摘要:
A positive electrode active material for a non-aqueous electrolyte secondary battery includes a particle of a composite oxide which contains Li and Co, wherein: the composite oxide further contains an element M 1 and an element M 2 ; the element M 1 is at least one selected from the group consisting of Mg, Cu and Zn; the element M 2 is at least one selected from the group consisting of Al, Ca, Ba, Sr, Y and Zr; the element M 1 is uniformly distributed in the particle; and the element M 2 is distributed in the surface portion of the particle more than in the inside thereof.
摘要:
In order to provide a 3V level non-aqueous electrolyte secondary battery with a flat voltage and excellent cycle life at a high rate with low cost, the present invention provides a positive electrode represented by the formula: Li 2±α [Me] 4 O 8-x , wherein 0 ≦ α
摘要:
The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound , which is composed of, the element included in the nuclear particles, and at least one other element except the elements included in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The present invention is characterized that the lithium content of the nuclear particles of the composite particles is 40-95 atomic percent of the theoretical limit of lithium content of each constituent element of the nuclear particles. Further, the batteries are first charged at a constant current and upon reaching the predetermined voltage, are charged at a constant voltage. The current density during charging are set at not more than 5mA/cm 2 as a in the area where the positive and negative electrodes face each other. With the foregoing construction, high energy-density non-aqueous electrolyte secondary batteries with superior cycle life properties and a charging method for the same can be obtained.
摘要翻译:本发明的负极的特征在于,其复合颗粒的构成是将含有锡,硅和锌中的至少一种作为构成元素的至少一部分核粒子的周围表面涂布固溶体 或由包含在核粒子中的元素构成的金属间化合物,以及除了选自包含第2族元素,过渡元素,第12族元素的核粒子中的元素以外的至少一种其它元素, 第13族元素和第14族元素,除了元素周期的碳。 本发明的特征在于,复合粒子的核粒子的锂含量为核粒子的各构成元素的锂含量的理论极限的40〜95原子%。 此外,电池首先以恒定电流充电并且在达到预定电压时以恒定电压被充电。 在正极和负极彼此面对的区域中,充电期间的电流密度设定为5mA / cm 2以下。 通过上述结构,可以获得具有优异循环寿命特性的高能量密度非水电解质二次电池及其充电方法。
摘要:
A method for manufacturing a rectangular cell is provided in which a rectangular case containing a power generating element is hermetically sealed by laser welding a sealing plate to an open end of the rectangular case. A sealing plate 2 formed into the same shape as the upper open end of a rectangular case 1 is laid on the upper open end, laser beams 3a to 3d are applied in a downward direction from the horizontal to a line of contact 4 comprising sides "a" to "d" including respective corners "e", and the line of contact 4 is scanned with laser beams 3a to 3d thereby sealing the open end of the case with the sealing plate.
摘要:
A non-aqueous electrolyte secondary cell is characterized in that the negative plate is made chiefly of composite particles of which at least part of the core particles containing at least one kind among tin, silicon, and zinc as a constituent element are coated with a solid solution or an intermetallic compound consisting of the constituent element constituting the core particles and at least one element selected from the group consisting of Group 2 elements of the periodic table except the constituent element, transition elements, Group 12 elements, Group 13 elements, and Group 14 elements except carbon and in that the content of lithium in the core particles of the composite particles lies in the range from 50 element% to 90 element% of the theoretical limit of the lithium content. The secondary cell is further characterized in that it is charged with, first, a constant current and then with a low voltage after the voltage reaches a preset voltage, and the current density in charging is controlled. Therefore, the non-aqueous electrolyte secondary cell has a high energy density, and excellent cycle life characteristics.
摘要:
A charge control means (10) provided for a battery charging apparatus (1) conducts protection control for a battery pack (2) by transmitting a signal to an output control switch (14) for turning off an output when a rise rate of the temperature of the battery pack (2) detected based on information from a temperature detection terminal (8) is equal to or more than a predetermined value, or a rise rate of the voltage of the battery pack (2) detected based on information from a voltage detection terminal (9) is equal to or less than a predetermined value.
摘要:
The present invention provides a high-capacity and low-cost non-aqueous electrolyte secondary battery, comprising: a negative electrode containing, as a negative electrode active material, a ssubstance capable of absorbing/desorbing lithium ions and/or metal lithium; a separator; a positive electrode; and an electrolyte, wherein the positive electrode active material contained in the positive electrode is composed of crystalline particles of an oxide containing two kinds of transition metal elements, the crystalline particles having a layered crystal structure, and oxygen atoms constituting the oxide forming a cubic closest packing structure.
摘要:
A method for manufacturing a battery electrode plate includes the steps of mixing a solvent (3) with a polyolefin resin (1); preparing a gel-like solution (5), a gelled solution as a whole having a high viscosity, by heating the mixture of the polyolefin and the solvent at a temperature at which a part or the whole of the polyolefin resin melts; forming an insulation layer (8) by coating the gel-like solution on the surface of the positive electrode plate or negative electrode plate (7); and heating the positive electrode plate or negative electrode plate formed with the insulation layer.
摘要:
A nonaqueous electrolyte solution being liquid at normal temperature, comprising (A) 1,2-dialkoxyethane represented by Formula: R-O-CH 2 -CH 2 -O-R' (wherein, R and R', which are same or different from each other, independently represent an unsubstituted or fluorine-substituted alkyl group having a carbon number of 3 or less) and (B) lithium bis[trifluoromethanesulfonyl]imide at a molar ratio [(A)/(B)] of 0.75 or more and 2 or less.
摘要:
A method for manufacturing a cell electrode plate comprising: the step of mixing a polyolefin resin (1) with a solvent (3); the step of preparing a gel solution (5) having a totally high viscosity by heating the mixture of the polyolefin resin and the solvent at a temperature to melt the polyolefin resin partially or totally; the step of forming an insulating layer (8) by applying the gel solution to the surface of an anode or cathode (7); and the step of heating the anode or cathode having the insulating layer formed thereon.