GRAFT COPOLYMER, PREPARATION METHOD THEREFOR, THERMOPLASTIC RESIN COMPOSITION CONTAINING SAME, AND MOLDED PRODUCT

    公开(公告)号:EP3409702A1

    公开(公告)日:2018-12-05

    申请号:EP18744366.8

    申请日:2018-01-02

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to a graft copolymer having excellent thermal stability, a method of preparing the graft copolymer, a thermoplastic resin composition including the graft copolymer, and a molded part including the thermoplastic resin composition. More specifically, the present invention relates to a graft copolymer having a core-shell structure and having excellent thermal stability, which is prepared according to an emulsion polymerization method, in which a metal salt of sorbic acid is included in reactants in a specific amount and is used as an emulsifier. According to the method, thermal stability of a graft copolymer can be improved by using the metal salt of sorbic acid, which can be easily removed in a dehydration process, instead of a conventional emulsifier, which remains in a reaction product after completion of emulsion polymerization and lowers thermal stability of a prepared graft copolymer.
    In addition, according to the present invention, since the thermoplastic resin composition of the present invention includes the graft copolymer having excellent thermal stability, the thermoplastic resin composition and the molded part manufactured using the thermoplastic resin composition have excellent physical properties, such as impact strength, fluidity, and transparency. Furthermore, the degree of discoloration that may occur when the resin composition or the molded part is allowed to stay in an injection molding machine or stay at a high temperature for a long period of time may be reduced.

    THERMOPLASTIC RESIN COMPOSITION AND MOLDED PRODUCT COMPRISING SAME
    4.
    发明公开
    THERMOPLASTIC RESIN COMPOSITION AND MOLDED PRODUCT COMPRISING SAME 审中-公开
    热塑性树脂组合物和包含该组合物的模制产品

    公开(公告)号:EP3235868A1

    公开(公告)日:2017-10-25

    申请号:EP16873284.0

    申请日:2016-12-01

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to a thermoplastic resin composition and a molded article including the same. More particularly, the present invention relates to a thermoplastic resin composition including 100 parts by weight of a base resin that includes an acrylic graft copolymer and an acrylic non-graft copolymer; and greater than 0.3 parts by weight and less than 1.2 parts by weight of a zinc-based antimicrobial agent, and a molded article including the same, wherein the zinc-based antimicrobial agent has an average particle diameter of greater than 3 µm to 30 µm.
    In accordance with the present invention, a thermoplastic resin composition providing superior transparency and excellent initial antimicrobial activity and persistent antimicrobial activity while providing the same mechanical properties as existing resin compositions, and a molded article including the same are provided.

    摘要翻译: 本发明涉及热塑性树脂组合物和包含其的模塑制品。 更具体地说,本发明涉及一种热塑性树脂组合物,其包含100重量份的包含丙烯酸类接枝共聚物和丙烯酸类非接枝共聚物的基础树脂; 以及大于0.3重量份且小于1.2重量份的锌基抗菌剂和包含其的模制品,其中所述锌基抗菌剂具有大于3μm至30μm的平均粒径 。 根据本发明,提供了一种热塑性树脂组合物,该组合物在提供与现有树脂组合物相同的机械性能的同时提供优异的透明度和优异的初始抗微生物活性和持久的抗微生物活性,以及​​包含该热塑性树脂组合物的模塑制品。

    THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE MANUFACTURED THEREFROM
    6.
    发明公开
    THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE MANUFACTURED THEREFROM 审中-公开
    热塑性树脂组合物及由其制造的模塑制品

    公开(公告)号:EP3287492A1

    公开(公告)日:2018-02-28

    申请号:EP17766912.4

    申请日:2017-03-02

    申请人: LG Chem, Ltd.

    摘要: The present disclosure relates to a thermoplastic resin composition and a molded article manufactured from the same. More particularly, the present disclosure relates to a thermoplastic resin composition including (A) a graft copolymer prepared by graft-copolymerizing a conjugated diene rubber, a (meth)acrylic acid alkyl ester compound, a methylene butyrolactone compound, and an aromatic vinyl compound; and (B) a copolymer prepared by copolymerizing a (meth)acrylic acid alkyl ester compound, an aromatic vinyl compound, and a vinyl cyanide compound, and a molded article manufactured from the thermoplastic resin composition.
    In accordance with the present disclosure, a thermoplastic resin composition having superior heat resistance and transparency and a molded article manufactured from the same are provided.

    摘要翻译: 本发明涉及热塑性树脂组合物和由其制造的模塑制品。 更具体地,本公开涉及一种热塑性树脂组合物,其包含:(A)通过将共轭二烯橡胶,(甲基)丙烯酸烷基酯化合物,亚甲基丁内酯化合物和芳香族乙烯基化合物接枝共聚而制备的接枝共聚物; 和(B)通过共聚合(甲基)丙烯酸烷基酯化合物,芳香族乙烯基化合物和氰化乙烯基化合物而制备的共聚物,和由该热塑性树脂组合物制造的模塑制品。 根据本公开,提供了具有优异耐热性和透明度的热塑性树脂组合物以及由其制造的模塑制品。