and optical isomers thereof, wherein X is oxygen or sulphur; R¹ is halogen, C₁₋₄ alkoxy or C₁₋₄ haloalkoxy; R² and R³, which are the same or different, are hydrogen, -CO₂R⁵ or C₁₋₄ alkyl; R⁴ is hydrogen, cyano, C₁₋₄ alkyl (optionally substituted with cyano or halogen), -(CH₂) n CO₂R⁶, -CONR⁶R⁷, C₃₋₆ cycloalkyl, C₂₋₄ alkenyl, C₂₋₄ alkynyl, optionally substituted phenyl or optionally substituted heteroaromatic; or the group CR²R³R⁴ can form an allene moiety optionally substituted with C₁₋₄ alkyl; R⁵, R⁶ and R⁷, which are the same or different, are hydrogen or C₁₋₄ alkyl; n is 0, 1, 2, 3 or 4; and metal complexes thereof are active as fungicides.
摘要翻译:具有通式(I)的化合物及其旋光异构体,其中X是氧或硫; R 1是卤素,C 1-4烷氧基或C 1-4卤代烷氧基; R 2和R 3可以相同或不同,为氢,-CO 2 R 5或C 1-4烷基; 氰基,C 1-4烷基(任选被氰基或卤素取代), - (CH 2)n CO 2 R 8,-CONR 9 R 9,C 3-6环烷基,C 2-4链烯基,C 2-4炔基,任选取代的苯基或任选取代的杂芳族 ; 或基团CR 2 R 3 R 4可以形成任意被C 1-4烷基取代的丙二烯部分; R 5,R 6和R 7可以相同或不同,为氢或C 1-4烷基; n是0,1,2,3或4; 及其金属络合物作为杀真菌剂是有效的。
摘要:
Compounds of formula (I): and stereoisomers thereof, wherein W is R 1 O 2 C-C=CH-ZR 2 , wherein R 1 and R 2 , which are the same or diffrent, are alkyl or fluoro-alkyl groups, and Z is either an oxygen or sulphur atom; A, B, D and E, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted aralkyl, optionally substituted arylalkoxy, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted heteroaryloxy, optionally substituted heteroarylthio, optionally substituted acyloxy, optionally substituted amino, optionally substituted arylazo, optionally substituted acylamino, nitro, cyano, -CO 2 R 3 , -CONR 3 R 4 , -COR 3 , -CR 3 =NR 4 , -N=CR 3 R 4 or-S(O) n R 3 groups; any two of the groups A, B, D and E when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; n is 0, 1 or 2; and R 3 and R 4 , which are the same or different, are hydrogen atoms or alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, alkynyl, optionally substituted aryl or optionally substituted aralkyl groups; and metal complexes thereof. The compounds are useful in agriculture especially as fungicides but also as insecticides, nematicides and plant growth regulators.
摘要翻译:式(I)化合物:其中W为R 1 O 2 C-C = CH-ZR 2,其中R 1和R 2相同或不同, 是烷基或氟代烷基,Z是氧或硫原子; A,B,D和E相同或不同,为氢或卤原子,或羟基,任选取代的烷基,任选取代的烷氧基,任选取代的芳烷基,任选取代的芳基烷氧基,任选取代的烯基,任选取代的炔基, 芳基,任选取代的芳氧基,任选取代的芳硫基,任选取代的杂芳氧基,任选取代的杂芳硫基,任选取代的酰氧基,任选取代的氨基,任选取代的芳基偶氮,任选取代的酰基氨基,硝基,氰基,-CO 2 R 3,-CONR 3 R -COR 3,-CR 3 = NR 4,-N = CR 3 R 4或-S(O)n R 3基团; 组A,B,D和E中的任何两个当它们位于环上的相邻位置时,任选地连接形成任选含有一个或多个杂原子的芳族或脂族稠合环; n为0,1或2; R 3和R 4相同或不同,为氢原子或烷基,环烷基,环烷基烷基,烯基,炔基,任选取代的芳基或任选取代的芳烷基; 及其金属络合物。 这些化合物在农业中尤其适用于杀真菌剂,也可用作杀虫剂,杀线虫剂和植物生长调节剂。
摘要:
Compounds of formula (I): and stereoisomers thereof, wherein W is R 1 O 2 C-C=CH-ZR 2 , wherein R 1 and R 2 , which are the same or diffrent, are alkyl or fluoro-alkyl groups, and Z is either an oxygen or sulphur atom; A, B, D and E, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted aralkyl, optionally substituted arylalkoxy, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted heteroaryloxy, optionally substituted heteroarylthio, optionally substituted acyloxy, optionally substituted amino, optionally substituted arylazo, optionally substituted acylamino, nitro, cyano, -CO 2 R 3 , -CONR 3 R 4 , -COR 3 , -CR 3 =NR 4 , -N=CR 3 R 4 or-S(O) n R 3 groups; any two of the groups A, B, D and E when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; n is 0, 1 or 2; and R 3 and R 4 , which are the same or different, are hydrogen atoms or alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, alkynyl, optionally substituted aryl or optionally substituted aralkyl groups; and metal complexes thereof. The compounds are useful in agriculture especially as fungicides but also as insecticides, nematicides and plant growth regulators.
摘要:
Fungicidal amide derivatives of the general formula (I): wherein R is a phenyl group substituted in the 4-position by a group of R 1 XCH 2 -, where R 1 is C,-C 4 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C 1 -C 4 alkylcarboyl, or H, and X is oxygen or sulphur; E is CN, or CSNH 2 or CONH 2 ; and Y is C 1 -C 4 alkoxy, C 3 -C 4 alkenyloxy, C 3 -C 4 alkynyloxy, 1-pyrazolyl or 2-furyl.
摘要:
Compounds of the formula: and stereoisomers thereof, wherein R' is -CH=CH-X or -C≡C-X where X is H or a straight chain alkyl; R 2 is halophenyl; Z is OR 3 where R 3 is H, alkyl, alkenyl or alkynyl; and their acid addition salts and metal complexes have fungicidal and plant growth regulating activity.
摘要翻译:其中R 1是-CH = CH-X或-C元素C-X,其中X是H或直链烷基; R 2是卤代苯基; Z是OR 3,其中R 3是H,烷基,烯基或炔基; 其酸加成盐和金属络合物具有杀真菌和植物生长调节活性。
摘要:
Soil-dwelling insect pests are combated and controlled by application to the soil of a composition, preferably a granular composition, comprising a compound of formula: wherein X is F, Cl or Br and R is a benzyl group optionally substituted with 1-3 substituents selected from Cl, Br, I, alkyl, alkenyl and alkoxy.