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1.发明授权Olefin polymer of very low polydispersity and process for preparing the same 有权具有用于其制备非常低的多分散性和处理的烯烃聚合物
公开(公告)号：EP2267044B1
公开(公告)日：2015-07-08
申请号：EP10177047.7
申请日：2001-01-26
发明人： Mitani, Makoto , Yoshida, Yasunori , Mohri, Junichi , Tsuru, Kazutaka , Ishii, Seiichi , Kojoh, Shinichi , Matsugi, Tomoaki , Saito, Junji , Matsukawa, Naoto , Matsui, Shigekazu , Nakano, Takashi , Tanaka, Hidetsugu , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F10/00 , C08F210/16 , C08F4/60 , C08F8/00 , C08F297/06
CPC分类号： C08F297/086 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08F297/083 , C08L53/00 , C08L2666/02 , C08F2500/03 , C08F2500/01 , C08F210/06 , C08F210/08 , C08F210/14 , C08F4/64048
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公开(公告)号：EP2050769A3
公开(公告)日：2011-08-03
申请号：EP09000431.8
申请日：1999-04-15
发明人： Matsui, Shigekazu , Nitabaru, Masatoshi , Tsuru, Kazutaka , Fujita, Terunori , Suzuki, Yasuhiko , Takagi, Yukihiro , Tanaka, Hidetsugu
CPC分类号： C08F10/00 , C08F110/02 , C08F4/659 , C08F2500/17 , C08F4/64051 , C08F4/64044 , C08F4/64048 , C08F4/6411 , C08F4/6412 , C08F4/7008 , C08F4/7054 , C08F4/64113 , C08F4/64148 , C08F4/64151 , C08F4/64141
摘要： The present invention is intended to provide an olefin polymerization catalyst comprising a transition metal compound and having an excellent olefin polymerization activity and to provide a process for olefin polymerization using this catalyst. The olefin polymerization catalyst comprises a transition metal compound (A-2) represented by the formula (II-b) and further comprises at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and a compound (B-3) which reacts with the transition metal compound (A-2) to form an ion pair.
(wherein M, m, A, R 1 , R 2 , R 7 - R 10 , n and X are further defined in the specification).-
公开(公告)号：EP0950667A3
公开(公告)日：2003-02-05
申请号：EP99106268.8
申请日：1999-04-15
发明人： Matsui, Shigekazu , Tsuru, Kazutaka , Nitabaru, Masatoshi , Fujita, Terunori , Mitani, Makoto , Takagi, Yukihiro , Nakano, Takashi
CPC分类号： C08F10/00 , C08F110/02 , C08F4/64048 , C08F2500/17 , C08F4/64044 , C08F4/64051 , C08F4/64075
摘要： An olefin polymerization catalyst having an excellent polymerization activity and an olefin polymerization process using the catalyst are disclosed. The olefin polymerization catalyst comprises (A) a transition metal compound represented by, for example, the following formula (I) and optionally (B) at least one compound selected from an organometallic compound, an organoaluminum oxy-compound and a compound which reacts with the transition metal compound (A) to from an ion pair; wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table; m is an integer of 1 to 6; A is -O-, -S-, -Se- or -N(R5)-; D is -C(R 7 )(R 8 )-, -Si(R 9 )(R 10 )- or the like; Z is -R 13 and -R 14 , =C(R 15 )R 16 , =NR 17 or the like; R 1 to R 17 are each H, a hydrocarbon group or the like; n is a number satisfying a valence of M; and X is halogen, a hydrocarbon group or the like.
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4.发明公开Olefin polymerization catalyst and process for producing olefin polymer with the catalyst 有权Olefinpolymerisationskatalysator和Verfahren zur Herstellung von Olefinpolymeren damit
公开(公告)号：EP1238989A2
公开(公告)日：2002-09-11
申请号：EP02003261.1
申请日：2002-02-21
发明人： Nakayama, Yasushi , Kaneko, Hideyuki , Bandoh, Hideki , Sonobe, Yoshiho , Saito, Junji , Kojoh, Shinichi , Mitani, Makoto , Suzuki, Yasuhiko , Matsui, Shigekazu , Kashiwa, Norio , Fujita, Terunori
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/68 , C08F4/62 , C08F4/626 , C08F4/025 , C08F4/16 , C08F2500/17 , C08F2500/03 , C08F210/06 , C08F4/68112 , C08F4/6812 , C08F4/68181 , C08F4/68224 , C08F4/68293 , C08F4/6831 , C08F4/68413 , C08F4/68396 , C08F4/64044 , C08F4/64048 , C08F4/64072 , C08F4/64079 , C08F4/7042 , C08F4/7006
摘要： A novel olefin polymerization catalyst is provided which comprises (A) a transition metal compound or lanthanoid compound containing two or more atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur, and selenium; and (B) a Lewis acid. A process for producing an olefin polymer is alsoprovided. The catalyst has a high olefin polymerization activity without a combined use of an expensive organoaluminum oxy-compound or organoboron compound, and can maintain the high activity for a long polymerization time.
摘要翻译： 提供一种新型的烯烃聚合催化剂，其包含（A）含有选自硼，氮，氧，磷，硫和硒中的两个或多个原子的过渡金属化合物或镧系元素化合物; 和（B）路易斯酸。 还提供了制备烯烃聚合物的方法。 催化剂具有高的烯烃聚合活性，而不需要昂贵的有机铝氧化合物或有机硼化合物的组合使用，并且可以在长时间聚合时保持高活性。
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5.发明公开Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and Alpha-olefin/conjugated diene copolymers 失效烯烃聚合催化剂，过渡金属化合物，烯烃聚合方法和α-烯烃/二烯共聚物conjugiertes
公开(公告)号：EP0874005A1
公开(公告)日：1998-10-28
申请号：EP98107497.4
申请日：1998-04-24
发明人： Fujita, Terunori , Tohi, Yasushi , Mitani, Makoto , Matsui, Shigekazu , Saito, Junji , Nitabaru, Masatoshi , Sugi, Kiyoaki , Makio, Haruyuki , Tsutsui, Toshiyuki
CPC分类号： C08F210/02 , C07F7/006 , C07F7/082 , C07F9/005 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/17 , C08F2500/01 , C08F2500/03 , C08F236/06 , C08F210/06 , C08F4/64189 , C08F4/64048 , C08F4/7022 , C08F4/6812
摘要： The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an α-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R 1 is a hydrocarbon group, etc.; R 2 to R 5 are each H, a halogen, a hydrocarbon group, etc.; R 6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
摘要翻译： 本发明提供的烯烃聚合催化剂显示出优异的聚合活性，用于烯烃聚合反应使用的催化剂，催化剂中有用的新颖过渡金属化合物，和α-烯烃的/共轭的处理服务具有特定性质的共聚物。 本发明的烯烃聚合催化剂包括有机金属化合物，以oranoaluminum氧基化合物的式（I）或（II），和（B）的或电离化离子化合物（A）的过渡金属化合物。 本发明的新颖过渡金属化合物是式（I）化合物worin M是第3族或周期表的第4族的过渡餐原子; m为1〜3的整数; [R <1>为烃基等; [R <2>至R卤素<5>各自为H，一个，烃基等; [R <6>是卤素，烃基等; n是满足M的化合价的数; 和X为卤素，烃基等
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6.发明授权Olefin polymerization catalyst and process for producing olefin polymer with the catalyst 有权用于产生与其烯烃聚合物的烯烃聚合催化剂和方法
公开(公告)号：EP1238989B1
公开(公告)日：2015-10-07
申请号：EP02003261.1
申请日：2002-02-21
发明人： Nakayama, Yasushi , Kaneko, Hideyuki , Bandoh, Hideki , Sonobe, Yoshiho , Saito, Junji , Kojoh, Shinichi , Mitani, Makoto , Suzuki, Yasuhiko , Matsui, Shigekazu , Kashiwa, Norio , Fujita, Terunori
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/68 , C08F4/62 , C08F4/626 , C08F4/025 , C08F4/16 , C08F2500/17 , C08F2500/03 , C08F210/06 , C08F4/68112 , C08F4/6812 , C08F4/68181 , C08F4/68224 , C08F4/68293 , C08F4/6831 , C08F4/68413 , C08F4/68396 , C08F4/64044 , C08F4/64048 , C08F4/64072 , C08F4/64079 , C08F4/7042 , C08F4/7006
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7.发明授权
公开(公告)号：EP2267045B1
公开(公告)日：2015-07-15
申请号：EP10177048.5
申请日：2001-01-26
发明人： Mitani, Makoto , Yoshida, Yasunori , Mohri, Junichi , Tsuru, Kazutaka , Ishii, Seiichi , Kojoh, Shinichi , Matsugi, Tomoaki , Saito, Junji , Matsukawa, Naoto , Matsui, Shigekazu , Nakano, Takashi , Tanaka, Hidetsugu , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F10/00 , C08F210/16 , C08F4/60 , C08F8/00 , C08F297/06
CPC分类号： C08F297/086 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08F297/083 , C08L53/00 , C08L2666/02 , C08F2500/03 , C08F2500/01 , C08F210/06 , C08F210/08 , C08F210/14 , C08F4/64048
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8.发明授权Olefin diblock copolymer of very low polydispersity and process for preparing the same 有权烯烃二嵌段共聚物具有非常低的多分散性和处理它的制备
公开(公告)号：EP2267042B1
公开(公告)日：2015-06-10
申请号：EP10177044.4
申请日：2001-01-26
发明人： Mitani, Makoto , Yoshida, Yasunori , Mohri, Junichi , Tsuru, Kazutaka , Ishii, Seiichi , Kojoh, Shinichi , Matsugi, Tomoaki , Saito, Junji , Matsukawa, Naoto , Matsui, Shigekazu , Nakano, Takashi , Tanaka, Hidetsugu , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F10/00 , C08F210/16 , C08F4/60 , C08F8/00 , C08F297/06
CPC分类号： C08F297/086 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08F297/083 , C08L53/00 , C08L2666/02 , C08F2500/03 , C08F2500/01 , C08F210/06 , C08F210/08 , C08F210/14 , C08F4/64048
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9.发明授权
公开(公告)号：EP1170308B1
公开(公告)日：2015-05-06
申请号：EP01115672.6
申请日：2001-07-04
发明人： Inoue, Yoshihisa , Matsui, Shigekazu , Suzuki, Yasuhiko , Yoshida, Yasunori , Takagi, Yukihiro , Fujita, Terunori , Matsugi, Tomoaki , Nakano, Takashi
IPC分类号： C08F210/02 , C08F4/68
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
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10.发明公开Tapered olefin copolymer of very low polydispersity and process for preparing the same 审中-公开连续变化的共聚单体组合物和方法及其制备的非常低的多分散性的烯烃共聚物
公开(公告)号：EP2267043A1
公开(公告)日：2010-12-29
申请号：EP10177046.9
申请日：2001-01-26
发明人： Mitani, Makoto , Yoshida, Yasunori , Mohri, Junichi , Tsuru, Kazutaka , Ishii, Seiichi , Kojoh, Shinichi , Matsugi, Tomoaki , Saito, Junji , Matsukawa, Naoto , Matsui, Shigekazu , Nakano, Takashi , Tanaka, Takashi , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F10/00 , C08F210/16 , C08F4/60 , C08F8/00 , C08F297/06
CPC分类号： C08F297/086 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08F297/083 , C08L53/00 , C08L2666/02 , C08F2500/03 , C08F2500/01 , C08F210/06 , C08F210/08 , C08F210/14 , C08F4/64048
摘要： The present invention provides a tapered olefin copolymer having a narrow molecular weight distribution and a specific molecular weight, containing a segment wherein monomer composition continuously changes in the polymer chain and a process for preparing this polymer. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 2.5. In the process for preparing an olefin polymer, olefins of 2 to 20 carbon atoms are polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I):
L m MX n (I)
wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.摘要翻译： 本发明提供了具有窄分子量分布和特定分子量的锥形烯烃共聚物，含一个段worin单体组合物连续地改变在聚合物链中和用于制备该聚合物的方法。 本发明的烯烃聚合物是含2-20个碳原子的烯烃的聚合物和具有不小于500和Mw / Mn为不大于2.5的数均分子量。 在用于烯烃聚合物的制备过程中，2至20个碳原子的烯烃聚合在一种烯烃聚合催化剂的存在下，包括由表示的过渡金属化合物，例如，下述式（I）：L M MX N（我 ）worin m是第3族的周期表第11族的过渡金属原子，m是1至5，n为满足m的化合价的数，L是配位到中心金属M的配位体和由含有配位体 具有杂原子不直接键合到中心金属，X是卤原子，烃基或类似物。
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