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1.发明公开ALKALI-CONTAINING CATALYST FORMULATIONS FOR LOW AND MEDIUM TEMPERATURE HYDROGEN GENERATION 审中-公开ALKALIMETALLHATIGE催化剂配方用于制氢，在低温和MEDIUM
公开(公告)号：EP1587753A1
公开(公告)日：2005-10-26
申请号：EP03814316.0
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond, F. , YACCATO, Karin , LESIK, Andreas , BROOKS, Christopher, James
CPC分类号： C01B3/16 , B01J23/58 , B01J23/6567 , B01J37/0205 , B01J2219/00364 , B01J2219/00527 , B01J2219/00691 , B01J2219/00745 , B01J2219/00747 , C01B2203/0283 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C40B30/08 , C40B40/18 , C40B60/14 , Y02P20/142 , Y02P20/52
摘要： The invention is directed toward methods of using alkali-containing catalysts for generation of hydrogen-rich gas at temperatures of less than about 260 °C. A WGS catalyst of the invention may have the following composition: a) at least one of Pt, Ru, their oxides and mixtures thereof; b) Na, its oxides or mixtures thereof; and optionally, c) Li, its oxides and mixtures thereof. The catalysts may be supported on a variety of catalyst support materials. The invention is also directed toward catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.
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2.发明公开PLATINUM-ALKALI/ALKALINE-EARTH CATALYST FORMULATIONS FOR HYDROGEN GENERATION 审中-公开氢发生用铂 - 碱/碱土催化剂配方
公开(公告)号：EP1578689A2
公开(公告)日：2005-09-28
申请号：EP03814106.5
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond, F. , YACCATO, Karin , LESIK, Andreas , BROOKS, Christopher, James , PHILLIPS, Cory, Bernard
CPC分类号： B01J23/652 , B01J23/58 , B01J23/63 , B01J23/648 , B01J23/6562 , B01J23/8946 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , Y02P20/52
摘要： A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift catalyst in the presence of water, preferably at a temperature of less than about 450°C, to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst comprising: a) Pt, its oxides or mixtures thereof; b) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, their oxides and mixtures thereof; and c) at least one of Sc, Y, Ti, Zr, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ir, Ni, Pd, La, Ce, Pr, Nd, Sm, Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
摘要翻译： 公开了用于生产富氢气体如富氢合成气的方法和催化剂以及燃料处理装置。 根据该方法，含CO的气体（例如合成气）在水存在下接触水煤气变换催化剂，优选在低于约450℃的温度下，产生富氢气体，例如 富氢合成气。 还公开了水煤气变换催化剂，其包含：a）Pt，其氧化物或其混合物; b）Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba中的至少一种，它们的氧化物及其混合物; 和c）Sc，Y，Ti，Zr，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Co，Ir，Ni，Pd，La，Ce，Pr，Nd，Sm，Eu ，它们的氧化物及其混合物。 WGS催化剂可以负载在载体上，例如氧化铝，氧化锆，二氧化钛，二氧化铈，氧化镁，镧系元素，氧化铌，氧化钇和氧化铁中的任何一种或其组合。 还公开了包含这种水煤气变换催化剂的燃料处理器。
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3.发明公开
公开(公告)号：EP1572579A2
公开(公告)日：2005-09-14
申请号：EP03814171.9
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond. F. , HERRMANN, Michael , YACCATO, Karin , BROOKS, Christopher, James
IPC分类号： C01B3/00 , B01J23/80 , B01J23/843 , B01J27/057 , B01J19/00 , B01J23/835
CPC分类号： B01J23/835 , B01J23/80 , B01J23/825 , B01J23/8435 , B01J27/0576 , B01J2219/00364 , B01J2219/00378 , B01J2219/00536 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00691 , B01J2219/00702 , B01J2219/00745 , B01J2219/00747 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1041 , C01B2203/1052 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , C40B60/14 , Y02E60/324 , Y02P20/52
摘要： The invention relates to methods of using noble metal-free nickel catalysts to generate a hydrogen-rich gas from gas mixtures containing carbon monoxide and water, such as water-containing syngas mixtures, where the nickel may exist in either a supported or a bulk state. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof. The invention is also directed toward noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.
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公开(公告)号：EP1578688A2
公开(公告)日：2005-09-28
申请号：EP03800058.4
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond, F. , YACCATO, Karin , STRASSER, Peter , HERRMANN, Michael , GRASSELLI, Robert, K. , BROOKS, Christopher, James , PHILLIPS, Cory, Bernard
CPC分类号： B01J23/52 , B01J23/48 , B01J23/50 , B01J23/66 , B01J23/755 , B01J23/835 , B01J23/89 , B01J23/894 , B01J23/8946 , B01J23/8966 , B01J23/8973 , B01J23/8993 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , Y02P20/142 , Y02P20/52
摘要： A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift ('WGS') catalyst, in the presence of water, preferably at a temperature of less than about 450 °C to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) at least one of Rh, Ni, Pt, their oxides and mixtures thereof; b) at least one of Cu, Ag, Au, their oxides and mixtures thereof; and c) at least one of K, Cs, Sc, Y, Ti, Zr, V, Mo, Re, Fe, Ru, Co, Ir, Pd, Cd, In, Ge, Sn, Pb, Sb, Te, La, Ce, Pr, Nd, Sm, Eu, their oxides and mixtures thereof. Another disclosed catalyst formulation comprises Rh, its oxides or mixtures thereof, Pt, its oxides or mixtures thereof and Ag, its oxides or mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, pervoskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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5.发明公开PLATINUM AND RHODIUM AND/OR IRON CONTAINING CATALYST FORMULATIONS FOR HYDROGEN GENERATION 审中-公开铂和铑和/或含铁催化剂组合物用于制氢
公开(公告)号：EP1578529A2
公开(公告)日：2005-09-28
申请号：EP03814187.5
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond F. , YACCATO, Karin , STRASSER, Peter , GRASSELLI, Robert, K. , BROOKS, Christopher, James , PHILLIPS, Cory, Bernard
IPC分类号： B01J23/89 , B01J23/63 , B01J23/644
CPC分类号： B01J23/622 , B01J23/464 , B01J23/56 , B01J23/624 , B01J23/63 , B01J23/6445 , B01J23/6525 , B01J23/8906 , B01J23/8933 , B01J23/894 , B01J23/8966 , B01J23/8973 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , Y02P20/52
摘要： A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof, b) at least one of Fe and Rh, their oxides and mixtures thereof, and c) at least one member selected from the group consisting of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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6.发明公开PLATINUM-FREE RUTHENIUM-COBALT CATALYST FORMULATIONS FOR HYDROGEN GENERATION 审中-公开免费铂钌 - 钴催化剂组合物技术制氢
公开(公告)号：EP1581456A2
公开(公告)日：2005-10-05
申请号：EP03814107.3
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond, F. , YACCATO, Karin , HERRMANN, Michael , LESIK, Andreas , BROOKS, Christopher, James , PHILLIPS, Cory, Bernard
IPC分类号： C01B3/16 , B01J23/652 , B01J23/89
CPC分类号： C01B3/16 , B01J19/0046 , B01J23/6525 , B01J23/8913 , B01J23/894 , B01J23/8946 , B01J23/8993 , B01J2219/00387 , B01J2219/00536 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00691 , B01J2219/00745 , B01J2219/00747 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , C40B60/14 , Y02P20/52
摘要： A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method, a CO-containing gas, such as a syngas, contacts a platinum-free ruthenium-cobalt water gas shift ('WGS') catalyst, in the presence of water and preferably at a temperature of less than about 450°C, to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a platinum-free ruthenium-cobalt water gas shift catalyst formulated from: a) Ru, its oxides or mixtures thereof; b) Co, Mo, their oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Ti, Zr, Cr, Fe, La, Ce, Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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公开(公告)号：EP1581339A2
公开(公告)日：2005-10-05
申请号：EP03814265.9
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , BROOKS, Christopher, James , CARHART, Raymond, F. , YACCATO, Karin , LESIK, Andreas
CPC分类号： B01J21/066 , B01J19/0046 , B01J21/06 , B01J23/42 , B01J23/58 , B01J23/75 , B01J23/894 , B01J23/8946 , B01J23/898 , B01J23/8986 , B01J23/8993 , B01J37/0201 , B01J37/0205 , B01J37/0244 , B01J37/031 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00689 , B01J2219/00702 , B01J2219/00745 , B01J2219/00747 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1041 , C01B2203/1052 , C01B2203/107 , C01B2203/1082 , C40B30/08 , C40B40/18 , Y02P20/52
摘要： The invention relates to methods of depositing platinum, vanadium and cobalt on a surface. The invention also relates to preparation of platinum- and sodium-containing catalysts. More particularly, the invention includes methods of preparing both precious metal- and non-precious metal-containing catalysts for the generation of a hydrogen-rich gas from gas mixtures containing carbon monoxide and water, such as water-containing syngas mixtures.
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8.发明公开
公开(公告)号：EP1572353A2
公开(公告)日：2005-09-14
申请号：EP03808536.1
申请日：2003-12-18
发明人： HAGEMEYER, Alfred , CARHART, Raymond, F. , YACCATO, Karin , STRASSER, Peter , GRASSELLI, Robert, K. , BROOKS, Christopher, James. , PHILLIPS, Cory, Bernard
IPC分类号： B01J23/40 , B01J23/58 , B01J23/62 , B01J23/63 , B01J23/648 , B01J23/652 , B01J23/656 , B01J23/89 , C01B3/32
CPC分类号： C01B3/16 , B01J23/40 , B01J23/462 , B01J23/56 , B01J23/58 , B01J23/622 , B01J23/63 , B01J23/6482 , B01J23/6525 , B01J23/6562 , B01J23/89 , B01J23/8933 , B01J23/894 , B01J23/8946 , B01J23/8993 , B01J37/024 , B01J2219/00585 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00662 , B01J2219/00691 , B01J2219/00702 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , H01M8/0618 , H01M8/0668 , Y02P20/52
摘要： A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450°C to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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