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1.发明公开PROCEDE DE PREPARATION D'UN MATERIAU SPHERIQUE A POROSITE HIERARCHISEE COMPRENANT DES PARTICULES METALLIQUES PIEGEES DANS UNE MATRICE MESOSTRUCTUREE 审中-公开用于生产球状颗粒材料具有分级的多孔与一个介孔结构基质随附的金属颗粒
公开(公告)号：EP2654947A1
公开(公告)日：2013-10-30
申请号：EP11808895.4
申请日：2011-12-15
申请人： IFP Energies Nouvelles , Université Pierre et Marie Curie , Centre National de la Recherche Scientifique
发明人： CHAUMONNOT, Alexandra , SANCHEZ, Clément , BOISSIERE, Cédric , COLBEAU-JUSTIN, Frédéric , BONDUELLE, Audrey
IPC分类号： B01J21/12 , B01J23/24 , B01J23/882 , B01J23/883 , B01J27/188 , B01J37/00 , B01J35/10 , C10G45/04 , C10G45/12 , C10G3/00 , B01J29/40 , B01J29/70 , B01J29/08
CPC分类号： B29C66/727 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/005 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J29/08 , B01J29/40 , B01J29/46 , B01J29/48 , B01J29/7007 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/02 , C01B39/06 , C01B39/40 , C10G49/04 , C10G49/08 , Y02P30/20
摘要： A process is described for the preparation of an inorganic material with a hierarchical porosity in the micropore and mesopore domains. The material has at least two elementary spherical particles having a maximum diameter of 200 microns. The process comprises: a) preparing a solution containing zeolitic nanocrystals with a maximum nanometric dimension equal to 60 nm based on silicon and/or precursor elements of proto-zeolitic entities based on silicon; b) mixing, in solution, metallic particles or at least one metallic precursor of metallic particles, a surfactant and the solution obtained in accordance with a) such that the ratio of the volumes of inorganic and organic materials, Vinorganic/Vorganic, is 0.29 to 0.50; c) aerosol atomization of the solution obtained in b) resulting in formation of spherical droplets; d) drying the droplets; g) eliminating the template and surfactant.
摘要翻译： 方法描述了制备的无机材料与微孔和中孔结构域分级的孔隙率。 该材料具有200微米的最大直径的至少两个基本球形颗粒。 该方法包括：a）基于硅和/或基于硅原沸石实体的前体元件制备含沸石纳米晶体具有最大尺寸纳米等于60纳米的溶液; b）将在溶液中的金属粒子或金属粒子中的至少一种金属前体，表面活性剂和在雅舞蹈获得具有溶液）检验做无机和有机材料，Vinorganic / Vorganic，的体积的比例为0时29至 零点50; c）以形成球形液滴的所得中B中获得的溶液）的气溶胶雾化; d）干燥微滴; 克）消除模板和表面活性剂。
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公开(公告)号：EP2197791B1
公开(公告)日：2011-10-19
申请号：EP08845167.9
申请日：2008-08-18
IPC分类号： C01B37/00 , C01B37/02 , C01B39/00 , B01J29/00 , B01J37/00 , C01B33/113 , B01J21/06 , B01J29/06
CPC分类号： C01B39/00 , B01J20/0288 , B01J20/18 , B01J20/28019 , B01J20/28057 , B01J20/2808 , B01J20/28083 , B01J20/28085 , B01J20/28092 , B01J21/08 , B01J21/12 , B01J29/035 , B01J29/08 , B01J29/40 , B01J29/7007 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/0045 , B01J37/033 , C01B37/00 , C01B37/02 , C07C4/18 , Y02P20/52 , Y10T428/2982 , C07C15/04 , C07C11/06
摘要： The invention relates to a material having a hierarchised porosity and consisting of at least two elementary spherical particles having a maximum diameter of 200 microns, at least one of said spherical particles comprising at least one matrix based on silicon oxide. Said material has a macroporous volume measured by mercury porosimetry of between 0.05 and 1 ml/g, a mesoporous volume measured by nitrogen volumetry of between 0.03 and 0.4 ml/g, and the matrix comprises amorphous walls. The invention also relates to the preparation of the material.
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3.发明公开
公开(公告)号：EP2274236A2
公开(公告)日：2011-01-19
申请号：EP09727588.7
申请日：2009-02-26
摘要： A mesostructured material is described that is composed of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminium oxide, said matrix having a pore diameter between 1.5 and 30 nm and an aluminium oxide content that represents more than 46% by weight relative to the weight of said matrix, which matrix has amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 µm and less than or equal to 100 µm (10 100). Said mesostructured matrix may also contain silicon oxide. Each of the spherical particles of the mesostructured material may also contain zeolite nanocrystals so as to form a material having a mixed porosity of both mesostructured and zeolitic nature. The preparation of said material is also described.
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公开(公告)号：EP2197794B1
公开(公告)日：2011-10-26
申请号：EP08846541.4
申请日：2008-08-29
CPC分类号： C01B37/00 , B01J20/18 , B01J20/28019 , B01J20/28057 , B01J20/2808 , B01J20/28083 , B01J20/28085 , B01J21/08 , B01J21/12 , B01J29/035 , B01J29/084 , B01J29/40 , B01J29/7007 , B01J35/1057 , B01J35/1061 , B01J35/1066 , B01J35/1095 , B01J37/0045 , B01J37/10 , C01B37/02 , C01B39/00
摘要： The invention relates to a material having a hierarchised porosity and made of at least two elementary spherical particles having a maximum diameter of 200 microns, at least one of said spherical particles including at least one matrix containing silicon oxide and having crystallised walls, wherein said material has a macroporous volume as measured by mercury porosimetry of between 0.05 and 1 ml/g, and a mesoporous volume as measured by nitrogen volumetric analysis of between 0.03 and 0.4 ml/g. The invention also relates to the preparation of this material and to the use thereof as an adsorbent or an acidic solid.
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5.发明授权
公开(公告)号：EP2274235B1
公开(公告)日：2012-07-25
申请号：EP09734713.2
申请日：2009-02-26
CPC分类号： C01B37/00 , B01J21/02 , B01J21/063 , B01J29/061 , C01B37/005 , C01B39/04 , Y10T428/2991 , Y10T428/2993
摘要： An inorganic material is described that is composed of at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having a size between 1 and 300 nm and a mesostructured matrix based on an oxide of at least one element X chosen from the group composed of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium and the mixture of at least two of these elements, said mesostructured matrix having a pore diameter between 1.5 and 30 nm and having amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 µm and less than or equal to 100 µm. Said material may also contain zeolite nanocrystals trapped within said mesostructured matrix.
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6.发明授权MATERIAU CRISTALLISE COMPRENANT DU SILICIUM A POROSITE HIERARCHISEE ET ORGANISEE 有权硅结晶材料BY分级的和有组织的孔隙
公开(公告)号：EP2197792B1
公开(公告)日：2012-01-25
申请号：EP08847212.1
申请日：2008-08-29
CPC分类号： C01B37/005 , C01B37/02 , C01B39/00
摘要： The invention relates to a material having a hierarchised and organised porosity in terms of microporosity and mesoporosity, that comprises at least two elementary spherical particles, each of said particles including a meso-structured silicon-oxide-containing matrix having a mesopore diameter of between 1.5 and 30 nm and having microporous crystallised walls with a thickness of between 1 and 60 nm, wherein said elementary spherical particles have a maximum diameter of 200 microns. The invention also relates to the preparation of said material.
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7.发明公开MATÉRIAU ALUMINOSILICATE MESOSTRUCTURE FORME DE PARTICULES SPHERIQUES DE TAILLE SPECIFIQUE 有权异形孔结构化铝硅酸盐材料的具体尺寸的球粒状
公开(公告)号：EP2274237A2
公开(公告)日：2011-01-19
申请号：EP09727359.3
申请日：2009-02-26
CPC分类号： C01B39/04 , B01J20/18 , B01J20/28004 , B01J20/28019 , B01J20/28057 , B01J20/28083 , B01J21/12 , B01J29/041 , B01J35/1057 , B01J35/1061 , B01J35/109 , Y10T428/2991 , Y10T428/2993
摘要： A mesostructured aluminosilicate material is described that is composed of at least two elementary spherical particles, each of said spherical particles being composed of a matrix based on silicon oxide and aluminium oxide, said matrix having a pore diameter between 1.5 and 30 nm, an Si/Al molar ratio at least equal to 1 and having amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D such that 10
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8.发明公开MATERIAU SPHERIQUE A BASE D' HETEROPOLYANIONS PIEGES DANS UNE MATRICE OXYDE MESOSTRUCTUREE ET SON UTILISATION COMME CATALYSEUR DANS LES PROCEDES DU RAFFINAGE D ' HYDROCARBURES 审中-公开基于在介孔结构氧化物基质球状颗粒材料捕获的杂多阴离子和使用的催化剂的KOHLENWASSERSTOFFRAFFINIERUNGSVERFAHREN
公开(公告)号：EP2654946A1
公开(公告)日：2013-10-30
申请号：EP11808894.7
申请日：2011-12-15
申请人： IFP Energies Nouvelles , Université Pierre et Marie Curie , Centre National de la Recherche Scientifique
发明人： CHAUMONNOT, Alexandra , SANCHEZ, Clément , BOISSIERE, Cédric , COLBEAU-JUSTIN, Frédéric , MARCHAND, Karine , DEVERS, Elodie , BONDUELLE, Audrey , UZIO, Denis , DAUDIN, Antoine , GUICHARD, Bertrand
IPC分类号： B01J21/12 , B01J23/20 , B01J23/24 , B01J35/00 , B01J35/10 , C01B37/00 , C10G45/04 , C10G47/12 , B01J37/00 , B01J27/188 , B01J23/882 , B01J23/883 , C10G3/00
CPC分类号： B01J27/199 , B01J23/882 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/00 , C01B37/005 , C01B37/02 , C01B39/04 , C01B39/06 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G45/06 , C10G47/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10L1/04 , C10L1/06 , C10L1/08 , Y02P30/10 , Y02P30/20
摘要： An inorganic material is described consisting of at least two elementary spherical particles, each of said spherical particles comprising metallic particles in the form of polyoxometalate of formula (XxMmOyHh)q- where H is hydrogen, O is oxygen, X is an element chosen from phosphorus, silicon, boron, nickel and cobalt and M is one or more elements chosen from vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x being equal to 0, 1, 2 or 4, m being equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y being between 17 and 72, h being between 0 and 12 and q being between 1 and 20 (y and q being integers). Said metallic particles are present within a mesostructured matrix based on an oxide of an element Y chosen from the group consisting of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium and the mixture of at least two of these elements. Said matrix has pores with a diameter between 1.5 and 50 nm and amorphous walls with a thickness between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 200 microns.
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9.发明授权
公开(公告)号：EP2197793B1
公开(公告)日：2011-08-17
申请号：EP08844304.9
申请日：2008-08-19
CPC分类号： C01B37/02 , C01B33/46 , C01B39/02 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： The invention relates to a material having a hierarchised porosity and consisting of at least two elementary spherical particles. Each of said particles comprises a mesostructured matrix based on silicon oxide, the diameter of the mesopores being between 1.5 and 30 nm, and amorphous and microporous walls having a thickness of between 1.5 and 50 nm, the elementary spherical paricules having a maximum diameter of 200 microns. The matrix based on silicon oxide can contain aluminium. The invention also relates to the preparation of said material.
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10.发明公开
公开(公告)号：EP2274235A1
公开(公告)日：2011-01-19
申请号：EP09734713.2
申请日：2009-02-26
CPC分类号： C01B37/00 , B01J21/02 , B01J21/063 , B01J29/061 , C01B37/005 , C01B39/04 , Y10T428/2991 , Y10T428/2993
摘要： An inorganic material is described that is composed of at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having a size between 1 and 300 nm and a mesostructured matrix based on an oxide of at least one element X chosen from the group composed of silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium and the mixture of at least two of these elements, said mesostructured matrix having a pore diameter between 1.5 and 30 nm and having amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 µm and less than or equal to 100 µm. Said material may also contain zeolite nanocrystals trapped within said mesostructured matrix.
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