PROCESS FOR DIMERIZING LIGHT OLEFINS
    1.
    发明公开
    PROCESS FOR DIMERIZING LIGHT OLEFINS 审中-公开
    工艺二聚化LICHTOLEFINEN

    公开(公告)号:EP1611071A1

    公开(公告)日:2006-01-04

    申请号:EP04718979.0

    申请日:2004-03-10

    摘要: The invention relates to a process for dimerizing lower, olefinic hydrocarbons. In particular, the present invention concerns a process for dimerizing C3-, C4 and C5-olefins with a medium pore zeolite under process conditions allowing selective dimerization. According to the invention, fresh olefinic hydrocarbon feedstock is fed to a reaction system including at least one reaction zone and at least one separation zone. The olefinic hydrocarbon feedstock is contacted with an acid catalyst at conditions in which at least a part of the olefins dimerizes. The effluent from the reaction zone is conducted to the separation zone where dimerized reaction product is separated from said effluent.

    A METHOD FOR PRODUCTION OF MIDDLE DISTILLATE COMPONENTS FROM GASOLINE COMPONENTS BY OLIGOMERIZATION OF OLEFINS
    2.
    发明公开
    A METHOD FOR PRODUCTION OF MIDDLE DISTILLATE COMPONENTS FROM GASOLINE COMPONENTS BY OLIGOMERIZATION OF OLEFINS 有权
    用于生产汽油组分中间馏分油成分研究烯烃的低聚

    公开(公告)号:EP2649161A2

    公开(公告)日:2013-10-16

    申请号:EP11805893.2

    申请日:2011-12-09

    申请人: Neste Oil Oyj

    IPC分类号: C10G50/00 C10L1/08

    摘要: The present invention relates to a method for producing middle distillate fuel components from gasoline fuel component fractions by oligomerization of olefins. In this method a liquid blend composition feed comprising 0-90% by weight of C5, 5-95% by weight of C6, 0-30% by weight of C7 hydrocarbons containing olefins is fed into an oligomerization reactor. Optionally at least one oxygenate is used together with the feed. Said feed is oligomerized by contacting it with an ion exchange resin catalyst at a temperature from 30°C to 200°C and at a pressure from 500 to 2000 kPa. The un-reacted feed is separated by distillation. Optionally, the recovered distillate is hydrogenated for forming a product suitable for use as a middle distillate fuel component.

    摘要翻译: 本发明涉及一种用于通过烯烃的低聚生产从汽油燃料组分馏分的中间馏分燃料组分的方法。 在该方法的液体共混物组合物饲料,其包含0-90%(重量)C5,按重量计C6的5-95%,按重量计7烃的含烯烃的0-30%是在低聚反应器中供入。 任选的至少一种含氧化合物与所述进料一起使用。 所述进料通过在从30℃至200℃的温度下和在500〜2000千帕的压力下用离子交换树脂催化剂接触它低聚。 未反应的进料通过蒸馏分离。 任选地,回收的馏出氢化用于形成适合用作中间馏分燃料组分的产物。

    PROCESS FOR OLIGOMERIZING OLEFINS
    3.
    发明公开
    PROCESS FOR OLIGOMERIZING OLEFINS 审中-公开
    低聚烯烃的方法

    公开(公告)号:EP2181081A1

    公开(公告)日:2010-05-05

    申请号:EP08787746.0

    申请日:2008-08-25

    申请人: Neste Oil Oyj

    IPC分类号: C07C2/12 C10G50/00

    摘要: A process for oligomerizing olefinic, lower hydrocarbons. The process comprises the steps of feeding a fresh olefinic hydrocarbon feedstock to a reaction zone; contacting the olefinic hydrocarbons of the feedstock with an acidic catalyst in the reaction zone in order to dimerize at least a part of the olefinic hydrocarbons, withdrawing an effluent containing oligomerized olefins from the reaction zone; and conducting the effluent to a separation zone, wherein the oligomerization reaction product is separated from said effluent. According to the invention, the reaction is carried out in homogeneous phase comprising a solvent for olefinic hydrocarbons, maintained at supercritical conditions. By using supercritical carbon dioxide as a solvent deactivation rate of catalyst can be diminshed. Carbon dioxide is easy to remove from the product mixture and spent reaction medium can be used for regeneration of the catalyst.

    摘要翻译: 烯烃低级烃低聚的方法。 该方法包括将新鲜烯烃原料加入反应区的步骤; 使所述原料的烯烃与酸性催化剂在所述反应区中接触以使至少一部分所述烯烃二聚化,从所述反应区排出含有低聚烯烃的流出物; 并将流出物引入分离区,其中将低聚反应产物与所述流出物分离。 根据本发明,反应在含有维持超临界条件的烯烃溶剂的均相中进行。 通过使用超临界二氧化碳作为溶剂,可以使催化剂的失活速率降低。 二氧化碳容易从产物混合物中除去,并且废反应介质可用于催化剂的再生。

    CATALYST AND METHOD FOR THE PREPARATION THEREOF
    10.
    发明公开
    CATALYST AND METHOD FOR THE PREPARATION THEREOF 有权
    催化剂及其制备方法

    公开(公告)号:EP1706204A1

    公开(公告)日:2006-10-04

    申请号:EP04798322.6

    申请日:2004-11-24

    申请人: Neste Oil Oyj

    IPC分类号: B01J23/40 B01J37/02

    摘要: The invention relates to a noble metal catalyst for hydrocarbon conversion, to a method for the preparation thereof based on gas phase technique, to the use of the catalyst in reactions such as ring- opening, isomerisation, alkylation, hydrocarbon reforming, dry reforming, hydrogenation and dehydrogenation reactions, and to a method for the manufacture of middle distillates. Said noble metal catalyst comprises a group VIII metal selected from platinum, palladium, ruthenium, rhodium, iridium, or mixtures of combinations thereof on a support, and the catalyst activates carbon monoxide at a temperature below 323 K.

    摘要翻译: 本发明涉及用于烃转化的贵金属催化剂,涉及基于气相技术制备其的方法,涉及该催化剂在诸如开环,异构化,烷基化,烃重整,干重整,氢化 和脱氢反应,并涉及制造中间馏分的方法。 所述贵金属催化剂包含选自铂,钯,钌,铑,铱或它们的组合的混合物的VIII族金属在载体上,并且该催化剂在低于323K的温度下活化一氧化碳。