摘要:
The present invention relates to a thermoplastic resin composition showing excellent transparency and whitening resistance. The thermoplastic resin composition of the present invention comprises (A) a graft copolymer having a multilayer structure and (B) a thermoplastic copolymer, wherein the graft copolymer having a multilayer structure (A) comprises a core of a conjugated diene-based rubber latex having a weight average particle diameter of 500 Å to 2,000 Å; an intermediate layer; and a graft layer. The glass transition temperature of the intermediate layer is 40°C or less, the glass transition temperature of the graft layer is 80°C or more, and the refractive index difference between the graft copolymer (A) and the thermoplastic copolymer (B) is less than 0.01.
摘要:
The present invention relates to a transparent thermoplastic resin. More particularly, the present invention relates to a transparent thermoplastic resin, including a random copolymerization block prepared by polymerizing 50 to 80 % by weight of an aromatic vinyl compound, 10 to 30 % by weight of a vinyl cyanide compound, and 0 to 15 % by weight of (meth) acrylic acid alkyl ester; and an aromatic vinyl compound block prepared by polymerizing 1 to 10 % by weight of an aromatic vinyl compound, a transparent thermoplastic resin composition including the transparent thermoplastic resin, and methods of preparing the aromatic vinyl compound and transparent thermoplastic resin.
摘要:
The present invention relates to a graft copolymer having excellent thermal stability, a method of preparing the graft copolymer, a thermoplastic resin composition including the graft copolymer, and a molded part including the thermoplastic resin composition. More specifically, the present invention relates to a graft copolymer having a core-shell structure and having excellent thermal stability, which is prepared according to an emulsion polymerization method, in which a metal salt of sorbic acid is included in reactants in a specific amount and is used as an emulsifier. According to the method, thermal stability of a graft copolymer can be improved by using the metal salt of sorbic acid, which can be easily removed in a dehydration process, instead of a conventional emulsifier, which remains in a reaction product after completion of emulsion polymerization and lowers thermal stability of a prepared graft copolymer. In addition, according to the present invention, since the thermoplastic resin composition of the present invention includes the graft copolymer having excellent thermal stability, the thermoplastic resin composition and the molded part manufactured using the thermoplastic resin composition have excellent physical properties, such as impact strength, fluidity, and transparency. Furthermore, the degree of discoloration that may occur when the resin composition or the molded part is allowed to stay in an injection molding machine or stay at a high temperature for a long period of time may be reduced.
摘要:
The present invention relates to a thermoplastic resin composition and a molded article including the same. More particularly, the present invention relates to a thermoplastic resin composition including 100 parts by weight of a base resin that includes an acrylic graft copolymer and an acrylic non-graft copolymer; and greater than 0.3 parts by weight and less than 1.2 parts by weight of a zinc-based antimicrobial agent, and a molded article including the same, wherein the zinc-based antimicrobial agent has an average particle diameter of greater than 3 µm to 30 µm. In accordance with the present invention, a thermoplastic resin composition providing superior transparency and excellent initial antimicrobial activity and persistent antimicrobial activity while providing the same mechanical properties as existing resin compositions, and a molded article including the same are provided.
摘要:
The present invention relates to a graft copolymer, a thermoplastic resin composition including the graft copolymer, and a method of preparing the thermoplastic resin composition. More specifically, the present invention provides a graft copolymer having a shell in which silica modified with a specific compound is dispersed within a specific content range, a thermoplastic resin composition including the graft copolymer, and a method of preparing the thermoplastic resin composition. In the graft copolymer according to the present invention, since silica modified with a specific compound is dispersed in the periphery of rubber particles, that is, in the shell of the graft copolymer, the dispersibility of the graft copolymer may be improved. Therefore, the graft copolymer may have transparency equal to or better than a conventional graft copolymer. In addition, compared to a resin composition having an equivalent rubber content, the thermoplastic resin composition of the present invention may have excellent physical properties, such as impact strength and tensile strength.
摘要:
The present disclosure relates to a thermoplastic resin composition and a molded article manufactured from the same. More particularly, the present disclosure relates to a thermoplastic resin composition including (A) a graft copolymer prepared by graft-copolymerizing a conjugated diene rubber, a (meth)acrylic acid alkyl ester compound, a methylene butyrolactone compound, and an aromatic vinyl compound; and (B) a copolymer prepared by copolymerizing a (meth)acrylic acid alkyl ester compound, an aromatic vinyl compound, and a vinyl cyanide compound, and a molded article manufactured from the thermoplastic resin composition. In accordance with the present disclosure, a thermoplastic resin composition having superior heat resistance and transparency and a molded article manufactured from the same are provided.
摘要:
The present invention relates to a transparent resin composition that includes a transparent matrix resin containing a chemically recycled monomer unit to reduce carbon emissions so as to be eco-friendly and have excellent mechanical properties and weather resistance, and a molded article formed therefrom.
摘要:
The present invention relates to a method for preparing a graft copolymer powder, which includes: performing emulsion polymerization of a conjugated diene polymer, an aromatic vinyl monomer and an alkyl (meth)acrylate monomer to prepare a graft copolymer latex; coagulating the graft copolymer latex; aging the coagulated graft copolymer; preparing a wet powder of the graft copolymer by dehydrating the aged graft copolymer; and adding poly(oxyalkylene)diglycolic acid to the wet powder of the graft copolymer.