A ZEOLITE CATALYST FOR SKELETAL ISOMERISATION OF OLEFINS
    2.
    发明公开
    A ZEOLITE CATALYST FOR SKELETAL ISOMERISATION OF OLEFINS 有权
    制造用于烯烃骨架的沸石催化剂

    公开(公告)号:EP1610895A1

    公开(公告)日:2006-01-04

    申请号:EP04718662.2

    申请日:2004-03-09

    申请人: Neste Oil Oyj

    IPC分类号: B01J29/70 C01B39/48 C07C5/27

    摘要: The present invention relates to an active and selective zeolite catalyst having MTT structure that is useful in skeletal isomerisation of light olefins. It also relates to a method for the manufacture of said catalyst. The method for the manufacture of the zeolite catalyst having MTT structure comprises the steps of a) Preparing of a gel mixture capable of forming crystalline material, and said mixture comprising sources of alkali or alkaline earth metal (M,) of an oxide of a trivalent element (X), of an oxide of a tetravalent element (Y), water and a directing agent (R), and said mixture having a composition, in terms of molar ratios, within the following ranges; (I) b) Maintaining of said mixture under sufficient conditions, including a temperature of from about 100 °C to about 250 °C, under dynamic mode of stirring until crystals of said material are formed, recovering the material, and b) Removing of said directing agent (R) partly or totally with a calcination procedure, whereby a zeolite catalyst having MTT structure is obtained.