公开(公告)号：EP1603182A1

公开(公告)日：2005-12-07

申请号：EP04029067.8

申请日：2004-12-08

申请人： HONDA MOTOR CO., Ltd.

发明人： Kanaoka, Nagayuki ,  Mitsuta, Naoki ,  Hama, Yuichiro ,  Takahashi, Ryoichiro ,  Souma, Hiroshi ,  Iguchi, Masaru ,  Asano, Yoichi

IPC分类号： H01M8/10 ,  C08J5/22

CPC分类号： H01M8/1032 ,  H01M4/8605 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1048 ,  H01M8/1081 ,  Y02P70/56

摘要： A membrane electrode assembly for a polymer electrolyte fuel cell has superior power generation characteristics under low humidity conditions and superior starting characteristics under low temperature conditions. In the membrane electrode assembly for a polymer electrolyte fuel cell in which a polymer electrolyte membrane is disposed between a pair of electrodes containing a catalyst, the polymer electrolyte membrane has a polymer segment A having an ion conductive component and a polymer segment B not having an ion conductive component. Furthermore, in the case in which the polymer electrolyte membrane is immersed in'water at 90°C for 30 minutes, absorbed water which exhibits a thawing temperature of from -30 to 0°C is in a range from 0.01 to 3.0 g per 1 g of the polymer.

摘要翻译： 用于聚合物电解质燃料电池的膜电极组件在低湿度条件下具有优异的发电特性，并且在低温条件下具有优异的起始特性。 在其中聚合物电解质膜设置在包含催化剂的一对电极之间的聚合物电解质燃料电池的膜电极组件中，聚合物电解质膜具有具有离子传导性成分的聚合物链段A和不具有 离子传导元件。 此外，在将聚合物电解质膜在90℃的水中浸渍30分钟的情况下，解冻温度为-30〜0℃的吸收水的浓度为0.01〜3.0g / 1 g的聚合物。

公开(公告)号：EP1482589A2

公开(公告)日：2004-12-01

申请号：EP04003826.7

申请日：2004-02-19

申请人： JSR Corporation ,  HONDA MOTOR CO., LTD.

发明人： Masaka, Fusazumi ,  Kita, Kiyonori ,  Hama, Yuichiro ,  Iguchi, Masaru ,  Mitsuta, Naoki ,  Yano, Junichi

IPC分类号： H01M8/12 ,  H01M4/88 ,  H01M8/10

CPC分类号： C08J5/122 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1081 ,  Y02P70/56

摘要： The invention provides a manufacturing process for MEA that enables sufficient bond strength among an electrolyte membrane and electrode substrates even when the electrolyte membrane comprises a heat-resistant material such as an aromatic polymer.
The process comprises pressure bonding an electrolyte membrane with catalyzed electrode substrates to form a membrane-electrode assembly, wherein a good solvent for the electrolyte membrane is applied to at least one of facing surfaces of the opposed electrode substrate and the electrolyte membrane prior to the pressure bonding. The electrolyte membrane may comprise a sulfonated aromatic polymer. The good solvent for the electrolyte membrane may be an aprotic dipolar solvent.

摘要翻译： 本发明提供了一种用于MEA的制造方法，即使当电解质膜包括诸如芳族聚合物的耐热材料时，也能够在电解质膜和电极基板之间实现足够的粘结强度。 该方法包括将电解质膜与催化的电极基底压接以形成膜 - 电极组件，其中用于电解质膜的良溶剂被施加到相对电极基底和电解质膜的至少一个相对表面 在压接之前。 电解质膜可以包含磺化芳族聚合物。 电解质膜的良溶剂可能是非质子偶极溶剂。

公开(公告)号：EP1420473A1

公开(公告)日：2004-05-19

申请号：EP03026194.5

申请日：2003-11-17

申请人： HONDA MOTOR CO., Ltd.

发明人： Sohma, Hiroshi, ,  Iguchi, Masaru ,  Kanaoka, Nagayuyki ,  Kaji, Hayato ,  Morikawa, Hiroshi ,  Mitsuta, Naoki

IPC分类号： H01M8/10

CPC分类号： H01M8/1039 ,  C08G65/4025 ,  C08G65/4056 ,  C08G2650/64 ,  C08L65/00 ,  C08L71/00 ,  H01M4/8605 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1025 ,  H01M2008/1095 ,  H01M2300/0082 ,  C08L2666/22

摘要： The present invention provides an electrode structure for polymer electrolyte fuel cells, inexpensive, and exhibiting excellent power production capacity and durability even under high temperature/low humidity conditions, and also provides a polymer electrolyte fuel cell which incorporates the same electrode structure. The present invention also provides an electrical device and transportation device, each incorporating the same polymer electrolyte fuel cell. The electrode structure comprises a pair of electrode catalyst layers 1,1, each containing a catalyst supported by carbon particles, and polymer electrolyte membrane 2 placed between these electrode catalyst layers 1,1. The polymer electrolyte membrane 2 is of a sulfonated polyarylene composed of 0.5 to 100% by mol of the first repeating unit represented by the general formula (1) and 0 to 99.5% by mol of the second repeating unit represented by the general formula (2):
(wherein, A is a divalent organic group; and a benzene ring includes its derivative),
(wherein, -W- is a divalent electron attracting group; - T- is a divalent organic group; and R 1 to R 8 are a hydrogen atom or fluorine atom, an alkyl group, fluorine-substituted alkyl group, allyl group, aryl group or cyano group, and may be the same or different).

摘要翻译： 本发明提供一种廉价的电池结构体，即使在高温/低湿条件下也具有优异的发电量和耐久性，并且还提供了结合了相同的电极结构的固体高分子型燃料电池。 本发明还提供了一种电气装置和运输装置，每个都装有相同的聚合物电解质燃料电池。 电极结构包括一对电极催化剂层1,1，每个电极催化剂层1,1包含由碳颗粒负载的催化剂和位于这些电极催化剂层1,1之间的聚合物电解质膜2。 聚合物电解质膜2是由通式（1）表示的第一重复单元为0.5〜100摩尔％，通式（2）表示的第二重复单元为0〜99.5摩尔％的磺化聚亚芳基 ）：（其中，A为二价有机基团，苯环包括其衍生物），CHEM（其中，-W-为二价吸电子基团; -T为二价有机基团; R 1至R 8为氢原子或氟原子，烷基，氟取代的烷基，烯丙基，芳基或氰基，可以相同或不同）。

公开(公告)号：EP1575115B1

公开(公告)日：2010-02-03

申请号：EP05005312.3

申请日：2005-03-10

申请人： HONDA MOTOR CO., LTD. ,  JSR Corporation

发明人： Otsuki, Toshihiro ,  Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Mitsuta, Naoki ,  Soma, Hiroshi

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01B1/12 ,  G01N27/00 ,  C25B9/00

CPC分类号： C08J5/2256 ,  C08J2365/02 ,  C08J2371/12 ,  H01B1/122 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039

公开(公告)号：EP1619739A3

公开(公告)日：2007-02-28

申请号：EP05015000.2

申请日：2005-07-11

申请人： Honda Motor Co., Ltd.

发明人： Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Sohma, Hiroshi

IPC分类号： H01M8/10 ,  C08J5/22 ,  C25B9/10

CPC分类号： C08J5/2256 ,  C08J2371/12 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2300/0082

摘要： A membrane-electrode structure for a solid polymer fuel cell excellent in power generation performance and durability and a solid polymer fuel cell comprising the membrane-electrode structure are provided. In the membrane-electrode structure for a solid polymer fuel cell in which the polymer electrolyte membrane 2 is sandwiched between a pair of electrodes 1 containing a catalyst, the polymer electrolyte membrane 1 comprises a constituent unit (A) which has an ion conductive moiety consisting of a sulfonic acid group and is represented by the following general formula (I) and a constituent unit (B) consisting only of a non-ion conductive moiety which has a number average molecular weight in the range of 1,000 to 12,000 measured by gel permeation chromatography and is represented by the following general formula (II). The above-mentioned copolymer is a block copolymer in which the constituent unit (A) and the constituent unit (B) are covalently bonded. The solid polymer fuel cell comprises the above-mentioned membrane-electrode structure for a solid polymer fuel cell.

(wherein Y represents a divalent electron withdrawing group; Z represents a divalent electron donating group or a direct bond; Ar represents an aromatic group having a substitutent represented by -SO 3 H; m represents an integer of 0 to 10; n represents an integer of 0 to 10; and k represents an integer of 1 to 4.)

(wherein R 1 to R 8 , which may be the same or different, each represent at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, a fluorine substituted alkyl group, an allyl group, an aryl group and a cyano group; W represents a divalent electron withdrawing group or a single bond; T represents a single bond or a divalent organic group and p represents 0 or a positive integer).

公开(公告)号：EP1619739A2

公开(公告)日：2006-01-25

申请号：EP05015000.2

申请日：2005-07-11

申请人： Honda Motor Co., Ltd.

发明人： Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Sohma, Hiroshi

IPC分类号： H01M8/10 ,  C08J5/22 ,  C25B9/10

CPC分类号： C08J5/2256 ,  C08J2371/12 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2300/0082

摘要： A membrane-electrode structure for a solid polymer fuel cell excellent in power generation performance and durability and a solid polymer fuel cell comprising the membrane-electrode structure are provided. In the membrane-electrode structure for a solid polymer fuel cell in which the polymer electrolyte membrane 2 is sandwiched between a pair of electrodes 1 containing a catalyst, the polymer electrolyte membrane 1 comprises a constituent unit (A) which has an ion conductive moiety consisting of a sulfonic acid group and is represented by the following general formula (I) and a constituent unit (B) consisting only of a non-ion conductive moiety which has a number average molecular weight in the range of 1,000 to 12,000 measured by gel permeation chromatography and is represented by the following general formula (II). The above-mentioned copolymer is a block copolymer in which the constituent unit (A) and the constituent unit (B) are covalently bonded. The solid polymer fuel cell comprises the above-mentioned membrane-electrode structure for a solid polymer fuel cell.

(wherein Y represents a divalent electron withdrawing group; Z represents a divalent electron donating group or a direct bond; Ar represents an aromatic group having a substitutent represented by -SO 3 H; m represents an integer of 0 to 10; n represents an integer of 0 to 10; and k represents an integer of 1 to 4.)

(wherein R 1 to R 8 , which may be the same or different, each represent at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, a fluorine substituted alkyl group, an allyl group, an aryl group and a cyano group; W represents a divalent electron withdrawing group or a single bond; T represents a single bond or a divalent organic group and p represents 0 or a positive integer).

摘要翻译： 提供了发电性能和耐久性优异的固体高分子型燃料电池用膜电极结构体和具有膜 - 电极结构的固体高分子型燃料电池。 在聚合物电解质膜2夹在含有催化剂的一对电极1之间的固体高分子型燃料电池用膜 - 电极结构体中，高分子电解质膜1包含具有离子导电性部分的构成单元（A） 的磺酸基，并且由以下通式（I）表示的构成单元（B）和仅由通过凝胶渗透测定的数均分子量为1,000〜12,000的非离子导电性部分构成的单元（B） 由以下通式（II）表示。 上述共聚物是其中构成单元（A）和构成单元（B）共价键合的嵌段共聚物。 固体聚合物燃料电池包括上述用于固体聚合物燃料电池的膜 - 电极结构。 （其中Y表示二价吸电子基团; Z表示二价给电子基团或直接键合; Ar表示-SO 3 H表示的具有取代基的芳香族基团，m表示0〜10的整数，n表示整数 0〜10; k表示1〜4的整数）（式中，R 1〜R 8可以相同或不同，表示选自氢原子， 氟原子，烷基，氟取代的烷基，烯丙基，芳基和氰基; W表示二价吸电子基团或单键; T表示单键或二价有机基团，p表示 表示0或正整数）。

公开(公告)号：EP2424018A1

公开(公告)日：2012-02-29

申请号：EP11178762.8

申请日：2011-08-25

申请人： JSR Corporation ,  Honda Motor Co., Ltd.

发明人： Yamakawa, Yoshitaka ,  Kadota, Toshiaki ,  Murakami, Takuya ,  Tsunoda, Yuuji ,  Iguchi, Masaru ,  Fukuda, Kaoru

IPC分类号： H01M8/00 ,  C08G65/40

CPC分类号： H01M8/1023 ,  C08G65/4006 ,  C08G75/23 ,  H01M2300/0082

摘要： A polyarylene copolymer having a sulfonic acid group which has high proton conductivity and reduced swelling in hot water and reduced shrinkage in drying; a solid polymer electrolyte and a proton conductive membrane comprising the copolymer; and a membrane-electrode assembly using these.
The polyarylene block copolymer comprises a polymer segment (A) having a sulfonic acid group, and a polymer segment (B) having substantially no sulfonic acid group, the polymer segment (B) having substantially no sulfonic acid group comprising a structural unit represented by the following formula (1).

摘要翻译： 具有磺酸基的聚亚芳基共聚物，其具有高质子传导性，并且在热水中膨胀减少并且减少了干燥收缩; 固体聚合物电解质和包含所述共聚物的质子传导膜; 以及使用这些的膜 - 电极组件。 聚亚芳基嵌段共聚物包含具有磺酸基的聚合物链段（A）和基本上不含磺酸基的聚合物链段（B），所述聚合物链段（B）基本上不含有磺酸基， 以下公式（1）。

公开(公告)号：EP1575115A3

公开(公告)日：2007-02-28

申请号：EP05005312.3

申请日：2005-03-10

申请人： HONDA MOTOR CO., Ltd. ,  JSR Corporation

发明人： Otsuki, Toshihiro ,  Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Mitsuta, Naoki ,  Soma, Hiroshi

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01B1/12 ,  G01N27/00 ,  C25B9/00

CPC分类号： C08J5/2256 ,  C08J2365/02 ,  C08J2371/12 ,  H01B1/122 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039

摘要： A solid polymer electrolyte includes a polymer having a sulfonic group and shows high proton conductivity in a wide range of temperatures and humidities and is excellent in hot water resistance and chemical stability. A proton conductive membrane is composed of the electrolyte. The polymer electrolyte includes a polymer having a structural unit represented by the following formula (1a) or (1b):


wherein A is a divalent electron-withdrawing group, B is a divalent electron-donating group or a direct bond, Ar is an aromatic group, Z is an oxygen or a sulfur atom, X is a hydrogen or a fluorine atom, j is an integer of 1 or greater, k is an integer of from 1 to 4, 1 is an integer of from 0 to 10, m is an integer of from 1 to 10, and n is an integer of from 1 to 8.

公开(公告)号：EP1575115A2

公开(公告)日：2005-09-14

申请号：EP05005312.3

申请日：2005-03-10

申请人： HONDA MOTOR CO., Ltd. ,  JSR Corporation

发明人： Otsuki, Toshihiro ,  Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Mitsuta, Naoki ,  Soma, Hiroshi

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01B1/12 ,  G01N27/00 ,  C25B9/00

CPC分类号： C08J5/2256 ,  C08J2365/02 ,  C08J2371/12 ,  H01B1/122 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039

摘要： A solid polymer electrolyte includes a polymer having a sulfonic group and shows high proton conductivity in a wide range of temperatures and humidities and is excellent in hot water resistance and chemical stability. A proton conductive membrane is composed of the electrolyte. The polymer electrolyte includes a polymer having a structural unit represented by the following formula (1a) or (1b):

wherein A is a divalent electron-withdrawing group, B is a divalent electron-donating group or a direct bond, Ar is an aromatic group, Z is an oxygen or a sulfur atom, X is a hydrogen or a fluorine atom, j is an integer of 1 or greater, k is an integer of from 1 to 4, 1 is an integer of from 0 to 10, m is an integer of from 1 to 10, and n is an integer of from 1 to 8.

摘要翻译： 固体聚合物电解质包括具有磺酸基的聚合物，并且在宽温度和湿度范围内显示高质子传导性，并且耐热水性和化学稳定性优异。 质子传导膜由电解质组成。 聚合物电解质包括具有由下式（1a）或（1b）表示的结构单元的聚合物：其中A是二价吸电子基团，B是二价给电子基团或直接键合，Ar是芳族 基团，Z为氧或硫原子，X为氢或氟原子，j为1以上的整数，k为1〜4的整数，1为0〜10的整数，m 为1〜10的整数，n为1〜8的整数。

公开(公告)号：EP1450430A3

公开(公告)日：2004-11-24

申请号：EP04002358.2

申请日：2004-02-03

申请人： JSR Corporation ,  HONDA MOTOR CO., Ltd.

发明人： Otsuki, Toshihiro ,  Kanaoka, Nagayuki ,  Iguchi, Masaru ,  Mitsuta, Naoki ,  Soma, Hiroshi

IPC分类号： H01M8/10 ,  C25B13/08 ,  C08J5/22 ,  C08G61/12 ,  B01D71/64 ,  B01D71/68 ,  B01D71/52 ,  C08G73/06 ,  C08G73/08 ,  C08G73/10 ,  C08G75/20 ,  C08G75/23 ,  C08G73/18

CPC分类号： H01M8/1004 ,  C08G65/48 ,  C08G73/10 ,  C08G75/23 ,  C08G2650/02 ,  C08G2650/40 ,  C08L71/00 ,  C08L81/06 ,  C25B13/08 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032

摘要： Disclosed are a polymer electrolyte having improved hot water resistance and radical resistance, a proton conductive membrane comprising the polymer electrolyte, and a membrane-electrode assembly including the proton conductive membrane. The polymer electrolyte comprises at least one polymer selected from polyether, polyketone, polyetherketone, polysulfone, polyethersulfone, polyimide, polyetherimide, polybenzimidazole, polybenzothiazole, polybenzoxazole and the like. The polymer comprises a repeating structural unit with either or both of an aromatic ring and a heterocyclic ring, and a repeating structural unit represented by the formula (1) : wherein X is a single bond, an electron-withdrawing group or an electron-donating group; R is a single bond, -(CH 2 ) q - or -(CF 2 ) q - where q ranges from 1 to 10; m is from 0 to 10; k is from 0 to 5; 1 is from 0 to 4; and k + l ≥ 1.

摘要翻译： 公开了一种具有改善的耐热水性和耐自由基性的聚合物电解质，一种包含该聚合物电解质的质子传导膜和一种包括该质子传导膜的膜 - 电极组件。 聚合物电解质包含选自聚醚，聚酮，聚醚酮，聚砜，聚醚砜，聚酰亚胺，聚醚酰亚胺，聚苯并咪唑，聚苯并噻唑，聚苯并恶唑等中的至少一种聚合物。 该聚合物包含具有芳环和杂环中的任一个或两个的重复结构单元和由式（1）表示的重复结构单元：其中X是单键，吸电子基团或给电子基团 组; R为单键， - （CH 2）q - 或 - （CF 2）q - ，其中q的范围为1至10; m为0至10; k是从0到5; 1是从0到4; 和k +l≥1。