Near infrared absorber, preparation process thereof and use thereof
    9.
    发明公开
    Near infrared absorber, preparation process thereof and use thereof 失效
    Absorber im nahen Infrarot,dessen Herstellungsverfahren sowie dessen Verwendung

    公开(公告)号:EP0718375A2

    公开(公告)日:1996-06-26

    申请号:EP95119802.7

    申请日:1995-12-15

    摘要: A phthalocyanine near infrared absorber having a broad absorption range in the near infrared region and represented by the following formula (1):

    wherein R¹ and R² each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; Ys each independently represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; m stands for an integer of 0 to 4; Pc represents a phthalocyanine nucleus; Z represents an -SH group or an -NHR³ group in which R³ represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; Xs each independently represents a halogen atom, a hydroxy group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted alkylamino group, a substituted or unsubstituted arylamino group and a substituted or unsubstituted alkylarylamino group; the adjacent pairs of Xs may form a 5- or 6-membered ring via two hetero atoms; M represents a divalent metal atom, a substituted trivalent or tetravalent metal or an oxymetal atom; p stands for an integer of 1 to 16; q stands for an integer of 0 to 8; r stands for an integer of 0 to 8; and p + 2q + r is not greater than 16 .

    摘要翻译: 在近红外区域具有宽吸收范围并由下式(1)表示的酞菁近红外吸收剂:其中R 1和R 2各自独立地表示氢原子,取代或未取代的烷基 基团或取代或未取代的芳基; Y各自独立地表示取代或未取代的烷基,取代或未取代的芳基,取代或未取代的烷氧基或取代或未取代的芳氧基; m代表0到4的整数; Pc代表酞菁核; Z表示-SH基或-NHR 3基,其中R 3表示氢原子,取代或未取代的烷基或取代或未取代的芳基; Xs各自独立地表示卤素原子,羟基,取代或未取代的烷氧基,取代或未取代的芳氧基,取代或未取代的烷硫基,取代或未取代的芳硫基,取代或未取代的烷基氨基,取代或未取代的烷基氨基, 未取代的芳基氨基和取代或未取代的烷基芳基氨基; 相邻的X对可以通过两个杂原子形成5-或6-元环; M表示二价金属原子,取代的三价或四价金属或氧金属原子; p代表1到16的整数; q表示0〜8的整数, r代表0到8的整数; 并且p + 2q + r不大于16。

    Phthalocyanine compounds and optical recording media comprising them
    10.
    发明公开
    Phthalocyanine compounds and optical recording media comprising them 失效
    酞菁染色剂和紫外线吸收剂

    公开(公告)号:EP0719839A3

    公开(公告)日:1998-03-18

    申请号:EP95120406.4

    申请日:1995-12-22

    摘要: A near infrared light-absorbing dye comprising phthalocyanine compounds represented by the following formula (2):

    wherein in formula (2), M is two hydrogen atoms, a divalent metallic atom, a trivalent monosubstituted metallic atom, a tetravalent disubstituted metallic atom or an oxymetal atom, and L 1 , L 2 , L 3 and L 4 are each independently formula (a) or (b),

       in the formula (a) or (b), R 1 and R 3 are each a substituted or unsubstituted alkyl group, and R 2 is a straight chain or branched halogenated alkyl or alkenyl group having 3 to 10 carbon atoms,
    X is a chlorine, bromine or iodine atom, and m is an integer of 1 to 12, provided that formula (2) represents a mixture of L 1 = L 2 = L 3 = L 4 = formula (a) , L 1 = L 2 = L 4 = formula (a) and L 3 = formula (b) , L 1 = L 4 = formula (a) and L 2 = L 3 = formula (b) , L 1 = L 3 = formula (a) and L 2 = L 4 = formula (b) , L 1 = formula (a) and L 2 = L 3 = L 4 = formula (b) , and L 1 = L 2 = L 3 = L 4 = formula (b) ,
    and an optical recording medium comprising the phthalocyanine mixture.

    摘要翻译: 一种包含由下式(2)表示的酞菁化合物的近红外光吸收染料:其中在式(2)中,M为两个氢原子,二价金属原子,三价单取代金属原子,四价二取代金属 原子或氧金属原子,L 1,L 2,L 3和L 4各自独立地为式(a)或(b),式(a)或(b)中的 = L 2 = L 4 =式(a)和L 3 =式(b),L 1 = L 4 =式(a)和L 2 = (b),L 1 = L 3 =式(a)和L 2 = L 4 =式(b),L 1 =式(a)和L < 2> = L 3 = L 4 =式(b),L 1 = L 2 = L 3 = L 4 > =式(b),以及包含酞菁混合物的光学记录介质。