摘要:
A coating process and system (20) for an article (10) having a substrate (22) formed of a metal alloy that is prone to the formation of a secondary reaction zone (SRZ) (36). The coating system (20) includes an aluminum-containing overlay coating (24) and a stabilizing layer (42) between the overlay coating (24) and the substrate (22). The overlay coating (24) contains aluminum in an amount greater by atomic percent than the metal alloy of the substrate (22), such that there is a tendency for aluminum to diffuse from the overlay coating (24) into the substrate (22). The stabilizing layer (42) is predominantly or entirely formed of at least one platinum group metal (PGM), namely, platinum, rhodium, iridium, and/or palladium. The stabilizing layer (42) is sufficient to inhibit diffusion of aluminum from the overlay coating (24) into the substrate (22) so that the substrate (22) remains essentially free of an SRZ (36) that would be deleterious to the mechanical properties of the alloy.
摘要:
An intermetallic composition suitable for use as an environmentally-protective coating (24) on surfaces of components (10) used in hostile thermal environments, including the turbine, combustor and augmentor sections of a gas turbine engine. The coating (24) contains the gamma-prime (Ni 3 Al) nickel aluminide intermetallic phase and either the beta (NiAl) nickel aluminide intermetallic phase or the gamma solid solution phase. The coating (24) has an average aluminum content of 14 to 30 atomic percent and an average platinum-group metal content of at least 1 to less than 10 atomic percent, the balance of the coating (24) being nickel, incidental impurities, and optionally hafnium.
摘要:
An intermetallic composition suitable for use as an environmentally-protective coating (24) on surfaces of components (10) used in hostile thermal environments, including the turbine, combustor and augmentor sections of a gas turbine engine. The coating (24) contains the gamma-prime (Ni 3 Al) nickel aluminide intermetallic phase and either the beta (NiAl) nickel aluminide intermetallic phase or the gamma solid solution phase. The coating (24) has an average aluminum content of 14 to 30 atomic percent and an average platinum-group metal content of at least 1 to less than 10 atomic percent, the balance of the coating (24) being nickel, one or more of chromium, silicon, tantalum, and cobalt, optionally one or more of hafnium, yttrium, zirconium, lanthanum, and cerium, and incidental impurities.
摘要:
A coating applied as a two layer system. The outer layer (22) is an oxide of a group IV metal selected from the group consisting of zirconium oxide, hafnium oxide and combinations thereof, which are doped with an effective amount of a lanthanum series oxide. These metal oxides doped with a lanthanum series addition comprises a high weight percentage of the outer coating (22). When the zirconium oxide is doped with an effective amount of a lanthanum series oxide, a dense reaction layer is formed at the interface of the outer layer of TBC and the CMAS. This dense reaction layer prevents CMAS infiltration below it. The second layer, or inner layer (20) underlying the outer layer (22), comprises a layer of partially stabilized zirconium oxide.
摘要:
An overlay coating (24) for articles used in hostile thermal environments. The coating (24) has a predominantly gamma prime-phase nickel aluminide (Ni 3 Al) composition suitable for use as an environmental coating and as a bond coat for a thermal barrier coating. The coating (24) has a composition of, by weight, at least 6% to about 15% aluminum, about 2% to about 5% chromium, optionally one or more reactive elements in individual or combined amounts of up to 4%, optionally up to 2% silicon, optionally up to 60% of at least one platinum group metal, and the balance essentially nickel. A thermal-insulating ceramic layer (26) may be deposited on the coating (24).
摘要:
A coating system (14) and coating method for damping vibration in an airfoil (10) of a rotating component of a turbomachine. The coating system (14) includes a metallic coating (18) on a surface of the airfoil (10), and a ceramic coating (20) overlying the metallic coating (18). The metallic coating (18) contains metallic particles (22) dispersed in a matrix (24) having a metallic and/or intermetallic composition. The metallic particles (22) are more ductile than the matrix (24), and have a composition containing silver and optionally tin. The method involves ion plasma cleaning the surface of the airfoil (10) before depositing the metallic coating (18) and then the ceramic coating (20).
摘要:
A process for reducing the incidence of a secondary reaction zone (SRZ) in alloys prone to SRZ formation, particularly superalloys that have a high refractory element content is described. The process finds use with articles having a wall region (22) that defines external and internal surfaces on the exterior and within the article, respectively. Diffusion coatings (32) are formed on the internal and external surfaces of the article, with at least the diffusion coating (32) on the external surface comprising an additive layer (34) and a diffusion zone (36) that is beneath the additive layer (34) and extends into the wall region (22). The additive layer (34) and at least a portion of the diffusion zone (36) of the external diffusion coating (32) is then removed to define an exposed surface region on the exterior of the article. An overlay coating (24) is then deposited on the exposed surface region.
摘要:
An article includes a substantially single crystal piece (40) having a composition consisting essentially of, in weight percent, from 0.4 to 6.5 percent ruthenium, from 3 to 8 percent rhenium, from 5.8 to 10.7 percent tantalum, from 4.25 to 17.0 percent cobalt, from 0.1 to 2.0 percent hafnium, from 0.02 to 0.4 percent carbon, from 0.001 to 0.005 percent boron, from 0 to 0.02 percent yttrium, from 1 to 4 percent molybdenum, from 1.25 to 10 percent chromium, from 0.5 to 2.0 percent niobium, from 0.05 to 0.5 percent zirconium, from 5.0 to 6.6 percent aluminum, from 0 to 2.0 percent titanium, from 3.0 to 7.5 percent tungsten, and from 0.1 to 6 percent of platinum, iridium, rhodium, and palladium, and combinations thereof, balance nickel and incidental impurities.