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    PROCESS FOR MAKING HCFO-1233zd
    1.
    发明公开
    PROCESS FOR MAKING HCFO-1233zd 审中-公开

    公开(公告)号：EP3294697A1

    公开(公告)日：2018-03-21

    申请号：EP16793142

    申请日：2016-04-25

    申请人： HONEYWELL INT INC

    发明人： WANG HAIYOU ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

    IPC分类号： C07C17/25 ,  C07C17/42 ,  C07C19/10

    CPC分类号： C07C17/25 ,  C07C21/18

    摘要： Disclosed is a process for the production of 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) which includes reacting a propane feedstock comprising tetrachlorofluoropropanes, trichlorodifluoropropanes, dichlorotrifluoropropanes, or a mixture thereof, in the presence of a solid catalyst. The process generally comprises the following four steps: (i) providing a propane feedstock comprising trichlorodifluoropropanes and dichlorotrifluoropropanes, (ii) reacting the feedstock in a vapor phase reactor in the presence of HF and in the presence of a solid catalyst under conditions effective to form a product stream comprising HCFO-1233zd and unconverted starting materials, (iii) recovering or removing HCl and HF, and (iv) isolating HCFO-1233zd(E), HCFO-1233zd(Z), or both.

    REACTOR FOR LIQUID PHASE FLUORINATION REACTIONS
    3.
    发明公开
    REACTOR FOR LIQUID PHASE FLUORINATION REACTIONS 审中-公开
    REAKTORFÜRFLUORIERUNGSREAKTIONEN DER DERFLÜSSIGPHASE

    公开(公告)号：EP3104965A4

    公开(公告)日：2017-08-02

    申请号：EP15747067

    申请日：2015-02-06

    申请人： HONEYWELL INT INC

    发明人： MERKEL DANIEL C ,  MAHLER BARRY ,  TUNG HSUEH SUNG ,  NAPPA MARIO JOSEPH

    IPC分类号： B01J8/38 ,  C07C17/087 ,  C07C19/10

    CPC分类号： C07C17/087 ,  B01J19/18 ,  B01J19/1868 ,  C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10

    摘要： The present invention relates to a hydrofluorinating process which comprises reacting a fluoroolefin with hydrogen fluoride in the liquid phase in the presence of a hydrofluorination catalyst in the reaction zone of a reactor, said reactor comprised of a reactor body having a length to diameter ratio of about 2:1 or greater; a stirred reaction zone containing said hydrofluorination catalyst, which may be prepared in situ, at least one inlet for supplying said hydrogen fluoride and fluoroolefin to the reaction zone and at least one outlet for recovering said fluoroalkane, said stirrer disposed in the reaction zone and comprising a plurality of blades fixedly attached to shaft drivable by a motor, said blades extending from about the bottom of the reaction zone to about the top of the reaction zone and said shaft extending on a longitudinal axis from the bottom of the reactor to the top of the reactor, said stirrer being rotated at a speed sufficient to promote a swirling of the liquid to effect the occurrence of hydrofluorination reaction and minimize overfluorination. The present invention also relates to said hydrofluorination reactor.

    摘要翻译： 本发明涉及氢氟酸化方法，其包括在反应器的反应区中在氢氟化催化剂存在下使氟代烯烃与氟化氢在液相中反应，所述反应器包含长度与直径之比为约 2：1或更大; 包含可以原位制备的所述氢氟化催化剂的搅拌反应区，用于将所述氟化氢和氟代烯烃供应到反应区的至少一个入口和用于回收所述氟代烷的至少一个出口，所述搅拌器设置在反应区中并且包含 多个叶片，其固定地连接到可由马达驱动的轴上，所述叶片从反应区的底部附近延伸到反应区的顶部附近，并且所述轴在纵轴上从反应器的底部延伸到 反应器中，所述搅拌器以足以促进液体涡旋的速度旋转以实现氢氟化反应的发生并使过氟化作用最小化。 本发明还涉及所述氢氟化反应器。

    A METHOD FOR MITIGATING HFC-245CB FORMATION DURING HCFO-1233XF HYDROFLUORINATION TO HCFC-244BB
    6.
    发明公开
    A METHOD FOR MITIGATING HFC-245CB FORMATION DURING HCFO-1233XF HYDROFLUORINATION TO HCFC-244BB 审中-公开
    在HCFC-244BB中加氢合成HCFO-1233XF过程中预防HFC-245CB的形成

    公开(公告)号：EP2970057A4

    公开(公告)日：2016-10-26

    申请号：EP14778098

    申请日：2014-03-11

    申请人： HONEYWELL INT INC

    发明人： WANG HAIYOU ,  MERKEL DANIEL C ,  TUNG HSUEH SUNG ,  KOPKALLI HALUK

    IPC分类号： C07C17/25 ,  C07C17/087 ,  C07C19/08 ,  C07C21/18

    CPC分类号： C07C17/23 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

    摘要： The present process relates to a method for minimizing the formation of 1,1,1,2,2-pentafluoropropane in a liquid phase reaction of 2-chloro-3,3,3-trifluoropropene and HF in the presence of a hydrofluorination catalyst comprising: (a) reacting HF with sufficient amount of 2-chloro-3,3,3-trifluoropropene in the presence of a hydrofluorination catalyst under conditions effective to form 2-chloro-1,1,1,2-tetrafluoropropane, the hydrofluorination catalyst being present in sufficient amounts to catalyze said reaction and the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of greater than 80% and a 1,1,1,2,2-pentafluoropropane selectivity lower than 20%; and (b) maintaining the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of about 80% or more and a 1,1,1,2,2-pentafluoropropane selectivity of about 20% or less by adding said hydrofluorination catalyst to the reactor in small increments.

    PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE
    10.
    发明公开
    PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON 2,3,3,3-TETRAFLUOROPROPEN

    公开(公告)号：EP2751057A4

    公开(公告)日：2015-08-12

    申请号：EP12836198

    申请日：2012-09-29

    申请人： HONEYWELL INT INC

    发明人： BEKTESEVIC SELMA ,  TUNG HSUEH SUNG ,  WANG HAIYOU

    IPC分类号： C07C17/25 ,  C07C17/42 ,  C07C21/18

    CPC分类号： C07C17/21 ,  C07C17/087 ,  C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C21/18 ,  C07C19/10

    摘要： The present invention relates, in part, to the discovery that high temperatures during the fluorination of 1,1,2,3-tetrachloropropene (HCO-1230xa) to 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) results in catalyst instability, reduced selectivity of the conversion, and/or the formation of one or more undesirable by-products. By controlling the reaction temperature, it is shown that the catalyst life may be extended and the selectivity of the reaction improved. Such control similarly results in an overall improvement in the production of certain hydrofluoroolefins, particularly 2,3,3,3-tetrafluoropropene (HFO-1234yf).

    摘要翻译： 本发明部分地涉及在1,1,2,3-四氯丙烯（HCO-1230xa）氟化成2-氯-3,3,3-三氟丙烯（HCFO-1233xf）期间的高温结果的发现 催化剂不稳定性，转化率的选择性降低，和/或一种或多种不需要的副产物的形成。 通过控制反应温度，可以看出可延长催化剂寿命，提高反应选择性。 这种控制类似地导致某些氢氟烯烃，特别是2,3,3,3-四氟丙烯（HFO-1234yf）的生产的总体改进。