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公开(公告)号:EP2215101A1
公开(公告)日:2010-08-11
申请号:EP08843506.0
申请日:2008-10-30
发明人: ABDUR-RASHID, Kamaluddin , AMOROSO, Dino , GUO, Rongwei , CHEN, Xuanhua , SUI-SENG, Christine , TSANG, Chi-Wing , JIA, Wenli
IPC分类号: C07F15/00 , B01J23/74 , C07C211/65 , C07F15/02 , C07F9/50
CPC分类号: C07F15/0053 , B01J31/1805 , B01J31/181 , B01J31/189 , B01J31/2452 , B01J2231/4205 , B01J2231/4277 , B01J2231/641 , B01J2531/821 , B01J2531/825 , B01J2531/842 , C07C211/09 , C07C211/11 , C07C211/12 , C07C211/27 , C07C211/30 , C07C211/36 , C07C217/34 , C07C2601/14 , C07C2601/18 , C07F15/0046 , C07F15/025 , C07F17/02
摘要: The present disclosure includes catiomc complexes of iron, ruthenium, and osmium, and their use as catalysts in organic synthesis transformations including the hydrogenation of unsaturated compounds. The complexes are represented by the following formulae I, II, III, IV, and V, wherein M is Fe, Ru or Os, P is a monodentate ligand with a phosphorus donor atom, P2 is a bidentate neutral ligand with two phosphorus donor atoms, N2 is a bidentate neutral ligand with two nitrogen donor atoms, PN is a bidentate neutral ligand with phosphorus and nitrogen donor atoms, PNNP is a tetradentate neutral ligand bonded to M via two phosphorus and two nitrogen atoms, X is any anionic ligand, LB is any neutral Lewis base, Y is any non-coordmatmg anion, n is 0, 1, or 2, m is 1 or 2, q is 0 or 1, r is 1 or 2 and q + r = 2.
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公开(公告)号:EP2158154A1
公开(公告)日:2010-03-03
申请号:EP08748325.1
申请日:2008-05-16
发明人: ABDUR-RASHID, Kamaluddin , GRAHAM, Todd , TSANG, Chi-Wing , CHEN, Xuanhua , GUO, Rongwei , JIA, Wenli , AMOROSO, Dino , SUI-SENG, Christine
CPC分类号: C01B3/065 , B01J31/1805 , B01J31/1815 , B01J31/1875 , B01J31/189 , B01J31/2265 , B01J31/2273 , B01J31/24 , B01J2531/0238 , B01J2531/0255 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/847 , Y02E60/362 , Y02E60/364
摘要: The present disclosure relates to processes and methods of generating hydrogen via the hydrolysis or solvolyis of a compound of the formula (I), R1R2HNBHR3R4, using ligand-stabilized homogeneous metal catalysts.
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