摘要:
In a lithium ion secondary battery including a positive electrode, a separator, a negative electrode, and a package body, the negative electrode includes simple substance silicon as a negative electrode active material, and a negative electrode binder, and is doped with lithium, and the following formulas (1) and (2) are satisfied: 1.2 ≤ M a / M c ≤ 1.9 1.0 M a / M c + M Li 1.6 wherein an amount of lithium inserted into the negative electrode until the negative electrode reaches a potential of 0.02 V with respect to metal lithium is M a (a number of atoms), an amount of lithium released from the positive electrode until the positive electrode reaches a potential of 4.3 V with respect to metal lithium is M c (a number of atoms), and an amount of lithium with which the negative electrode is doped is M Li (a number of atoms).
摘要翻译:在包括正极,隔膜,负极和封装体的锂离子二次电池中,负极包括作为负极活性物质的单质硅和负极粘合剂,并掺杂有锂,并且 满足以下公式(1)和(2):1.2‰M a / M c‰1.9 1.0 M a / M c + M Li <1.6其中插入负极直到负极 相对于金属锂达到0.02V的电位为M a(原子数),从正极释放到正电极相对于金属锂的电位达到4.3V为止的锂量为M c(a 原子数),掺杂负极的锂量为M Li(原子数)。
摘要:
There is provided a nonaqueous electrolyte secondary battery having high capacity in which the reduction in the capacity of the battery due to the irreversible capacity in the first charge and discharge is suppressed using a high capacity positive electrode. The nonaqueous electrolyte secondary battery according to the exemplary embodiment includes a positive electrode and a negative electrode including at least one negative electrode active material selected from the group consisting of Si, a Si oxide and carbon, wherein the positive electrode includes a positive electrode active material including an oxide capable of absorbing and releasing lithium and a transition metal oxide, the transition metal oxide being represented by Li 2 MO 2 (wherein M is at least one of Cu and Ni) and including a square-planar coordination MO 4 structure, the square-planar coordination MO 4 structure forming a one-dimensional chain which shares an edge formed by two opposing oxygen atoms, wherein the relation Z ≤ Y is satisfied provided that Y represents the first charge capacity of the negative electrode, and Z represents the first charge capacity of the positive electrode.
摘要:
There is provided a nonaqueous electrolyte secondary battery having high capacity in which the reduction in the capacity of the battery due to the irreversible capacity in the first charge and discharge is suppressed using a high capacity positive electrode. The nonaqueous electrolyte secondary battery according to the exemplary embodiment includes a positive electrode (6) and a negative electrode (3) comprising at least one negative electrode active material selected from the group consisting of Si, a Si oxide and carbon,wherein the positive electrode (6) comprises a positive electrode active material comprising an oxide capable of absorbing and releasing lithium and a transition metal oxide, the transition metal oxide being represented by Li 2 MO 2 (wherein M is at least one of Cu and Ni) and including a square-planar coordination MO 4 structure, the square-planar coordination MO 4 structure forming a one-dimensional chain which shares an edge formed by two opposing oxygen atoms, wherein a relation Z ≤ Y is satisfied provided that Y represents a first charge capacity of the negative electrode, and Z represents a first charge capacity of the positive electrode, characterized in that a relation γ
摘要:
There is provided a polymer secondary battery using silicon and silicon oxide as a negative electrode active material that shows a high capacity retention rate also when a charge and discharge cycle is repeated. A polymer secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a polymer-containing gel electrolyte, wherein the negative electrode includes silicon and silicon oxide as a negative electrode active material, and the polymer-containing gel electrolyte is present in voids formed by fine division of particles of the negative electrode active material.
摘要:
The anode of a nonaqueous electrolyte secondary cell contains (A) a lithium-manganese compound oxide and (B1) a lithium-nickel compound oxide having a specific surface area X of below 0.3 (m2/g) and consisting of at least one kind selected from among the group consisting of LiNiO¿2?, Li2NiO2, LiNi2O4, Li2Ni2O4, and LiNi1-xMxO2 (0∫x≤0.5, and M represents at least one metallic element selected from among the group consisting of Co, Mn, Al, Fe, Cu, and Sr). Such a nonaqueous electrolyte secondary cell is excellent in cell characteristics, and especially charging/discharging cycle characteristic, storage characteristic, and safety.
摘要:
A positive electrode of a nonaqueous electrolyte solution secondary battery comprises (A) a lithium-manganese composite oxide and (B1) at least one lithium-nickel composite oxide which has a specific surface area X of 0.3 ≤ X (m 2 /g) and which is selected from a group consisting of LiNiO 2 , Li 2 NiO 2 , LiNi 2 O 4 , Li 2 Ni 2 O 4 and LiNi 1-x M x O 2 (0