摘要:
The invention concerns a method and facility for CLC of a solid hydrocarbon feedstock which involves injecting the solid hydrocarbon feedstock in such a way as to limit any occurrence of the feedstock sticking to the walls of the injection device. The solid feedstock is introduced into a conveying area operating in a fluidised bed opening into a combustion reactor. A fluidising gas is injected into this conveying area, while controlling the flow of the gas such that the superficial gas velocity in the conveying area is greater than the terminal falling velocity of the particles of the solid hydrocarbon feedstock and the terminal falling velocity of solid particles located in the combustion reactor, and while controlling the temperature of the fluidising gas such that the temperature of the conveying area is less than or equal to 500 0 C.
摘要:
The invention relates to a method and an apparatus for combustion by chemical-loop oxidation reduction (CLC) of a gaseous hydrocarbon feedstock, for example natural gas consisting essentially of methane. According to the invention, catalytic steam reforming of the feedstock is carried out between two consecutive steps of combustion of the feedstock in contact with an oxidation-reduction active mass in particle form. The reforming catalyst is placed in a fixed bed in a reforming zone (130) between the two reduction zones (120, 140) in which the two combustion steps are performed.
摘要:
The invention relates to a plant and a process for chemical looping oxidation-reduction combustion of a gaseous hydrocarbon feedstock, for example natural gas essentially comprising methane. According to the invention, a catalytic pre-reforming of the feedstock is carried out in a prereforming zone comprising a fixed reforming catalyst, while benefiting from a heat transfer between the reduction or oxidation zone of the chemical loop and the prereforming zone adjacent to the reduction or oxidation zone. The prereforming zone (130) and the oxidation zone (110) or the prereforming zone (130) and the reduction zone (120) are thus thermally integrated within the same reactor (100) while being separated by at least one thermally conductive dividing wall (140).
摘要:
The invention relates to a method and an apparatus for combustion by chemical-loop oxidation reduction (CLC) of a gaseous hydrocarbon feedstock, for example natural gas consisting essentially of methane. According to the invention, catalytic reforming of the feedstock is carried out within the reduction zone in which the combustion of the feedstock takes place, in contact with an oxidation-reduction active mass in particle form. The reforming catalyst is in the form of fluidised particles which are not transported within the reduction zone. The catalyst thus confined to the reduction zone does not circulate in the CLC loop.
摘要:
The invention concerns a method of chemical-loop oxidation-reduction combustion (CLC) of liquid hydrocarbon feedstocks carried out in a fluidised bed, in which the liquid hydrocarbon feedstock (2) is partially vaporised in contact with a hot solid (1) in the form of particles to form a partially vaporised liquid feedstock and to form coke on said solid (1), before bringing the partially vaporised liquid feedstock (19) into contact with an oxidation-reduction active mass in the form of particles (12) to carry out the combustion of the partially vaporised liquid feedstock (19). The hot solid particles (1) used to carry the coke can, in particular, form a second particle circulation loop in the fluidised bed, the first being that of the particles of the oxygen-transporting oxidation-reduction active mass (12) flowing between the oxidation and combustion reactors, thus allowing the coke-carrying particles (1) to be recycled in the method.