摘要:
Adherent metal coatings are provided on articles comprising a polyimide of 3,3',4,4'-tetracarboxybiphenyl and 4-aminoethyl ether by non-electrolytic metal deposition (e.g., physical vapor deposition or electroless deposition) following a treatment method comprising steps of contact with strong nitric acid, with strong sulfuric acid and with an aqueous alkaline permanganate solution, the first two steps being followed by a water rinse. The metallized article is then heat-treated for at least about 30 minutes at a temperature in the range of about 60-100°C. Optional steps are treatment with an alkaline solution after sulfuric acid treatment and deposition of a further metal coating such as an electrolytic coating; said further metal deposition is also followed by a heat treatment step.
摘要:
Iodonation of novolak resin or polyphenylene ether followed by the metatheses of the resulting iodonated product with a polyhalometal or metalloid salt can provide a photoactive cure catalyst or thermally active cure catalyst for cationically polymerizable organic materials. A copper cocatalyst has been found useful in thermal curing.
摘要:
The adhesion of metal coatings deposited by electroless deposition on polycarbonate-addition polymer substrates, especially polycarbonate-ABS substrates, containing up to about 85% (by weight) polycarbonate is improved by first contacting the substrate with an alkali metal hydroxide solution for about 1-2 minutes, followed by an alkaline permanganate solution and a reducing agent to remove any manganese residue.
摘要:
Curable compositions contain a low molecular weight polyphenylene ether and a polyepoxide composition containing brominated and non-brominated bisphenol polyglycidyl ethers, in combination with further components including specific catalysts. Said compositions are preferably free from hardeners for epoxy resins. They may be used in the preparation of bonding sheets which are useful in the manufacture of multilayer printed circuit assemblies and which have excellent physical and electrical properties.
摘要:
Aryl ester-grafted polyphenylene ethers are prepared by heating a polyphenylene ether with an olefinic aryl ester, usually an unsubstituted or substituted phenyl acrylate. The products react with lactams such as ε-caprolactam in the presence of lactam polymerization catalysts to produce phenylene ether-amide copolymers.
摘要:
The invention provides a composition for a platable resinous substrate having enhanced heat performance comprising: a thermoplastic mixture of at least one polyphenylene ether and at least one poly(alkenylaromatic) compound, at least one inorganic filler material and optionally at least one rubber compound.
摘要:
Increases in surface resistivity of electroless nickel coatings on polycarbonate-containing substrates are inhibited by employing two electroless nickel plating solutions. The first solution is one which deposits a metal layer containing phosphorus, if any, in an amount up to 5% by weight and is used to deposit a layer at least 0.5 micron thick. The second solution is one which deposits a layer containing phosphorus in the amount of at least 5% and preferably at least 6% by weight. Another metal layer may be interposed between the two nickel layers.