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公开(公告)号:EP2301991A1
公开(公告)日:2011-03-30
申请号:EP09794550.5
申请日:2009-07-09
申请人: Japan Science And Technology Agency , National University Corporation Kanazawa University , JSR Corporation
CPC分类号: C08G77/60
摘要: A polysilane production process comprising reacting a specific silane compound typified by a cyclic silane compound represented by the following formula (2) in the presence of a binuclear metal complex represented by the following formula (4).
Si j H 2j (2)
(in the formula (2), j is an integer of 3 to 10.)
[CpM(µ-CH 2 )] 2 (4)
(in the formula (4), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.)摘要翻译: 一种聚硅烷的制造方法,其特征在于,在下述式(4)所示的双核金属络合物的存在下,使以下述式(2)表示的环状硅烷化合物为代表的特定硅烷化合物反应。 (式(2)中,j为3〜10的整数。)[式(4)中,C p为环戊二烯基系配体, M是选自Rh和Ir的金属原子,并且M之间的键是双键。)
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公开(公告)号:EP2301990A1
公开(公告)日:2011-03-30
申请号:EP09794549.7
申请日:2009-07-09
申请人: Japan Science And Technology Agency , National University Corporation Kanazawa University , JSR Corporation
CPC分类号: C08G77/60 , C07F7/0896
摘要: A polymer production process comprising reacting a compound represented by the following formula (1) in the presence of a binuclear metal complex represented by the following formula (2).
R 4-n MH n (1)
(in the formula (1), R is a monovalent organic group, M is a silicon atom or a germanium atom, and n is 2 or 3.)
[CpM(µ-CH 2 )] 2 (2)
(in the formula (2), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.)摘要翻译: 一种聚合物制备方法,包括在下式(2)表示的双核金属络合物的存在下使由下式(1)表示的化合物反应。 ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR4-n MH n€ƒ€ƒ€ƒ(1)(在公式(1)中,R是一价有机组,M 是硅原子或锗原子,n为2或3.)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ[CpM(μ-CH 2)] 2€ƒ€ƒ€ƒ€ ƒƒ(2)(式(2)中,Cp为环戊二烯基配体,M为选自Rh和Ir的金属原子,M之间的键为双键。
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