摘要:
A catalyst for purification of exhaust gas, comprises: a substrate; and a catalyst coat layer which is formed on a surface of the substrate and which comprises catalyst particles, wherein the catalyst coat layer has an average thickness in a range of 25 to 160 µm, and a void fraction in a range of 50 to 80% by volume as measured by a weight-in-water method, 0.5 to 50% by volume of all voids in the catalyst coat layer consist of high-aspect ratio pores which have equivalent circle diameters in a range of 2 to 50 µm in a cross-sectional image of a cross-section of the catalyst coat layer which the cross-section is perpendicular to a flow direction of exhaust gas in the substrate, and which have aspect ratios of 5 or higher, and the high-aspect ratio pores have an average aspect ratio in a range of 10 to 50.
摘要:
When the amount of coating is increased in a two-layer catalyst or the like containing two noble metals in respective different layers, gas diffusivity in the catalyst and use efficiency of a catalytic active site are reduced to thereby reduce purification performance. In view of this, an organic fiber having a predetermined shape is used as a pore-forming material in formation of an uppermost catalyst coating layer of a multi-layer catalyst, to thereby form an uppermost catalyst coating layer having a high-aspect-ratio pore excellent in connectivity and therefore excellent gas diffusivity.
摘要:
An object of the present invention is to provide an exhaust gas purification catalyst which can exhibit high durability and warm-up performance. The present invention relates to an exhaust gas purification catalyst comprising a substrate and a catalyst coating layer formed on the substrate, wherein the catalyst coating layer comprises catalyst particles, the catalyst coating layer having an upstream region extending by 40 to 60% of the entire length of the substrate from an upstream end of the catalyst in the direction of an exhaust gas flow and a downstream region corresponding to the remainder portion of the catalyst coating layer, the composition of the catalyst particle of the upstream region being different from that of the downstream region. The upstream region in the direction of an exhaust gas flow has a structure where a void is included in a large number, and furthermore high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain percentage or more of the whole volume of voids. Thus, the exhaust gas purification catalyst exhibits enhanced purification performance.
摘要:
The present invention is directed to address the following problem: in an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst and an underfloor catalyst, reduction in the gas diffusivity of the startup catalyst results in reduction in the use efficiency of a catalytic active site, resulting in reduction in purification performance. The present invention relates to an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst having a catalyst coating where a large number of voids are included and an underfloor catalyst, wherein high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain rate or more of the whole volume of the voids, to thereby enhance the purification performance of the catalyst.
摘要:
An object of the present invention is to provide an exhaust gas purification catalyst which can exhibit sufficient purification performance even under a high Ga condition. The present invention relates to an exhaust gas purification catalyst comprising a substrate and a catalyst coating layer formed on the substrate, wherein the catalyst coating layer comprises catalyst particles, the catalyst coating layer having an upstream region extending by 40 to 60% of the entire length of the substrate from an upstream end of the catalyst in the direction of an exhaust gas flow and a downstream region corresponding to the remainder portion of the catalyst coating layer, the composition of the catalyst particle of the upstream region being different from that of the downstream region. The downstream region in the direction of an exhaust gas flow has a structure where a void is included in a large number, and furthermore high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain percentage or more of the whole volume of voids. Thus, the exhaust gas purification catalyst exhibits enhanced purification performance.
摘要:
The present invention is directed to address the following problem: in an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst and an underfloor catalyst, reduction in the gas diffusivity of the underfloor catalyst results in reduction in the use efficiency of a catalytic active site, resulting in reduction in purification performance. The present invention relates to an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst and an underfloor catalyst having a catalyst coating where a large number of voids are included, wherein high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain rate or more of the whole volume of the voids, to thereby enhance the purification performance of the catalyst.
摘要:
The problem of the present invention is to provide an exhaust gas purification catalyst which can exhibit sufficient purification performance under a high Ga condition while having a resistance to stress such as high-temperature and poisonous substances. The present invention relates to an exhaust gas purification catalyst comprising two or more catalyst coating layers on a substrate, wherein a lower catalyst coating layer that is present lower with respect to an uppermost catalyst coating layer has a structure where a large number of voids are included and high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain proportion or more of the whole volume of voids, thereby to improve gas diffusivity in the lower catalyst coating layer.
摘要:
In the damper device, when the large diameter portion (51) does not apply an impact force on the flange portion (532), the elastic body (53b, 63b, 73b) is disposed in one of the housing (22) and the cylindrical portion with a gap and when the large diameter portion applies the impact force on the flange portion, the elastic body is compressed by the restricting surface and the flange portion in an axial direction to be deformed into a state that the elastic body is brought into contact with all of the housing, the restricting surface (52b, 62b), the cylindrical portion (531) and the flange portion to be filled in the gap. The impact receiving member (53a) is restricted from a movement relative to the housing by the deformed elastic body when the end portion (531 c) of the cylindrical portion (531) is advanced into the relief portion (52f, 62f, 72f) and the impact receiving member keeps a non-contact state with the housing.
摘要:
In the damper device, when the large diameter portion (51) does not apply an impact force on the flange portion (532), the elastic body (53b, 63b, 73b) is disposed in one of the housing (22) and the cylindrical portion with a gap and when the large diameter portion applies the impact force on the flange portion, the elastic body is compressed by the restricting surface and the flange portion in an axial direction to be deformed into a state that the elastic body is brought into contact with all of the housing, the restricting surface (52b, 62b), the cylindrical portion (531) and the flange portion to be filled in the gap. The impact receiving member (53a) is restricted from a movement relative to the housing by the deformed elastic body when the end portion (531 c) of the cylindrical portion (531) is advanced into the relief portion (52f, 62f, 72f) and the impact receiving member keeps a non-contact state with the housing.
摘要:
The exhaust gas purification device according to the present invention is provided with a particulate filter disposed in an exhaust passage of an internal combustion engine and capturing particulate matter in exhaust gas discharged from the internal combustion engine. The particulate filter is provided with a wall-flow part 20 having an inlet-side cell 22 that is open only at an end on an exhaust gas inflow side, an outlet-side cell 24 that is adjacent to this inlet-side cell 22 and is open only at an end on an exhaust gas outflow side, and a porous wall 26 that partitions the inlet-side cell 22 from the outlet-side cell 24, and is also provided with a straight-flow part 30 having a through cell 32 that penetrates the filter in an axial direction thereof and is open at the end on the exhaust gas inflow side as well as the end on the exhaust gas outflow side.