申请人： Centre National de la Recherche Scientifique , Ecole Normale Supérieure de Paris , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Université de Versailles Saint-Quentin-en-Yvelines , Instituto Superior Técnico
发明人： SERRE, Christian , PINTO, Moisés L.
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8.发明公开
公开(公告)号：EP3680311A1
公开(公告)日：2020-07-15
申请号：EP19305025.9
申请日：2019-01-08
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Instituto Politécnico De Bragança , Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris , Ecole Normale Supérieure de Paris , Universidade Do Porto
摘要： The present invention relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(AI) metal-organic framework, for separating C6 alkane isomers into linear, mono-branched and di-branched isomers. The present invention also relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(AI) metal-organic framework, preferably in combination with Zeolite 5A for producing higher research octane number gasoline blends. Also within the scope of the invention is a system for separating C6 and C5 alkane isomer mixtures into linear, mono-branched and di-branched fractions.
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9.发明授权SOLIDE HYBRIDE CRISTALLIN POREUX REDUCTIBLE POUR LA SEPARATION DE MELANGES DE MOLECULES AYANT DES DEGRES ET/OU UN NOMBRE D'INSATURATIONS DIFFERENTS 有权还原，多孔结晶混合固体FOR分离有不同程度的和/或单元不饱和不同数量分子的混合物
公开(公告)号：EP2294036B1
公开(公告)日：2012-09-05
申请号：EP09772658.2
申请日：2009-06-11
申请人： Centre National de la Recherche Scientifique - CNRS , Université de Caen Basse Normandie , Université de Versailles Saint-Quentin-en-Yvelines , Korea Research Institute of Chemical Technology (KRICT)
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公开(公告)号：EP2193136A1
公开(公告)日：2010-06-09
申请号：EP08861269.2
申请日：2008-10-01
申请人： Centre National de la Recherche Scientifique- CNRS , Université de Versailles Saint-Quentin-en-Yvelines
发明人： HORCAJADA CORTES, Patricia , FEREY, Gérard , SERRE, Christian , GREF, Ruxandra , COUVREUR, Patrick
CPC分类号： C07F15/025
摘要： The invention relates to solid organometallic hybrids with modified surface. Said solid may be used for example for the encapsulation and vectoring of molecules of interest such as active pharmaceutical agents, compounds of interest in cosmetic s and markers, for example, contrast agents. Said solids show good results in terms of loading capacity in medicament agents and in biocompatibility.
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