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公开(公告)号：EP0409580B1
公开(公告)日：1995-05-03
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
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2.发明公开Hydrogenated diene copolymer-containing resin composition and process for producing the same 失效Hydrogenierte Dien-copolymer-Zusammensetzung und Verfahren zu deren Herstellung。
公开(公告)号：EP0373834A2
公开(公告)日：1990-06-20
申请号：EP89312821.5
申请日：1989-12-08
发明人： Shibata, Tooru , Teramoto, Toshio , Takeuchi, Yasuo , Makino, Kenya , Mawatari, Masaaki , Maeda, Minoru , Kimura, Shinichi , Hasegawa, Minoru , Goshima, Kunio , Takeuchi, Mikio
CPC分类号： C08L15/00 , C08L23/10 , C08L25/02 , C08L67/00 , C08L71/123 , C08L77/00 , Y10S525/905 , C08L2666/14 , C08L2666/06 , C08L2666/04
摘要： A hydrogenated diene copolymer resin composition comprising (A) 5-70% by weight of a hydrogenated diene copolymer which is a hydrogenation product of a random copolymer of at least one conjugated diene and 3-50% by weight of an alkenyl aromatic compound having a number average molecular weight of 5,000-1,000,000 and a molecular weight distribution (Mw/Mn) of 10 or less, the vinyl content in the diene portion of the random copolymer being 10-90%, at least 70% of the olefinic unsaturation of the random copolymer being hydrogenated, and (B) 95-30% by weight of at least one resin selected from the group consisting of a polypropylene resin, a polyphenylene ether resin and an alkenyl aromatic compound polymer resin. The hydrogenated diene copolymer (A) can be used in combination with (B) a polyphenylene ether resin and (C) at least one member selected from the group consisting of a polyamide and a thermoplastic polyester in such a proportion that the amount of (A) is 1-50 parts by weight, the amount of (B) is 10-89 parts by weight and the amount of (C) is 10-89 parts by weight. The above composition has improved impact resistance and improved gloss and appearance of molded article.
摘要翻译： 一种氢化二烯共聚物树脂组合物，其包含（A）5-70重量％的氢化二烯共聚物，其是至少一种共轭二烯的无规共聚物和3-50重量％的链烯基芳族化合物的氢化产物， 数均分子量为5,000-1,000,000，分子量分布（Mw / Mn）为10以下，无规共聚物的二烯部分中的乙烯基含量为10-90％，至少70％的烯属不饱和度为 无规共聚物被氢化，和（B）95-30重量％的至少一种选自聚丙烯树脂，聚苯醚树脂和烯基芳族化合物聚合物树脂的树脂。 氢化二烯共聚物（A）可以与（B）聚苯醚树脂和（C）至少一种选自聚酰胺和热塑性聚酯的组分与（A）的组分（A ）为1-50重量份，（B）的量为10-89重量份，（C）的量为10-89重量份。 上述组合物具有改善的耐冲击性和改善的模塑制品的光泽和外观。
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公开(公告)号：EP0708147B1
公开(公告)日：1998-08-05
申请号：EP95307212.1
申请日：1995-10-11
发明人： Itoh, Hiroyuki , Ito, Yukiko , Mawatari, Masaaki , Nagai, Hisao , Miyamoto, Kazuo , Kawakita, Mitsuru
CPC分类号： C08L55/02 , B41M5/267 , C08K3/10 , C08L2666/04
摘要： A laser marking resin composition excellent in appearance of molded article and impact resistance which comprises: (A) 100 parts by weight of a rubber-reinforced vinyl resin consisting of: (A-1) 1 to 100% by weight of a rubber-reinforced resin having a grafting degree of 5 to 150% by weight obtained by polymerizing, in the presence of (a) 5 to 70% by weight of a rubbery polymer, (b) 95 to 30% by weight of at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (a) + (b) = 100% by weight, and (A-2) 99 to 0% by weight of a polymer obtained by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (A-1) + (A-2) = 100% by weight, the matrix resin in the component (A) having an intrinsic viscosity Ä eta Ü of 0.1 to 1.5 dl/g as measured in methyl ethyl ketone at 30 DEG C, and (B) 0.01 to 30 parts by weight of at least one compound selected from the group consisting of (B-1) titanium black, (B-2) black iron oxide, (B-3) yellow iron oxide and (B-4) carbon black.
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公开(公告)号：EP0606762A2
公开(公告)日：1994-07-20
申请号：EP93310518.1
申请日：1993-12-23
CPC分类号： C08K5/0058 , C08K3/015 , C08L51/04 , C08L25/02
摘要： An antibacterial resin composition comprising (A) 100 parts by weight of a styrene resin, (B) 0.01 to 30 parts by weight of an antibacterial agent and (C) 0.01 to 30 parts by weight of a compound having a specific functional group, and said antibacterial resin composition is excellent in antibacterial property and surface appearance of molded article and can give a molded article which can be applied to many fields.
摘要翻译： 一种抗菌性树脂组合物，其含有（A）苯乙烯系树脂100重量份，（B）抗菌剂0.01〜30重量份和（C）具有特定官能团的化合物0.01〜30重量份， 所述抗菌树脂组合物具有优异的抗菌性能和模塑制品的表面外观，并且可以提供可应用于许多领域的模塑制品。
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公开(公告)号：EP0606762A3
公开(公告)日：1994-11-02
申请号：EP93310518.1
申请日：1993-12-23
CPC分类号： C08K5/0058 , C08K3/015 , C08L51/04 , C08L25/02
摘要： An antibacterial resin composition comprising (A) 100 parts by weight of a styrene resin, (B) 0.01 to 30 parts by weight of an antibacterial agent and (C) 0.01 to 30 parts by weight of a compound having a specific functional group, and said antibacterial resin composition is excellent in antibacterial property and surface appearance of molded article and can give a molded article which can be applied to many fields.
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公开(公告)号：EP0409580A3
公开(公告)日：1992-04-15
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by eight of at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer. The above thermopalstic elastomer composition has properties comparable to a vulcanized rubber and is useful in various industrial parts.
摘要翻译： 1。一种热塑性弹性体组合物，其特征在于，含有：（i）氢化二烯系聚合物，该氢化二烯系聚合物是由（C）1,2-乙烯基含量的聚丁二烯嵌段链段 和（D）作为聚丁二烯或链烯基芳族化合物 - 丁二烯共聚物的嵌段链段，其丁二烯部分的1,2-乙烯基含量为25-95％，所述嵌段结构为 由式C-（DC）n或（CD）m表示的直链或支链嵌段共聚物，其中C表示上述聚丁二烯嵌段链段（C），D表示上述嵌段链段（D）， n表示1或更大的整数，m表示2或更大的整数，至少90％的直链或支链嵌段共聚物的丁二烯部分中的双键被氢化，或（i'）改性氢化 二烯聚合物，其中0.01至10摩尔％的至少一种功能基团 （i）中加入选自羧基，酸酐基，羟基，环氧基，卤素原子和氨基中的至少一种，并且通过八种1-99个单元中的至少一种选自 该组由热塑性树脂和橡胶状聚合物组成。 上述热溶性弹性体组合物具有与硫化橡胶相当的性能，并可用于各种工业部件。
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公开(公告)号：EP0409580A2
公开(公告)日：1991-01-23
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by eight of at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer. The above thermopalstic elastomer composition has properties comparable to a vulcanized rubber and is useful in various industrial parts.
摘要翻译： 一种热塑性弹性体组合物，其包含：99-1重量份的（ⅰ）氢化二烯聚合物，其是由（C）具有1,2-乙烯基含量的聚丁二烯嵌段链段构成的直链或支链嵌段共聚物的氢化产物 为（D）作为聚丁二烯或链烯基芳族化合物 - 丁二烯共聚物的嵌段链段，其丁二烯部分的1,2-乙烯基含量为25-95％，所述嵌段结构为 直链或支链嵌段共聚物由式C-（DC）n或（CD）m表示，其中C表示上述聚丁二烯嵌段段（C），D表示上述嵌段链段（D）， n表示1以上的整数，m表示2以上的整数，直链或支链嵌段共聚物的丁二烯部分中的双键的至少90％被氢化，或（i分钟）改性氢化 二烯聚合物，其中0.01至10摩尔％的至少一种官能团 将由羧基，酸酐基，羟基，环氧基，卤素原子和氨基组成的组中加入的加成物加入到氢化二烯系聚合物（i）中，将1-99份×8的至少一种选自 由热塑性树脂和橡胶状聚合物组成的组。 上述热塑性弹性体组合物具有与硫化橡胶相当的性质，并且可用于各种工业部件。
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公开(公告)号：EP0130839B1
公开(公告)日：1990-05-02
申请号：EP84304533.7
申请日：1984-07-02
IPC分类号： C08L51/04 , C08L25/04 , C08L71/12 , C08F291/02
CPC分类号： C08L25/12 , C08L51/04 , C08L63/00 , C08L67/00 , C08L69/00 , C08L71/00 , C08L71/12 , C08L71/123 , C08L77/00 , C08L81/00 , C08L81/02 , C08L81/06 , C08L2205/02 , C08L2666/02
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公开(公告)号：EP0708147A1
公开(公告)日：1996-04-24
申请号：EP95307212.1
申请日：1995-10-11
发明人： Itoh, Hiroyuki , Ito, Yukiko , Mawatari, Masaaki , Nagai, Hisao , Miyamoto, Kazuo , Kawakita, Mitsuru
CPC分类号： C08L55/02 , B41M5/267 , C08K3/10 , C08L2666/04
摘要： A laser marking resin composition excellent in appearance of molded article and impact resistance which comprises:
(A) 100 parts by weight of a rubber-reinforced vinyl resin consisting of:
(A-1) 1 to 100% by weight of a rubber-reinforced resin having a grafting degree of 5 to 150% by weight obtained by polymerizing, in the presence of (a) 5 to 70% by weight of a rubbery polymer, (b) 95 to 30% by weight of at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (a) + (b) = 100% by weight, and
(A-2) 99 to 0% by weight of a polymer obtained by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound,
provided that (A-1) + (A-2) = 100% by weight, the matrix resin in the component (A) having an intrinsic viscosity [η] of 0.1 to 1.5 dl/g as measured in methyl ethyl ketone at 30°C, and
(B) 0.01 to 30 parts by weight of at least one compound selected from the group consisting of (B-1) titanium black, (B-2) black iron oxide, (B-3) yellow iron oxide and (B-4) carbon black.摘要翻译： 一种模塑制品的外观和耐冲击性优异的激光标记树脂组合物，其包含：（A）100重量份由以下组成的橡胶增强乙烯基树脂组成：（A-1）1至100重量％的橡胶增强 在（a）5〜70重量％的橡胶状聚合物的存在下，通过聚合得到的接枝度为5〜150重量％的树脂，（b）95〜30重量％的至少一种选自 由（a）+（b）= 100重量％和（A-2）组成的组成的芳族乙烯基化合物，乙烯基氰化合物，（甲基）丙烯酸酯，马来酸酐和马来酰亚胺化合物， 通过聚合至少一种选自芳族乙烯基化合物，乙烯基氰化合物，（甲基）丙烯酸酯，马来酸酐和马来酰亚胺化合物的单体获得的聚合物的99至0重量％，条件是（ A-1）+（A-2）= 100重量％，成分（A）中的基质树脂为特性粘度 在甲基乙基酮中在30℃下测得的0.1至1.5dl / g的Ä等级，和（B）0.01至30重量份的至少一种选自（B-1）钛黑， （B-2）黑色氧化铁，（B-3）黄色氧化铁和（B-4）炭黑。
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公开(公告)号：EP0520096B1
公开(公告)日：1995-09-20
申请号：EP91201664.9
申请日：1991-06-28
CPC分类号： C09K21/14 , C08K5/0066 , C08K5/523 , C08L25/00 , C08L51/04
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