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公开(公告)号：EP0409580B1
公开(公告)日：1995-05-03
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
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公开(公告)号：EP0275186A3
公开(公告)日：1989-02-22
申请号：EP88300235.4
申请日：1988-01-12
发明人： Ono, Hisao , Nagano, Masanobu , Sato, Hozumi , Miyachi, Takumi
CPC分类号： C08L51/04 , C08L9/00 , C08L77/00 , C08L77/02 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic polymer composition consisting essentially of
(A) 20-99% by weight of (i) a polyamide, (ii) a polyamide elastomer or a mixture thereof and (B) 80-1% by weight of a rubber component which is a copolymer of (1) 70 - 99.98% by weight of a rubber, (2) 0.01-20% by weight of a crosslinking monomer and (3) 0.01-20% by weight of an olefinically unsaturated monomer having a carboxyl group, an epoxy group or both thereof and which has an average particle diameter of not more than 10 µm and a gel content of at least 20%. Said composition is superior in permanent compression set, flex resistance, mechanical strengths, heat resistance and oil resistance.摘要翻译： 一种热塑性聚合物组合物，其基本上由（A）20-99％（重量）的（ⅰ）聚酰胺，（ⅱ）聚酰胺弹性体或其混合物和（B）80-1％（重量）的橡胶组分组成， （1）70-99.98重量％橡胶，（2）0.01-20重量％交联单体和（3）0.01-20重量％具有羧基的烯属不饱和单体的共聚物，环氧 组或其两者，并且其具有不超过10μm的平均粒径和至少20％的凝胶含量。 所述组合物在永久压缩永久变形，耐弯曲性，机械强度，耐热性和耐油性方面优异。
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公开(公告)号：EP0736366B1
公开(公告)日：2002-10-02
申请号：EP96302448.4
申请日：1996-04-04
CPC分类号： B29C49/4823 , B29C35/041 , B29C35/045 , B29C35/049 , B29C35/08 , B29C49/04 , B29C49/20 , B29C49/78 , B29C49/783 , B29C2035/1616 , B29C2035/1658 , B29C2049/2008 , B29C2049/2402 , B29C2049/4876 , B29K2105/04 , Y10S264/904
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4.发明公开Molding apparatus and molding process utilizing the same 失效Formvorrichtung und Verfahren zu ihrer Herstellung
公开(公告)号：EP0736366A3
公开(公告)日：1999-01-20
申请号：EP96302448.4
申请日：1996-04-04
CPC分类号： B29C49/4823 , B29C35/041 , B29C35/045 , B29C35/049 , B29C35/08 , B29C49/04 , B29C49/20 , B29C49/78 , B29C49/783 , B29C2035/1616 , B29C2035/1658 , B29C2049/2008 , B29C2049/2402 , B29C2049/4876 , B29K2105/04 , Y10S264/904
摘要： A process and an apparatus for molding, in which a molten thermoplastic resin is firmly fitted onto a molding surface (30) of a mold under a pressure lower than or equal to 100 kg/cm 2 and is cured to obtain a molded product. The molding apparatus has a mold main body (4), and a mold body (3) on which the molding surface (90) is defined. The mold body (3) is supported relative to the mold main body (4) with maintaining a space (B) on the back side (31) of the molding surface (30) in a heat insulative manner by a supporting member (1) which includes at least a heat insulative supporting member having a thermal conductivity of 0.001 to 1 Kcal/mh °C and a longitudinal elastic modulus of 0.01 to 10 kg/cm 2 . In the space (B), a heating fluid for heating the molding surface (30) from the bask side to a temperature higher than or equal to Vicat softening temperate (T) °C of the thermoplastic resin and a cooling fluid for cooling the molding surface (30) from the back side to a temperature lower than or equal to (Vicat softening temperature (T) of the thermoplastic resin - 10) °C are supplied.
摘要翻译： 一种成型方法和装置，其中熔融热塑性树脂在低于或等于100kg / cm 2的压力下牢固地装配到模具的模制表面（30）上并固化以获得模塑产品 。 成型装置具有模具主体（4）和形成有成形面（90）的模具体（3）。 模具主体（3）通过支撑构件（1）以绝热方式在模制主体（4）上支撑在模制表面（30）的背侧（31）上的空间（B） 其至少包括热导率为0.001〜1Kcal / mh℃，纵向弹性模量为0.01〜10kg / cm 2的隔热支撑构件。 在该空间（B）中，将从底部侧的成形面（30）加热到高于或等于热塑性树脂的维卡软化温度（T）℃的温度的加热流体和冷却成形用冷却液 表面（30）从背面到低于或等于（热塑性树脂的维卡软化温度（T）-10）℃的温度。
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公开(公告)号：EP0736366A2
公开(公告)日：1996-10-09
申请号：EP96302448.4
申请日：1996-04-04
CPC分类号： B29C49/4823 , B29C35/041 , B29C35/045 , B29C35/049 , B29C35/08 , B29C49/04 , B29C49/20 , B29C49/78 , B29C49/783 , B29C2035/1616 , B29C2035/1658 , B29C2049/2008 , B29C2049/2402 , B29C2049/4876 , B29K2105/04 , Y10S264/904
摘要： A process and an apparatus for molding, in which a molten thermoplastic resin is firmly fitted onto a molding surface (30) of a mold under a pressure lower than or equal to 100 kg/cm 2 and is cured to obtain a molded product. The molding apparatus has a mold main body (4), and a mold body (3) on which the molding surface (90) is defined. The mold body (3) is supported relative to the mold main body (4) with maintaining a space (B) on the back side (31) of the molding surface (30) in a heat insulative manner by a supporting member (1) which includes at least a heat insulative supporting member having a thermal conductivity of 0.001 to 1 Kcal/mh °C and a longitudinal elastic modulus of 0.01 to 10 kg/cm 2 . In the space (B), a heating fluid for heating the molding surface (30) from the bask side to a temperature higher than or equal to Vicat softening temperate (T) °C of the thermoplastic resin and a cooling fluid for cooling the molding surface (30) from the back side to a temperature lower than or equal to (Vicat softening temperature (T) of the thermoplastic resin - 10) °C are supplied.
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公开(公告)号：EP0409580A3
公开(公告)日：1992-04-15
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by eight of at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer. The above thermopalstic elastomer composition has properties comparable to a vulcanized rubber and is useful in various industrial parts.
摘要翻译： 1。一种热塑性弹性体组合物，其特征在于，含有：（i）氢化二烯系聚合物，该氢化二烯系聚合物是由（C）1,2-乙烯基含量的聚丁二烯嵌段链段 和（D）作为聚丁二烯或链烯基芳族化合物 - 丁二烯共聚物的嵌段链段，其丁二烯部分的1,2-乙烯基含量为25-95％，所述嵌段结构为 由式C-（DC）n或（CD）m表示的直链或支链嵌段共聚物，其中C表示上述聚丁二烯嵌段链段（C），D表示上述嵌段链段（D）， n表示1或更大的整数，m表示2或更大的整数，至少90％的直链或支链嵌段共聚物的丁二烯部分中的双键被氢化，或（i'）改性氢化 二烯聚合物，其中0.01至10摩尔％的至少一种功能基团 （i）中加入选自羧基，酸酐基，羟基，环氧基，卤素原子和氨基中的至少一种，并且通过八种1-99个单元中的至少一种选自 该组由热塑性树脂和橡胶状聚合物组成。 上述热溶性弹性体组合物具有与硫化橡胶相当的性能，并可用于各种工业部件。
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公开(公告)号：EP0409580A2
公开(公告)日：1991-01-23
申请号：EP90307827.7
申请日：1990-07-17
IPC分类号： C08L15/00 , C08L101/00 , C08L53/00
CPC分类号： C08L53/005 , C08C19/02 , C08L9/00 , C08L9/06 , C08L21/00 , C08L51/00 , C08L51/006 , C08L53/02 , C08L53/025 , C08L67/02 , C08L77/00 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic elastomer composition comprising: 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95%, the block structure of said straight or branched chain block copolymer being represented by the formula, C-(D-C) n or (C-D) m in which C means the above-mentioned polybutadiene block segment (C), D means the above-mentioned block segment (D), n means an integer of 1 or more and m means an integer of 2 or more, at least 90% of the double bond in the butadiene portion of the straight or branched chain block copolymer having been hydrogenated, or (i′) a modified hydrogenated diene polymer in which 0.01 to 10 mole % of at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, hydroxyl group, epoxy group, halogen atom and amino group is added to the hydrogenated diene polymer (i), and 1-99 parts by eight of at least one member selected from the group consisting of a thermoplastic resin and a rubbery polymer. The above thermopalstic elastomer composition has properties comparable to a vulcanized rubber and is useful in various industrial parts.
摘要翻译： 一种热塑性弹性体组合物，其包含：99-1重量份的（ⅰ）氢化二烯聚合物，其是由（C）具有1,2-乙烯基含量的聚丁二烯嵌段链段构成的直链或支链嵌段共聚物的氢化产物 为（D）作为聚丁二烯或链烯基芳族化合物 - 丁二烯共聚物的嵌段链段，其丁二烯部分的1,2-乙烯基含量为25-95％，所述嵌段结构为 直链或支链嵌段共聚物由式C-（DC）n或（CD）m表示，其中C表示上述聚丁二烯嵌段段（C），D表示上述嵌段链段（D）， n表示1以上的整数，m表示2以上的整数，直链或支链嵌段共聚物的丁二烯部分中的双键的至少90％被氢化，或（i分钟）改性氢化 二烯聚合物，其中0.01至10摩尔％的至少一种官能团 将由羧基，酸酐基，羟基，环氧基，卤素原子和氨基组成的组中加入的加成物加入到氢化二烯系聚合物（i）中，将1-99份×8的至少一种选自 由热塑性树脂和橡胶状聚合物组成的组。 上述热塑性弹性体组合物具有与硫化橡胶相当的性质，并且可用于各种工业部件。
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公开(公告)号：EP0275186A2
公开(公告)日：1988-07-20
申请号：EP88300235.4
申请日：1988-01-12
发明人： Ono, Hisao , Nagano, Masanobu , Sato, Hozumi , Miyachi, Takumi
CPC分类号： C08L51/04 , C08L9/00 , C08L77/00 , C08L77/02 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic polymer composition consisting essentially of
(A) 20-99% by weight of (i) a polyamide, (ii) a polyamide elastomer or a mixture thereof and
(B) 80-1% by weight of a rubber component which is a copolymer of (1) 70 - 99.98% by weight of a rubber, (2) 0.01-20% by weight of a crosslinking monomer and (3) 0.01-20% by weight of an olefinically unsaturated monomer having a carboxyl group, an epoxy group or both thereof and which has an average particle diameter of not more than 10 µm and a gel content of at least 20%. Said composition is superior in permanent compression set, flex resistance, mechanical strengths, heat resistance and oil resistance.摘要翻译： 一种热塑性聚合物组合物，其基本上由（A）20-99重量％的（i）聚酰胺，（ii）聚酰胺弹性体或其混合物组成，和（B）80-1重量％的橡胶组分，其为 （1）70-99.98重量％的橡胶的共聚物，（2）0.01-20重量％的交联单体和（3）0.01-20重量％的具有羧基的烯属不饱和单体，环氧树脂 组或二者，平均粒径不大于10μm，凝胶含量至少为20％。 所述组合物在永久压缩变形，抗弯曲性，机械强度，耐热性和耐油性方面优异。 G
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