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18 条记录 (耗时 0.009 秒)

    FLUORINATION PROCESS AND REACTOR
    1.
    发明公开
    FLUORINATION PROCESS AND REACTOR 审中-公开
    荧光探测器

    公开(公告)号：EP2969181A4

    公开(公告)日：2017-01-18

    申请号：EP14773146

    申请日：2014-03-13

    申请人： HONEYWELL INT INC

    发明人： MERKEL DANIEL C ,  TUNG HSUEH SUNG ,  WANG HAIYOU ,  KOPKALLI HALUK ,  CHIU YUON

    IPC分类号： B01J19/26 ,  B01J8/08 ,  C07C17/25 ,  C07C21/18

    CPC分类号： B01J19/24 ,  B01J4/002 ,  C07C17/206 ,  C07C17/25 ,  C07C21/18

    摘要： The invention relates to a process to prepare tetrahalopropenes, such as 2-chloro-3,3,3-trifluoropropene (1233xf). The process comprises atomizing a feed material, such as 1,2,3-tetrachloropropene (1230xa) and the like, and mixing it with superheated HF to form a vaporized composition of feed material and HF with substantially instantaneous contact with a vapor phase fluorination catalyst. The invention extends catalyst life and forestalls catalyst deactivation.

    摘要翻译： 本发明涉及制备四卤丙烯如2-氯-3,3,3-三氟丙烯（1233xf）的方法。 该方法包括将原料如1,1,2,3-四氯丙烯（1230xa）等进行雾化，并将其与过热HF混合以形成与气相基本上瞬时接触的原料和HF的汽化组合物 氟化催化剂。 本发明延长了催化剂的寿命并阻止了催化剂的失活。

    A METHOD FOR MITIGATING HFC-245CB FORMATION DURING HCFO-1233XF HYDROFLUORINATION TO HCFC-244BB
    6.
    发明公开
    A METHOD FOR MITIGATING HFC-245CB FORMATION DURING HCFO-1233XF HYDROFLUORINATION TO HCFC-244BB 审中-公开
    在HCFC-244BB中加氢合成HCFO-1233XF过程中预防HFC-245CB的形成

    公开(公告)号：EP2970057A4

    公开(公告)日：2016-10-26

    申请号：EP14778098

    申请日：2014-03-11

    申请人： HONEYWELL INT INC

    发明人： WANG HAIYOU ,  MERKEL DANIEL C ,  TUNG HSUEH SUNG ,  KOPKALLI HALUK

    IPC分类号： C07C17/25 ,  C07C17/087 ,  C07C19/08 ,  C07C21/18

    CPC分类号： C07C17/23 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

    摘要： The present process relates to a method for minimizing the formation of 1,1,1,2,2-pentafluoropropane in a liquid phase reaction of 2-chloro-3,3,3-trifluoropropene and HF in the presence of a hydrofluorination catalyst comprising: (a) reacting HF with sufficient amount of 2-chloro-3,3,3-trifluoropropene in the presence of a hydrofluorination catalyst under conditions effective to form 2-chloro-1,1,1,2-tetrafluoropropane, the hydrofluorination catalyst being present in sufficient amounts to catalyze said reaction and the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of greater than 80% and a 1,1,1,2,2-pentafluoropropane selectivity lower than 20%; and (b) maintaining the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of about 80% or more and a 1,1,1,2,2-pentafluoropropane selectivity of about 20% or less by adding said hydrofluorination catalyst to the reactor in small increments.

    METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS
    9.
    发明公开
    METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
    VERFAHREN ZUR HERSTELLOW FLUORINIERTER有机化学家VERBINDUNGEN

    公开(公告)号：EP2274260A4

    公开(公告)日：2014-04-23

    申请号：EP09747644

    申请日：2009-05-15

    申请人： HONEYWELL INT INC

    发明人： KOPKALLI HALUK ,  CHIU YUON ,  TUNG HSUEH SUNG

    IPC分类号： C07C17/04 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C21/18

    CPC分类号： C07C21/18 ,  C07C17/087 ,  C07C17/204 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10

    摘要： Disclosed is a process for producing tetrafluoropropene comprising: (a) catalytically fluorinating at least one tetrafluoropropene in a first reactor to produce HCFO-1233xf; (b) reacting said HCFO-1233xf with hydrogen fluoride in a second reactor to produce HCFC-244bb; (c) recycling at least a portion of said HCFC-244bb back to said first reactor as recycled HCFC-244bb; and (d) catalytically dehydrochlorinating said recycled HCFC-244bb in said first reactor to produce HFO-1234yf.

    摘要翻译： 公开了一种生产四氟丙烯的方法，包括：（a）在第一反应器中催化氟化至少一种四氟丙烯以产生HCFO-1233xf; （b）在第二反应器中使所述HCFO-1233xf与氟化氢反应以产生HCFC-244bb; （c）将所述HCFC-244bb的至少一部分再循环回所述第一反应器作为再循环HCFC-244bb; 和（d）在所述第一反应器中对所述再循环HCFC-244bb进行催化脱氯化氢以产生HFO-1234yf。