摘要:
Provided is a biomass-resource-derived polyester, comprising as a main repeating unit thereof a dicarboxylic acid unit and a diol unit, wherein at least one of the dicarboxylic acid and diol used as raw materials of the polyester is obtained from biomass resources, a nitrogen atom content in the polyester except nitrogen atoms contained in covalently bonded functional groups in the molecule of the polyester is 0.01 ppm to 50 ppm, wherein an amount of terminal acid in the polyester is 50 equivalents/metric ton or less, and wherein a metal amount of a polymerization catalyst selected from the group consisting of titanium, zirconium, tin, antimony, cerium, germanium, zinc, cobalt, manganese, iron, aluminum, magnesium, calcium, strontium, sodium and potassium in the polyester, is 5 ppm to 130 ppm.
摘要:
Provided is a biomass-resource-derived polyester, comprising as a main repeating unit thereof a dicarboxylic acid unit and a diol unit, wherein at least one of the dicarboxylic acid and diol used as raw materials of the polyester is obtained from biomass resources, a nitrogen atom content in the polyester except nitrogen atoms contained in covalently bonded functional groups in the molecule of the polyester is 0.01 ppm to 50 ppm, wherein an amount of terminal acid in the polyester is 50 equivalents/metric ton or less, and wherein a metal amount of a polymerization catalyst selected from the group consisting of titanium, zirconium, tin, antimony, cerium, germanium, zinc, cobalt, manganese, iron, aluminum, magnesium, calcium, strontium, sodium and potassium in the polyester, is 5 ppm to 130 ppm.
摘要:
Provided is a pellet obtained from a biomass-resource-derived polyester comprising as a main repeating unit thereof a dicarboxylic acid unit and a diol unit, wherein at least one of the dicarboxylic acid and diol used as raw materials of the polyester is obtained from biomass resources; and wherein a nitrogen atom content in the polyester except nitrogen atoms contained in the covalently bonded functional group in the molecule of the polyester is, in terms of a mass ratio, 0.01 ppm or greater but not greater than 50 ppm relative to the polyester.
摘要:
Provided is an aliphatic diol which is derived from a biomass resource and the diol comprises nitrogen atoms in an amount of 0.01 to 100 ppm based on the mass of the diol, or a derived compound thereof, a polyester comprising at least one compound unit of the aliphatic diol or the derived compound thereof, and a process for producing a biomass-resource-derived polyester by reaction of a dicarboxylic acid and the diol. Moreover, a process is provided for producing a cyclic monomer.
摘要:
Provided is a pellet obtained from a biomass-resource-derived polyester, wherein the biomass-resource-derived polyester comprises as a main repeating unit thereof a dicarboxylic acid unit and a diol unit, wherein at least one of the dicarboxylic acid and diol used as raw materials of the polyester is obtained from biomass resources, and wherein a water content in the polyester pellets is 0.1 ppm to 3000 ppm, as a mass ratio based on the polyester.
摘要:
Provided is a pellet obtained from a biomass-resource-derived polyester comprising as a main repeating unit thereof a dicarboxylic acid unit and a diol unit, wherein at least one of the dicarboxylic acid and diol used as raw materials of the polyester is obtained from biomass resources; and wherein a nitrogen atom content in the polyester except nitrogen atoms contained in the covalently bonded functional group in the molecule of the polyester is, in terms of a mass ratio, 0.01 ppm or greater but not greater than 50 ppm relative to the polyester.
摘要:
The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use. The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要:
Provided is a process for producing a polyester composed mainly of a diol unit and a dicarboxylic acid unit, wherein at least one of the dicarboxylic acid and the diol used as raw materials of the polyester is obtained from a biomass resource and a nitrogen atom content in the polyester except nitrogen atoms contained in the covalently bonded functional groups in the molecule of the polyester is, in terms of a mass ratio, 0.01 ppm to 50 ppm relative to the polyester.
摘要:
Provided is an aliphatic diol which is derived from a biomass resource and the diol comprises nitrogen atoms in an amount of 0.01 to 100 ppm based on the mass of the diol, or a derived compound thereof, a polyester comprising at least one compound unit of the aliphatic diol or the derived compound thereof, and a process for producing a biomass-resource-derived polyester by reaction of a dicarboxylic acid and the diol. Moreover, a process is provided for producing a cyclic monomer.