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公开(公告)号：EP2305752A1
公开(公告)日：2011-04-06
申请号：EP09766624.2
申请日：2009-06-15
发明人： KATO, Masaki , TSUBOI, Akira , NAKAMAE, Masato , FUSS Robert , MICHEL Samuel
摘要： A polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a vinyl alcohol-based polymer having a degree of saponification of not less than 30 mol% and less than 75 mol% and having a viscosity average degree of polymerization of less than 300; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. A polyvinyl chloride resin composition is thereby provided that is good in thermal stability while being shaped and with which a shaped article of excellent transparency can be obtained.
摘要翻译： 聚氯乙烯树脂组合物含有：0.005〜5重量份皂化度为30摩尔％以上且小于75摩尔％的乙烯醇系聚合物，其粘度平均聚合度小于 300; 和0.01〜5重量份的锌化合物，基于100重量份的聚氯乙烯树脂。 由此提供一种聚乙烯树脂组合物，其在成形时热稳定性好，并且可以获得具有优异透明性的成型制品。
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公开(公告)号：EP2348070B1
公开(公告)日：2013-06-26
申请号：EP09819154.7
申请日：2009-10-05
发明人： KATO, Masaki , TSUBOI, Akira , NAKAMAE, Masato , FUSS, Robert , MICHEL, Samuel
CPC分类号： C08L27/06 , C08K5/098 , C08K5/103 , C08K5/12 , C08L29/04 , C08L2205/02 , C08L2205/03 , C08L2666/04
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公开(公告)号：EP2305752B1
公开(公告)日：2016-08-24
申请号：EP09766624.2
申请日：2009-06-15
发明人： KATO, Masaki , TSUBOI, Akira , NAKAMAE, Masato , FUSS Robert , MICHEL Samuel
摘要： A polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a vinyl alcohol-based polymer having a degree of saponification of not less than 30 mol% and less than 75 mol% and having a viscosity average degree of polymerization of less than 300; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. A polyvinyl chloride resin composition is thereby provided that is good in thermal stability while being shaped and with which a shaped article of excellent transparency can be obtained.
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4.发明公开POLYVINYL CHLORIDE RESIN COMPOSITIONS AND MANUFACTURING METHOD THEREFOR 有权VERFAHREN ZUR HERSTELLUNG VON POLYVINYLCHLORIDHARZZUSAMMENSETZUNGEN
公开(公告)号：EP2348070A1
公开(公告)日：2011-07-27
申请号：EP09819154.7
申请日：2009-10-05
发明人： KATO, Masaki , TSUBOI, Akira , NAKAMAE, Masato , FUSS, Robert , MICHEL, Samuel
CPC分类号： C08L27/06 , C08K5/098 , C08K5/103 , C08K5/12 , C08L29/04 , C08L2205/02 , C08L2205/03 , C08L2666/04
摘要： A polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a polyvinyl alcohol having a viscosity average degree of polymerization of from 100 to 3000 and having a ratio Mw/Mn of a weight average molecular weight Mw to a number average molecular weight Mn of from 2.2 to 4.9; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. A polyvinyl chloride resin composition is thereby provided that enables to obtain a shaped article thereof excellent in thermal stability while being shaped and less colored.
摘要翻译： 聚氯乙烯树脂组合物含有0.005〜5重量份的粘均聚合度为100〜3000的聚乙烯醇，重均分子量Mw与数均分子量Mw / Mn的比例 Mn为2.2〜4.9; 和0.01〜5重量份的锌化合物，基于100重量份的聚氯乙烯树脂。 由此提供了一种聚氯乙烯树脂组合物，其能够获得其成型性和颜色较少的热稳定性优异的成型制品。
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公开(公告)号：EP3699207A1
公开(公告)日：2020-08-26
申请号：EP18869225.5
申请日：2018-10-16
申请人： Kuraray Co., Ltd.
IPC分类号： C08F216/06 , C08F8/12 , C08J7/04 , C09D5/00 , C09D123/04 , C09D129/04
摘要： The present invention relates to ethylene-vinyl alcohol copolymer particles, comprising an ethylene-vinyl alcohol copolymer having an ethylene unit content of 1 mol% or more and less than 20 mol%, a viscosity-average polymerization degree of 200 to 5000, and a saponification degree of 80 to 99.99 mol%, wherein a crystallinity in water Cw (30 °C) at 30 °C and a crystallinity in water Cw (70 °C) at 70 °C as determined by pulse NMR satisfy formula (I). There is thus provided ethylene-vinyl alcohol copolymer particles having excellent solubility in water and excellent gas barrier performance.
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公开(公告)号：EP2735577B1
公开(公告)日：2017-12-13
申请号：EP12817551.0
申请日：2012-07-19
申请人： Kuraray Co., Ltd.
IPC分类号： C08F290/06 , B32B27/30 , B41M5/00 , B41M5/50 , B41M5/52 , C08F8/12 , C09D5/02 , C09D129/04 , C09D129/10 , D21H21/16
CPC分类号： C08F218/08 , B32B7/06 , B32B7/12 , B32B27/306 , B32B29/005 , B32B2250/26 , B32B2255/12 , B32B2255/26 , B32B2307/54 , B32B2307/726 , B32B2307/7265 , B32B2307/748 , B32B2554/00 , B41M5/5254 , B41M2205/32 , C08F8/12 , C08F290/062 , C09D131/04 , C09D151/08 , D21H19/60 , D21H21/16 , D21H27/001 , Y10T428/1476 , Y10T428/31895 , C08F216/06 , C08F218/00 , C08F220/58 , C08F2216/1433
摘要： Provided is a polyoxyalkylene modified vinyl alcohol-based polymer comprising a polyoxyalkylene group in a side chain, wherein the polymer has a viscosity average degree of polymerization of not less than 150 and not more than 5000, a degree of saponification of not less than 40 mol% and not more than 99. 99 mol%, and a polyoxyalkylene group modification rate of not less than 0.05 mol% and not more than 10 mol%; and the polyoxyalkylene group is composed of a polyoxypropylene block and a (poly) oxyethylene block and is represented by the following general formula (I). Such polymer is excellent in temperature-sensitive thickening properties. (in the general formula (I), R 1 denotes a hydrogen atom or an alkyl group having a carbon number of from 1 to 8; either one of R 2 and R 3 is a methyl group and the other is a hydrogen atom; and 10 ‰¤ m ‰¤ 40 and 1 ‰¤ n ‰¤ 50).
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7.发明授权VINYL ALCOHOL POLYMER-CONTAINING COATING AGENT FOR PAPER AND PAPER AND THERMAL PAPER COATED WITH THE COATING AGENT 有权乙烯醇系聚合物含涂剂文件，并与包衣剂和涂料纸热敏纸
公开(公告)号：EP2194188B1
公开(公告)日：2012-08-15
申请号：EP08834545.9
申请日：2008-09-19
申请人： Kuraray Co., Ltd.
CPC分类号： B41M5/5254 , B41M5/3372 , B41M5/44 , D21H19/20 , D21H19/24 , Y10T428/31895
摘要： This invention provides a vinyl alcohol polymer-containing coating agent for paper, which, despite the fact that a curing step after coating the coating agent onto a paper surface can be omitted, can form a layer (for example, a coating layer or a color developing layer) having excellent water resistance and having no significant susceptibility to yellowing with the elapse of time. The coating agent is an aqueous composition comprising a vinyl alcohol polymer (A) satisfying a formula “X + 0.2Y > 95”, wherein X represents the content of vinyl alcohol units, % by mole; and Y represents the content of ethylene units, % by mole, and an addition condensation product (B) between ethylene urea and glyoxal. In the addition condensation product (B), the content of the terminal aldehyde group per g of the solid is 1.2 to 3.0 (mmol). The weight ratio on a solid basis between the vinyl alcohol polymer (A) and the addition condensation product (B) is in the range of (A) : (B) = 99 : 1 to 50 : 50. In the above formula, X
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公开(公告)号：EP2292690A1
公开(公告)日：2011-03-09
申请号：EP09770111.4
申请日：2009-06-22
申请人： Kuraray Co., Ltd.
发明人： KATO, Masaki , TSUBOI, Akira , NAKAMAE, Masato
摘要： A polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a vinyl alcohol-based polymer having a degree of saponification of from 30 to 99. 9 mol%, having a viscosity average degree of polymerization of 1000 or less, and having a carboxyl group, a sulfonic acid group, or a salt thereof at a terminal; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. In addition, a polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a vinyl alcohol-based polymer having an alkyl group with a carbon number of 6 or more at a terminal, having a degree of saponification of from 30 to 99. 9 mol%, and having a viscosity average degree of polymerization of 1000 or less; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. A polyvinyl chloride resin composition is thereby provided which is excellent in thermal stability while being shaped and with which a less colored shaped article can be obtained.
摘要翻译： 聚氯乙烯树脂组合物含有：0.005〜5重量份的皂化度为30〜99.9摩尔％，粘均聚合度为1000以下的乙烯醇系聚合物， 末端羧基，磺酸基或其盐; 和基于100重量份聚氯乙烯树脂0.01至5重量份的锌化合物。 另外，聚氯乙烯树脂组合物含有0.005〜5重量份的末端具有碳数为6以上的烷基的乙烯醇系聚合物，皂化度为30〜99 9摩尔％，粘均聚合度为1000以下， 和基于100重量份聚氯乙烯树脂0.01至5重量份的锌化合物。 由此提供一种聚氯乙烯树脂组合物，其在形状上具有优异的热稳定性并且可以获得较少着色的成形制品。
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公开(公告)号：EP1857503A1
公开(公告)日：2007-11-21
申请号：EP06713289.4
申请日：2006-02-08
申请人： KURARAY CO., LTD.
发明人： MAKI, Hideki , TANIMOTO, Seiji , NAKAMAE, Masato
IPC分类号： C08L33/06 , C08F2/24 , C08L25/10 , C08L29/04 , C09D5/02 , C09D7/12 , C09D125/10 , C09D129/04 , C09D133/06
CPC分类号： C09D129/04 , C08F2/24 , C08L29/04 , C08L33/06 , C09D5/02 , C09D133/06 , C08L2666/04
摘要： [Object] To provide an aqueous emulsion which is excellent in mechanical stability and pigment compatibility and further is excellent in film transparency and solvent resistance, and a coating by the use thereof. [Solution Means] The object is achieved by the aqueous emulsion including a polymer having at least one monomer unit selected from the group consisting of a (meth)acrylate ester monomer unit, a styrene monomer unit and a diene monomer unit as a dispersoid, further including a vinyl alcohol polymer (A) having 1.9 mol% or more 1,2-glycol bond and a saponification degree of 70 mol% or more and a surfactant (B) as dispersants, wherein a weight ratio of (A) / (B) is 50/50 to 95/5 and an average particle diameter of dispersed particles is 0.5 µm or less, and the coating by the use thereof.
摘要翻译： 本发明提供机械稳定性和颜料相容性优异的水性乳液，并且还具有优异的膜透明性和耐溶剂性，以及通过其使用的涂层。 [解决方案]本发明的目的是通过包含具有至少一种选自（甲基）丙烯酸酯单体单元，苯乙烯单体单元和作为分散质的二烯单体单元的单体单元的聚合物的水性乳液，进一步 包括具有1.9摩尔％以上的1,2-二醇键，皂化度为70摩尔％以上的乙烯醇系聚合物（A）和作为分散剂的表面活性剂（B），其中（A）/（B ）为50/50〜95/5，分散粒子的平均粒径为0.5μm以下，通过使用涂布。
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公开(公告)号：EP3819316A1
公开(公告)日：2021-05-12
申请号：EP19831478.3
申请日：2019-07-04
申请人： Kuraray Co., Ltd.
IPC分类号： C08F8/14 , B01F17/52 , C08F2/20 , C08F216/06
摘要： The present invention provides a modified vinyl alcohol polymer having a side chain with an ethylenic double bond, and having reduced a water-insoluble content and superior storage stability in the form of an aqueous solution. The present invention also provides a method for producing such a modified vinyl alcohol polymer. A dispersion stabilizer for suspension polymerization comprising the modified vinyl alcohol polymer is also provided that provides superior polymerization stability during suspension polymerization of a vinyl compound, and with which reduced formation of coarse particles, high bulk specific gravity, and superior plasticizer absorbability can be achieved, in addition to reducing fisheyes. The present invention also provides a method for producing a vinyl polymer. The present invention relates to a modified vinyl alcohol polymer (A) having a degree of saponification of 68 mol% or more and less than 99.9 mol%, and a viscosity-average degree of polymerization of 200 or more and less than 3,000, and comprising a side chain with 0.01 mol% or more and less than 0.50 mol% of a double bond derived from an esterification agent, the esterification agent being one or more selected from the group consisting of (i) itaconic acid and/or derivatives thereof, and (ii) methacrylic acid and/or derivatives thereof, and the modified vinyl alcohol polymer (A) having a peak width W 0.05h of at least 2.85 minutes and less than 3.70 minutes at a height of 5% from the baseline in a peak measured by HPLC.
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