公开(公告)号：EP1790613A1

公开(公告)日：2007-05-30

申请号：EP05765739.7

申请日：2005-07-13

申请人： Japan Science and Technology Agency ,  Taiyo Nippon Sanso Corporation ,  Otsuka Chemical Holdings Co., Ltd. ,  Nissin Electric Co., Ltd. ,  Public University Corporation, Osaka Prefecture University

发明人： NAKAYAMA, Yoshikazu ,  NAGASAKA, Takeshi, TAIYO NIPPON SANSO CORPORATION ,  SAKAI, Toru, TAIYO NIPPON SANSO CORPORATION ,  GOTO, Toshiki, OTSUKA CHEMICAL CO., LTD. ,  TSUCHIYA, Hiroyuki, NISSIN ELECTRIC CO., LTD. ,  SHIONO, Keisuke, DAIKEN CHEMICAL CO., LTD. ,  OKAZAKI, Nobuharu

IPC分类号： C01B31/02 ,  D01F9/127 ,  D01F9/133

CPC分类号： D01F9/127 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/36 ,  D01F9/133

摘要： The subject invention provides a stable mass production method of carbon nano structure at low cost immune to variation of particle diameter of the catalyst microparticle in the catalyst material. The subject invention also provides a production device used for the method, and a new carbon nano structure having a conformation suitable for the mass production.
The production method of carbon nano structure comprising fluidizing a material gas and catalyst microparticles in the reactor so that the material gas and the catalyst microparticles are brought into contact with each other, wherein said catalyst microparticles are suspended by the instantaneous spraying of the high-pressure gas, and then the suspension effect of the catalyst microparticles is stopped so that the catalyst microparticles naturally fall. The particle diameter of the catalyst microparticles is thus selected. With this arrangement, only the selected catalyst microparticles with the desired diameter are supplied to the reactor. Since this arrangement is immune to influence of variation in particle diameter of catalyst microparticles contained in the catalyst material, it achieves stable mass production of carbon nano structure at low cost.

摘要翻译： 本发明提供碳纳米结构体的成本低的免疫材料中的微粒催化剂催化剂的粒径的变化的稳定的大量生产方法。 本主题发明做提供用于该方法的制造装置，和具有适合于大量生产的构造一个新的碳纳米结构。 碳纳米结构物的制造方法，包括在反应器中的流化的原料气体和催化剂微粒子所以没有将原料气体和催化剂微粒子被带入与海誓山盟接触，worin所述催化剂微粒通过高压的瞬时喷涂悬浮 气，然后催化剂微粒的悬浮效果被停止如此做了催化剂微粒自然下降。 微粒催化剂的颗粒直径被如此选择。 利用这种布置，只有具有所需直径的选择的催化剂微粒子供给到反应器中。 由于这种布置是免疫中所含的催化剂的催化剂材料的微粒的粒径的变化的影响，实现了以低成本稳定批量生产碳纳米结构的。

公开(公告)号：EP1810949A1

公开(公告)日：2007-07-25

申请号：EP05785943.1

申请日：2005-09-21

申请人： Japan Science and Technology Agency ,  Taiyo Nippon Sanso Corporation ,  Otsuka Chemical Holdings Co., Ltd. ,  Nissin Electric Co., Ltd.

发明人： NAKAYAMA, Yoshikazu ,  TSUCHIYA, Hiroyuki, c/o Nissin Electric Co., Ltd. ,  HIGASHI, Yugo, c/o Nissin Electric Co., Ltd. ,  GOTO, Toshiki, c/o Otsuka Chemical Co., Ltd. ,  SHIONO, Keisuke, c/o Deiken Chemical Co. Ltd. ,  NAGASAKA, Takeshi, c/o Taiyo Nippon Sanso Corp. ,  OKAZAKI, Nobuharu

IPC分类号： C01B31/02

CPC分类号： B82Y40/00 ,  B01J8/008 ,  B01J8/1818 ,  B01J8/1836 ,  B01J23/825 ,  B01J23/835 ,  B01J2208/00212 ,  B01J2208/00548 ,  B01J2219/00006 ,  B82Y30/00 ,  C01B32/05 ,  C01B32/162

摘要： A material gas and a catalyst are introduced through a material supplying tube path (4) and a catalyst supplying tube path (3) together with a carrier gas into a reactor (1) equipped on its outer periphery with a heat applicator (12) for thermally decomposing the material gas. The reactor (1) has a convention regulator (61) fitted to the discharge end of the catalyst supplying tube path (3). The convection regulator (61) covers an edge side of the reactor (1) to regulate gas flow in the reactor so that the flow does not reach the edge side. Due to this, a convection state can be efficiently produced in a reaction region. Consequently, it becomes possible to prevent contamination defect caused by accumulation/adherence of concretion of catalyst, which was generated by aggregation of cooled catalyst in the low-temperature region of the reactor (1) and a decomposition product of the material gas. Thus the efficiency of carbon nanostructure production can be improved.

摘要翻译： 材料气体和催化剂通过材料供应管路（4）和催化剂供应管路（3）与载气一起引入到其外周装备的反应器（1）中，所述反应器（1）具有用于 热分解原料气。 反应器（1）具有安装在催化剂供给管路（3）的排出端的惯性调节器（61）。 对流调节器（61）覆盖反应器（1）的边缘侧，以调节反应器中的气流，使得流体不到达边缘侧。 由此，可以在反应区域中有效地产生对流状态。 因此，可以防止由反应器（1）的低温区域中冷却的催化剂的凝集产生的催化剂的凝结的累积/粘附引起的污染缺陷和原料气体的分解产物。 因此，可以提高碳纳米结构生产的效率。

公开(公告)号：EP1649929B1

公开(公告)日：2009-04-29

申请号：EP04735390.9

申请日：2004-05-28

申请人： Japan Science and Technology Agency ,  Public University Corporation Osaka Prefecture University ,  Taiyo Nippon Sanso Corporation ,  OTSUKA CHEMICAL COMPANY, LIMITED ,  Nissin Electric Co., Ltd.

发明人： NAKAYAMA, Yoshikazu ,  PAN, Lujun ,  NOSAKA, Toshikazu ,  SUEKANE, Osamu ,  OKAZAKI, Nobuharu ,  NAGASAKA, Takeshi, c/o TAIYO NIPPON SANSON CORPORA ,  GOTO, Toshiki, c/o OTSUKA CHEMICAL CO. LTD. ,  TSUCHIYA, Hiroyuki, c/o NISSIN ELECTRIC CO. LTD. ,  OKAWA, Takashi, c/o DAIKEN CHEMICAL Co. Ltd. ,  SHIONO, Keisuke, c/o DAIKEN CHEMICAL Co. Ltd.

IPC分类号： B01J27/22 ,  B01J29/76 ,  B01J23/835 ,  B01J23/86 ,  B01J37/02 ,  B01J35/02 ,  D01F9/127 ,  C01B31/02 ,  B01J29/14

CPC分类号： B82Y30/00 ,  B01J23/835 ,  B01J27/22 ,  B01J29/146 ,  B82Y40/00 ,  C01B32/18 ,  C01B32/90 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/13 ,  C01P2006/16 ,  D01F9/127

摘要： A catalyst for preparing a carbon nanocoil which comprises a carbide catalyst comprising the elements of (transition metal element, In, C) or (transition metal element, Sn, C), or comprises a metal catalyst comprising the elements of (Fe, Al, Sn) or (Fe, Cr, Sn). The transition metal element of the carbide catalyst is preferably Fe, Co or Ni. More preferable catalysts include Fe3InC0.5, Fe3InC0.5Snw and Fe3SnC. A catalyst comprising a porous carrier and the above catalyst carried thereon is capable of controlling the diameters of the wire and the coil of the resulting carbon nanocoil. The above catalyst allows the preparation of a carbon nanocoil with high efficiency, and it has been found through taking the catalyst nucleus attached on the apex of a carbon nanocoil as a true catalyst for preparing the carbon nanocoil and determining the structure of the catalyst nucleus.

公开(公告)号：EP1777195A8

公开(公告)日：2008-04-23

申请号：EP05734218.0

申请日：2005-04-19

申请人： Japan Science and Technology Agency ,  OSAKA PREFECTURAL GOVERNMENT ,  Taiyo Nippon Sanso Corporation ,  Otsuka Chemical Co., Ltd. ,  Nissin Electric Co., Ltd. ,  Public University Corporation Osaka Prefecture University

发明人： NAKAYAMA, Yoshikazu ,  NOSAKA, Toshikazu ,  SUEKANE Osamu ,  NAGASAKA Takeshi c/o Taiyo Nippon Sanso Corporation ,  GOTO Toshiki c/o Otsuka Chemical Co., Ltd. ,  TSUCHIYA Hiroyuki c/o Nissin Electric Co., Ltd. ,  SHIONO Keisuke c/o Daiken Chemical Co., Ltd.

IPC分类号： C01B31/02 ,  B32B9/00 ,  B82B1/00 ,  D02G3/02 ,  D03D15/12

CPC分类号： C01B31/00 ,  B82B1/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/158 ,  C01B32/162 ,  C01B2202/08 ,  Y10S977/742 ,  Y10T428/24372 ,  Y10T428/2918 ,  Y10T428/292

摘要： An aggregate of carbon-based fine structures in which a plurality of carbon-based fine structures are collected, wherein respective carbon-based fine structures are oriented in the same direction. The above aggregate of carbon-based fine structures is an aggregate of a plurality of carbon-based fine structures in a state they are pulled by one another with strong interaction, and has such a length that allows the improvement of the handeability and workability thereof.

公开(公告)号：EP1777195A1

公开(公告)日：2007-04-25

申请号：EP05734218.0

申请日：2005-04-19

申请人： Japan Science and Technology Agency ,  OSAKA PREFECTURAL GOVERNMENT ,  Taiyo Nippon Sanso Corporation ,  Otsuka Chemical Co., Ltd. ,  NISSIN ELECTRIC COMPANY, LIMITED ,  Public University Corporation, Osaka Prefecture University

发明人： NAKAYAMA, Yoshikazu ,  NOSAKA, Toshikazu ,  SUEKANE, Osamu ,  NAGASAKA, Takeshi, ,  GOTO, Toshiki, OTSUKA CHEMICL Ltd., ,  TSUCHIYA, Hiroyuki, NISSIN ELECTRIC Co., Ltd., ,  SHIONO, Keisuke, DAIKEN CHEMICAL Co., Ltd.,

IPC分类号： C01B31/02 ,  B32B9/00 ,  B82B1/00 ,  D02G3/02 ,  D03D15/12

CPC分类号： C01B31/00 ,  B82B1/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/158 ,  C01B32/162 ,  C01B2202/08 ,  Y10S977/742 ,  Y10T428/24372 ,  Y10T428/2918 ,  Y10T428/292

摘要： An aggregate of carbon-based fine structures in which a plurality of carbon-based fine structures are collected, wherein respective carbon-based fine structures are oriented in the same direction. The above aggregate of carbon-based fine structures is an aggregate of a plurality of carbon-based fine structures in a state they are pulled by one another with strong interaction, and has such a length that allows the improvement of the handeability and workability thereof.

公开(公告)号：EP1649929A1

公开(公告)日：2006-04-26

申请号：EP04735390.9

申请日：2004-05-28

申请人： Japan Science and Technology Agency ,  OSAKA PREFECTURE ,  Taiyo Toyo Sanso Co., Ltd. ,  OTSUKA CHEMICAL COMPANY, LIMITED ,  Nissin Electric Co., Ltd. ,  Daiken Chemical Co. Ltd. ,  OSAKA PREFECTURE UNIVERSITY

发明人： NAKAYAMA, Yoshikazu ,  PAN, Lujun ,  NOSAKA, Toshikazu ,  SUEKANE, Osamu ,  OKAZAKI, Nobuharu ,  NAGASAKA, Takeshi, c/o TAIYO NIPPON SANSON CORPORA ,  GOTO, Toshiki, c/o OTSUKA CHEMICAL CO. LTD. ,  TSUCHIYA, Hiroyuki, c/o NISSIN ELECTRIC CO. LTD. ,  OKAWA, Takashi, c/o DAIKEN CHEMICAL Co. Ltd. ,  SHIONO, Keisuke, c/o DAIKEN CHEMICAL Co. Ltd.

IPC分类号： B01J27/22 ,  B01J29/76 ,  B01J23/835 ,  B01J23/86 ,  B01J37/02 ,  B01J35/02 ,  D01F9/127 ,  C01B31/02

CPC分类号： B82Y30/00 ,  B01J23/835 ,  B01J27/22 ,  B01J29/146 ,  B82Y40/00 ,  C01B32/18 ,  C01B32/90 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/13 ,  C01P2006/16 ,  D01F9/127

摘要： A method for synthesizing carbon nanocoils with high efficiency, by determining the structure of carbon nuclei that have been attached to the ends of carbon nanocoils and thus specifying a true catalyst for synthesizing carbon nanocoils is implemented. The catalyst for synthesizing carbon nanocoils according to the present invention is a carbide catalyst that contains at least elements (a transition metal element, In, C) or (a transition metal element, Sn, C), and in particular, it is preferable for the transition metal element to be Fe, Co or Ni. In addition to this carbide catalyst, a metal catalyst of (Fe, Al, Sn) and (Fe, Cr, Sn) are effective. From among these, catalysts such as Fe 3 InC 0.5 , Fe 3 InC 0.5 Snw and Fe 3 SnC are particularly preferable. The wire diameter and the coil diameter can be controlled by using a catalyst where any of these catalysts is carried by a porous carrier.

摘要翻译： 通过确定已经连接到碳纳米线的末端的碳原子核的结构，从而确定了用于合成碳纳米线的真正的催化剂，实现了高效合成碳纳米线的方法。 根据本发明的用于合成碳纳米薄膜的催化剂是至少含有元素（过渡金属元素，In，C）或（过渡金属元素Sn，C）的碳化物催化剂，特别地，优选 过渡金属元素为Fe，Co或Ni。 除了这种碳化物催化剂之外，（Fe，Al，Sn）和（Fe，Cr，Sn）的金属催化剂也是有效的。 其中，特别优选Fe 3 InC 0.5，Fe 3 InC 0.5 Snw，Fe 3 SnC等催化剂。 线径和线圈直径可以通过使用其中任何这些催化剂由多孔载体承载的催化剂来控制。

公开(公告)号：EP1630134A1

公开(公告)日：2006-03-01

申请号：EP04722656.8

申请日：2004-03-23

申请人： Japan Science and Technology Corporation ,  OSAKA PREFECTURE ,  Taiyo Nippon Sanso Corporation ,  Nissin Electric Co., Ltd. ,  OTSUKA CHEMICAL COMPANY, LIMITED ,  Daiken Chemical Co., Ltd

发明人： SUEKANE, Osamu ,  NOSAKA, Toshikazu ,  NAKAYAMA, Yoshikazu ,  PAN, Lujun ,  NAGASAKA, Takeshi, c/o TAIYO TOYO SANSO Co., Ltd. ,  SAKAI, Toru, c/o TAIYO TOYO SANSO Co., Ltd. ,  TSUCHIYA, Hiroyuki, c/o NISSIN ELECTRIC CO., LTD. ,  GOTO, Toshiki, c/o OTSUKA CHEMICAL CO., LTD. ,  LI, Xu, c/o DAIKEN CKEMICAL Co., Ltd.

IPC分类号： C01B31/02

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/30

摘要： Developed is high-efficiency synthesis method and apparatus capable of promoting the initial growth of carbon nanostructure by eliminating the initial fluctuation time and rising time in raw gas flow quantity.
A high-efficiency synthesis method of carbon nanostructure according to the present invention is a high-efficiency synthesis method of carbon nanostructure, the method comprising: bringing raw material gas and a catalyst into contact with each other under reactive conditions so as to produce a carbon nanostructure, wherein: the initiation of contact of the raw material gas with the catalyst is carried out instantaneously. Reaction conditions such as temperature and raw material gas concentration are set so as to meet those for catalyst growth, and under the reaction conditions, the initiation of contact of raw material gas G with catalyst 6 is carried out instantaneously. Consequently, the initial growth of carbon nanostructure is positively carried out, and the height growth and thickness growth thereof can be effected in high efficiency. Further, high-density growth and short-time high-speed growth can be realized. The catalyst includes any forms of catalyst such as catalyst substrate, catalyst structure, catalyst powders and catalyst pellet. It is especially preferred to employ a system wherein the feed and interruption of the raw material gas G are intermittently controlled by means of an electromagnetic three-way valve 24.

摘要翻译： 开发了通过消除原始气体流量的初始波动时间和上升时间，可以促进碳纳米结构初始生长的高效合成方法和装置。 根据本发明的碳纳米结构的高效合成方法是碳纳米结构的高效合成方法，该方法包括：使原料气体和催化剂在反应条件下彼此接触，以产生碳 纳米结构，其中：原料气与催化剂的接触开始立即进行。 反应条件如温度和原料气体浓度设定为满足催化剂生长的条件，在反应条件下，原料气体G与催化剂6的接触开始立即进行。 因此，积极地进行碳纳米结构的初始生长，并且可以高效率地实现其高度生长和厚度生长。 此外，可以实现高密度生长和短时高速生长。 催化剂包括任何形式的催化剂，如催化剂底物，催化剂结构，催化剂粉末和催化剂颗粒。 特别优选采用其中通过电磁三通阀24间歇地控制原料气体G的进料和中断的系统。

公开(公告)号：EP1987878A1

公开(公告)日：2008-11-05

申请号：EP07714703.1

申请日：2007-02-21

申请人： Taiyo Nippon Sanso Corporation

发明人： NAKAYAMA, Yoshikazu ,  NAGASAKA, Takeshi ,  SAKAI, Toru ,  SUEKANE, Osamu

IPC分类号： B01J23/745 ,  B01J23/825 ,  B01J23/835 ,  B01J37/12 ,  B01J37/14 ,  B01J37/16 ,  B82B3/00 ,  C01B31/02

CPC分类号： B01J23/745 ,  B01J35/002 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162

摘要： It is the purpose of this invention to present a process for producing carbon nanostructure in which the mechanism of continuous carbon nanostructure growth can be optimized and a high-quality carbon nanostructure can be produced, a catalyst for carbon nanostructure growth which is for use in the production, a raw-material gas and a carrier gas for producing the same, and an apparatus for producing the same. The process for carbon nanostructure production, in which the length of the nanostructure can be continuously controlled comprises feeding a carrier gas and a raw-material gas to a reaction chamber (4) to produce a carbon nanostructure (2) with a catalytic structure (6), wherein the concentrations of oxidation gases contained in the carrier gas and raw-material gas, such as oxygen and water (in the case of raw-material acetylene gas, minor ingredients such as DMF and acetone, which are solvents), are regulated to a moderate value. Thus, a carbon nanostructure of good quality can be produced at a high efficiency.

摘要翻译： 它是本发明的目的是提出一种用于生产碳纳米结构物在哪个连续的碳纳米结构物成长的机构可以被优化和高品质的碳纳米结构可以制造，对碳纳米结构物成长的催化剂全部是用于在使用 生产中，原料气体和用于生产其的载气，并且对制造装置相同。 对碳纳米结构物的生产过程中，其中纳米结构的长度可连续地控制包括将载气和原料气体的反应室（4）与催化结构以产生碳纳米结构体（2）（6 ）worin包含在载气和原料气，：诸如氧气和水（以原料的乙炔气体的情况下，次要成分的氧化气体的浓度：如DMF和丙酮，其溶剂）进行调节 以适度的值。 因此，良好质量的碳纳米结构物能够以高效率制造。

公开(公告)号：EP2259043A1

公开(公告)日：2010-12-08

申请号：EP09714780.5

申请日：2009-02-26

申请人： Japan Science and Technology Agency

发明人： NAKAYAMA, Yoshikazu ,  HIRAHARA, Kaori ,  SENGA, Ryosuke

IPC分类号： G01N13/10

CPC分类号： G01Q70/12

摘要： Disclosed is a CNT nanodevice using small-diameter CNT having a monolayer, two-layer or other structure produced by virtue of strong CNT fastening treatment under high vacuum of an environment having a very low residual hydrocarbon content. Also disclosed are a CNT supporting body such as a CNT holding body necessary for the production process of the CNT nanodevice, and a process for producing the CNT supporting body. A supporting portion (18a) is provided on a supporting body (18). A base end portion (15a) in CNT (15) is transferred to the supporting portion (18a), and electron beams (17) or ion beams are applied toward the base end portion (15a) in CNT (15). A carbon material layer (19) covering the base end portion (15a) and the supporting portion (18a) is converted to an amorphous carbon layer and a graphite layer by the application of the beams. CNT (15) is fixed to the supporting body (18) by the graphite layer to produce the CNT supporting body. The application of the beams is carried out under high vacuum within TEM.

摘要翻译： 公开了使用具有单层，双层或其它结构的小直径CNT的CNT纳米器件，其通过在具有非常低的残余烃含量的环境的高真空下由于强CNT紧固处理而产生。 还公开了CNT纳米器件的制造工序所需的碳纳米管保持体等CNT支撑体以及CNT支撑体的制造方法。 支撑部分（18a）设置在支撑体（18）上。 CNT（15）中的基端部（15a）被转移到支撑部（18a），电子束（17）或离子束朝向CNT（15）的基端部（15a）施加。 覆盖基端部（15a）的碳材料层（19）和支撑部（18a）通过施加梁将其转变为无定形碳层和石墨层。 CNT（15）通过石墨层固定到支撑体（18）上，以产生CNT支撑体。 梁的应用在TEM内高真空下进行。